Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Study of the flood control scheduling scheme for the Three Gorges Reservoir in a catastrophic flood          下载免费PDF全文

Shanghong Zhang  Zhu Jing  Wenda Li  Yujun Yi  Yong Zhao 《水文研究》2018,32(11):1625-1634

The Three Gorges Project is the world's largest water conservancy project. According to the design standards for the 1,000‐year flood, flood diversion areas in the Jingjiang reach of the Yangtze River must be utilized to ensure the safety of the Jingjiang area and the city of Wuhan. However, once these areas are used, the economic and life loss in these areas may be very great. Therefore, it is vital to reduce this loss by developing a scheme that reduces the use of the flood diversion areas through flood regulation by the Three Gorges Reservoir (TGR), under the premise of ensuring the safety of the Three Gorges Dam. For a 1,000‐year flood on the basis of a highly destructive flood in 1954, this paper evaluates scheduling schemes in which flood diversion areas are or are not used. The schemes are simulated based on 2.5‐m resolution reservoir topography and an optimized model of dynamic capacity flood regulation. The simulation results show the following. (a) In accord with the normal flood‐control regulation discharge, the maximum water level above the dam should be not more than 175 m, which ensures the safety of the dam and reservoir area. However, it is necessary to utilize the flood diversion areas within the Jingjiang area, and flood discharge can reach 2.81 billion m³. (b) In the case of relying on the TGR to impound floodwaters independently rather than using the flood diversion areas, the maximum water level above the dam reaches 177.35 m, which is less than the flood check level of 180.4 m to ensure the safety of the Three Gorges Dam. The average increase of the TGR water level in the Chongqing area is not more than 0.11 m, which indicates no significant effect on the upstream reservoir area. Comparing the various scheduling schemes, when the flood diversion areas are not used, it is believed that the TGR can execute safe flood control for a 1,000‐year flood, thereby greatly reducing flood damage.  相似文献   

γ射线暴的logN(>P)～logP分布     

吴枚  宋黎明  余文飞  李惕碚  李毅 《中国天文和天体物理学报》1997,(1)

本文用简单的宇宙学模型 ,在标准烛光和均匀分布的假设下计算了γ射线暴的logN(>P)～logP分布 (大小谱 ) .在考虑了探测效率修正和死时间修正后 ,由宇宙学模型计算的理论结果和BATSE实测的大小谱没有显著的偏离  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

On penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere     

Zhong-Wei Hu  Yi Chu  Kai-Jun Zhang 《Earth, Moon, and Planets》1996,73(2):147-155

The actual penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere is still an open question. From fundamental equations of meteoric physics with variable cross-section, a new analytic model of energy release of the fragments is presented. In use of reasonable parameters, a series of results are calculated for different initial mass of the fragments. The results show that the largest fragment explodes above pressure levels of 3 bars and does not penetrate into the H₂O cloud layer of the Jovian atmosphere, and that airburst of smaller fragments occur even above the upper cloud layer.  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

First Post-Newtonian Angular Momentum In Relativistic Celestial Mechanics     

Jin-He Tao  Tian-Yi Huang  Zhao-Hua Yi 《Astrophysics and Space Science》1997,254(2):173-186

With a new theory on the 1PN celestial mechanics recently developed by Damour, Soffel and Xu (1991,1992,1993,1994), definitions and expressions of the 1PN spin angular momentum are investigated and analysed. The total spin angular momentum of a system of extended bodies such as the solar system is calculated and expressed as the function of local parameters and observables under reasonable assumptions, which would find its application in the evolution and dynamics of systems of celestial bodies. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献   

成都及附近地区旅游气候资源研究   总被引：9，自引：0，他引：9  

胡毅  朱克云  江毓忠 《成都信息工程学院学报》2001,16(4):237-242

通过对成都及附近等7个地区多年气候资源及人体舒适指数进行分级比较，得出了7个地区的人体舒适指数的时间分布特征及对当地旅游的影响。  相似文献   

Remarks on dynamical ellipticity at the Earth's     

C. Z. Zhang  Y. F. Xia 《Earth, Moon, and Planets》1994,65(3):269-276

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.  相似文献