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We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. 87Sr/86Sr vs 143Nd/144Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both 206Pb/204Pbvs 207Pb/204Pb and 208Pb/204Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (206Pb/204Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (206Pb/204Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low 18Oolivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic 206Pb/204Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; 206Pb/204Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high 87Sr/86Sr and 207Pb/204Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction  相似文献   
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We conducted an assessment of the TOPEX dual-frequency nadir ionosphere observations in the TOPEX/Poseidon (T/P) GDR by comparing TOPEX with the Center for Orbit Determination in Europe (CODE) Global Ionosphere Map (GIM), the climatological model IRI2001, and the DORIS (onboard T/P) relative ionosphere delays. We investigated the TOPEX (TOPEX Side A and TOPEX Side B altimeters, TSA and TSB, respectively) ionosphere observations for the time period 1995–2001, covering periods of low, intermediate, and high solar activity. Here, we use absolute path delays (at Ku-band frequency of the TOPEX altimeter and with positive signs) rather than Total Electron Content (TEC). We found significant biases between GIM and TOPEX (GIM–TOPEX) nadir ionosphere path delays: ?8.1 ± 0.4 {mm} formal uncertainties and equivalent to 3.7 TECu) and ?9.0 ± 0.7 {mm} (4.1 TECu) for TSA and TSB, respectively, indicating that the TOPEX path delay is longer (or with higher TECu) than GIM. The estimated relative biases vary with latitude and with daytime or nighttime passes. The estimated biases in the path delays (DORIS–TOPEX) are: ?10.9 ± 0.4 {mm} (5.0 TECu) and ?14.8 ± 0.6 {mm} (6.7 TECu), for TSA and TSB, respectively. There is a distinct jump of the DORIS path delays (?3.9 ± 0.7 {mm}, TSA delays longer than TSB delays) at the TSB altimeter switch in February 1999, presumably due to inconsistent DORIS processing. The origin of the bias between GIM (GPS, L-band) and TOPEX (radar altimeter, Ku-band) is currently unknown and warrants further investigation. Finally, the estimated drift rates between GIM and TSA, DORIS and TSA ionosphere path delays for the 6-year study span are ?0.4 mm/yr and ?0.8 mm/yr, respectively, providing a possible error bound for the TOPEX/Poseidon sea level observations during periods of low and intermediate solar activity.  相似文献   
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A piston core from the basinal part (depth of 5188 m) of the South Shetland Trench (West Antarctica) yielded a terrigenous mud section 11 m long, which can be subdivided with great precision into turbidite and hemipelagite layers. Mud turbidites (mean bed thickness = 44 cm) alternate regularly with, and are best distinguishable from, their hemipelagite host (mean bed thickness = 17 cm) by the following features: (i) sharp basal contacts; (ii) terrigenous sand-free textures (except basal, well-sorted silt laminae) and the absence of outsized (ice-rafted) components; (iii) a laminated, little to non-bioturbated internal structure; (iv) distinct textural and compositional grading; and (v) marked steps on water-content and sediment-density logs. Mud turbidites recovered from the South Shetland Trench differ from an earlier model mud-turbidite sequence by their: (i) excessive (about six times larger) bed thickness; (ii) complex internal organization, manifested in multiple repetitions (up to four) of the same structural interval(s) in sequential or nonsequential order; (iii) distinctive very fine-grained cap of highly porous clay, rich in fragments of siliceous biogenics; (iv) widespread zones of penesyndepositional deformation; and (v) evidence of flow reversals. These features are interpreted to record deposition from large, muddy turbidity currents subjected to flow transformations, including soliton- and/or seiche-related reversals, induced by ponding and interactions of the flow with the topographical confinements of the trench. It is concluded that‘contained’muddy turbidites cannot be adequately modelled using published sequences. Differentiation of single-model and‘contained’mud turbidites offers obvious advantages in basin analysis and in understanding the plethora of turbidity current-related depositional mechanisms of deep-sea mud.  相似文献   
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Résumé

Nous examinons ici le phénomène très complexe de l'érosion hydrique de bassins versants. L'approche adoptée consiste d'une part à quantifier l'érosion à plusieurs échelles spatiales, au sens de la méthode Wischmeier, de la simulation de pluies sur 1 et 87 m2, de micro-bassins expérimentaux, de retenues collinaires et d'un barrage en exploitation, et d'autre part à rechercher un modèle régressif pouvant expliquer la relation débit solide-débit liquide pour les différentes formes d'érosion. Une zone de marnes du bassin de la Mina en Algérie, productive en sédiments pour un barrage en aval et représentant le cinquième de la surface, a constitué la zone expérimentale. Les résultats montrent que, vu la complexité des facteurs mis enjeu, il est quasiment impossible d'extrapoler à différentes échelles. Le modèle puissance caractérise la relation débit solide-débit liquide, quelle que soit l'échelle spatiale considérée.  相似文献   
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Formation of Organic Aerosols from the Oxidation of Biogenic Hydrocarbons   总被引:15,自引:0,他引:15  
Measurements of aerosol formation during thephotooxidation of -pinene, -pinene,d-3-carene, d-limonene, ocimene, linalool, terpinene-4-ol, andtrans-caryophyllene were conducted in anoutdoor smog chamber. Daylight experiments in thepresence of and dark experiments withelevated ozone concentrations were performed. Theevolution of the aerosol was simulated by theapplication of a gas/particle absorption model inconnection with a chemical reaction mechanism. Thefractional aerosol yield is shown to be a function ofthe organic aerosol mass concentration andtemperature. Ozone and, for selected hydrocarbons, theNO3 reaction of the compounds were found torepresent efficient routes to the formation ofcondensable products. For initial hydrocarbon mixingratios of about 100 ppb, the fractional aerosol yieldsfrom daylight runs have been estimated to be 5%for open-chain hydrocarbons, such as ocimene andlinalool, 5–25% for monounsaturated cyclicmonoterpenes, such as -pinene, d-3-carene, orterpinene-4-ol, and 40% for a cyclic monoterpenewith two double bonds like d-limonene. For the onlysesquiterpene investigated, trans-caryophyllene, afractional aerosol yield of close to 100% wasobserved. The majority of the compounds studied showedan even higher aerosol yield during dark experimentsin the presence of ozone.  相似文献   
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