The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States     

Herbert L Windom  Ralph G Smith  Masaru Maeda 《Marine Chemistry》1985,17(1):43-56

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.  相似文献   

Quadruple sulfur isotope analysis of ca. 3.5 Ga Dresser Formation: New evidence for microbial sulfate reduction in the early Archean     

Yuichiro Ueno  Shuhei Ono  Douglas Rumble 《Geochimica et cosmochimica acta》2008,72(23):5675-5691

Multiple sulfur isotope system is a powerful new tracer for atmospheric, volcanic, and biological influences on sulfur cycles in the anoxic early Earth. Here, we report high-precision quadruple sulfur isotope analyses (³²S/³³S/³⁴S/³⁶S) of barite, pyrite in barite, and sulfides in related hydrothermal and igneous rocks occurring in the ca. 3.5 Ga Dresser Formation, Western Australia. Our results indicate that observed isotopic variations are mainly controlled by mixing of mass-dependently (MD) and non-mass-dependently fractionated (non-MD) sulfur reservoirs. Based on the quadruple sulfur isotope systematics (δ³⁴S-Δ³³S-Δ³⁶S) for these minerals, four end-member sulfur reservoirs have been recognized: (1) non-MD sulfate (δ³⁴S = −5 ± 2‰; Δ³³S = −3 ± 1‰); (2) MD sulfate (δ³⁴S = +10 ± 3‰); (3) non-MD sulfur (δ³⁴S > +6‰; Δ³³S > +4‰); and (4) igneous MD sulfur (δ³⁴S = Δ³³S = 0‰). The first and third components show a clear non-MD signatures, thus probably represent sulfate and sulfur aerosol inputs. The MD sulfate component (2) is enriched in ³⁴S (+10 ± 3‰) and may have originated from microbial and/or abiotic disproportionation of volcanic S or SO₂. Our results reconfirm that the Dresser barites contain small amounts of pyrite depleted in ³⁴S by 15-22‰ relative to the host barite. These barite-pyrite pairs exhibit a mass-dependent relationship of δ³³S/δ³⁴S with slope less than 0.512, which is consistent with that expected for microbial sulfate reduction and is significantly different from that of equilibrium fractionation (0.515). The barite-pyrite pairs also show up to 1‰ difference in Δ³⁶S values and steep Δ³⁶S/Δ³³S slopes, which deviate from the main Archean array (Δ³⁶S/Δ³³S = −0.9) and are comparable to isotope effects exhibited by sulfate reducing microbes (Δ³⁶S/Δ³³S = −5 to −11). These new lines of evidence support the existence of sulfate reducers at ca. 3.5 Ga, whereas microbial sulfur disproportionation may have been more limited than recently suggested.  相似文献   

Near inertial motion excited by wind change in a margin of the Typhoon 9019   总被引：1，自引：0，他引：1  

Akio Maeda  Kazuki Uejima  Toru Yamashiro  Masahito Sakurai  Hiroshi Ichikawa  Masaki Chaen  Keisuke Taira  Shinjirou Mizuno 《Journal of Oceanography》1996,52(3):375-388

An excitation of inertial oscillation in the upper layer east of course of Typhoon 9019 was fortuitously observed at three surface buoys deployed during the Ocean Mixed Layer Experiment (OMLET). The observed inertial oscillation was compared with wind fluctuation measured at Ocean Weather Station T (29°N, 135°E) which was placed at the center of a triangle with three vertexes occupied by the respective surface buoys. Inertial oscillation is effectively excited in the mixed layer at the eastern margin of the typhoon by a rapid decrease of wind rather than by prevailing strong wind. It is shown by means of a least square deviation that the inertial oscillation observed in the mixed layer has a period of 23.9 hours shorter than the local inertial period of 24.7 hours. This shorter period suggests that the inertial oscillation has the finite velocities of phase and group as an inertial internal wave. A theoretically obtained ratio of vertical component of group velocity to that of phase velocity, approximately agrees with observed value. The inertial internal wave is excited by fluctuation of divergence with near inertial period in the mixed layer.  相似文献   

A description of short period temperature fluctuations in the upper ocean     

Akio Maeda 《Journal of Oceanography》1974,30(3):121-136

Dynamical properties of short-period temperature fluctuations are studied. Water temperature was measured continuously at several depths at the following stations: at 38°29.5′N, 141°35.8′E (100 m depth) on the continental shelf off Miyagi Prefecture in the summer of 1967, at 35°01.8′N, 139°0.8.5′E (100 m depth) in Sagami Bay in the summer of 1968, and at 32°32.2′N, 129°53.7′E (74 m depth) in Tachibana Bay in the summer of 1970. These measurements were made with a thermistor array laid down from the R. V.Tanseimaru (Ocean Research Institute, University of Tokyo) which was fixed with bow and stern anchors. Significant temperature fluctuations found at the first and the third stations are thought to be due to first mode internal waves having amplitude 3 to 5 m and period 5 to 20 minutes. The wave length of the waves is estimated to be 25 m to 400 m from the observed density structure. At the second station, we found second-mode internal waves. The period, amplitude and wave length of the waves are about 30 minutes, 1.3 m and 600 m, respectively. In all cases, the spectral density of the temperature fluctuations decreases with increase in frequency. However, the decrease obey neither the ?3 power law nor the ?5/3 power law. Coherences in the temperature fluctuations between two depths of measurement in the seasonal thermocline are significantly high in the range of frequencies lower than the local Brunt-Väisälä frequency, but are low in the higher frequency range. At the first and the third stations, the difference in the level of coherences between the lower frequencies and the higher frequencies are large. Phase differences between two depths in the thermocline are small in the lower frequency range. This suggests that the first-mode internal waves are predominant over higher-mode internal waves and over other disturbances.  相似文献   

Transport of copper from the Bering Sea to the northwestern North Pacific     

Masaru Maeda 《Journal of Oceanography》1986,42(5):333-346

Dissolved copper concentrations in surface waters of the Bering Sea ranged from 106 to 882 ngl^–1. Higher concentrations were found in continental shelf waters. In the northwestern North Pacific dissolved copper ranged from 54 to 140 ngl^–1. Particulate copper concentrations varied regionally and seasonally from 6 to 79 ngl^–1. Regionally averaged particulate copper concentrations decreased from 175 to 33g g^–1 against an increase in suspended materials because of the dilution effects of biological fractions. Apparent sporadic increases in copper concentrations were found in the mixing area of the Kuroshio and the Oyashio waters. The feature is attributed to the lateral distribution of different water types rather than to the upwelling of deeper waters by eddies. In the same area west of 160E, waters with high concentrations of dissolved copper (96±9 ngl^–1) were found. Their origin appears to be the continental shelf of the Bering Sea. In spite of intensive biological activity, a considerable fraction of copper added to shelf waters was transported to the area off Japan via the circulation in the Bering Sea and the Oyashio current.  相似文献   

State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment   总被引：1，自引：0，他引：1  

Toshiyuki Awaji  Shuhei Masuda  Yoichi Ishikawa  Nozomi Sugiura  Takahiro Toyoda  Tomohiro Nakamura 《Journal of Oceanography》2003,59(6):931-943

A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Changing grading of soil: effect on critical states   总被引：6，自引：3，他引：3  

David Muir Wood  Kenichi Maeda 《Acta Geotechnica》2008,3(1):3-14

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.  相似文献   

Mass-dependent fractionation of quadruple stable sulfur isotope system as a new tracer of sulfur biogeochemical cycles     

Shuhei Ono  Boswell Wing  James Farquhar 《Geochimica et cosmochimica acta》2006,70(9):2238-2252

Sulfur isotope studies of post-Archean terrestrial materials have focused on the ratio ³⁴S/³²S because additional isotopes, ³³S and ³⁶S, were thought to carry little information beyond the well-known mass-dependent relationship among multiple-isotope ratios. We report high-precision analyses of Δ³³S and Δ³⁶S values, defined as deviations of ³³S and ³⁶S from ideal mass-dependent relationships, for international reference materials and sedimentary sulfides of Phanerozoic age by using a fluorination technique with a dual-inlet isotope ratio mass spectrometer. Measured variations in Δ³³S and Δ³⁶S are explained as resulting from processes involve branching reactions (two or more reservoirs formed) or mixing. Irreversible processes in closed systems (Rayleigh distillation) amplify the isotope effect. We outline how this new isotope proxy can be used to gain new insights into fundamental aspects of the sulfur biogeochemical cycle, including additional constraints on seawater sulfate budget and processes in sedimentary sulfide formation. The isotope systematics discussed here cannot explain the much larger variation of Δ³³S and Δ³⁶S observed in Archean rock records. Furthermore, Phanerozoic samples we have studied show a characteristic Δ³³S and Δ³⁶S relationship that differs from those measured in Archean rocks and laboratory photolysis experiments. Thus, high precision analysis of Δ³³S and Δ³⁶S can be used to distinguish small non-zero Δ³³S and Δ³⁶S produced by mass-dependent processes from those produced by mass-independent processes in Archean rocks and extraterrestrial materials.  相似文献   

Evidence for high-Ca boninite magmatism from Paleogene primitive low-K tholeiite, Mukoojima, Hahajima Island group, southern Bonin (Ogasawara) forearc, Japan   总被引：2，自引：0，他引：2  

Kosuke  Maehara  Jinichiro  Maeda 《Island Arc》2004,13(3):452-465

Abstract   High-Ca boninitic inclusions are found in primitive low-K tholeiite from Mukoojima (Mukoo-Jima), an islet in the Hahajima Island group, Bonin (Ogasawara) forearc, Japan. While Chichijima Island group, 50 km north of Hahajima Island group, is well known as a type locality of boninite, there has been no report of boninitic rocks from the Hahajima Island group. The high-Ca boninitic inclusions are aphanitic and contain olivine, Ca-rich clinopyroxene, plagioclase, chromian spinel, opaque minerals and dark brown glass. The mode of occurrence of the inclusions and host tholeiite under the microscope indicates mingling of these two magmas, suggesting intimate association in space and time of the boninite and primitive tholeiite magmas around the Hahajima Island group in Paleogene time. Primitive compositions and slightly different Sr and Nd isotopic ratios suggest that these two magmas are derived from two distinct mantle sources. These two mantle sources were present at the same time around the Hahajima Island group, southern Bonin forearc. The source of the high-Ca boninite was higher in water content and/or shallower in depth compared to that of the primitive tholeiite.  相似文献   

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating     

Yukio Isozaki  Shinji Yamamoto  Shuhei Sakata  Hideyuki Obayashi  Takafumi Hirata  Ken-ichi Obori  Toshinori Maebayashi  Satoshi Takeshima  Toshikazu Ebisuzaki  Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1073-1083

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.  相似文献