邻菲啰啉在测定亚铁中的保护效果          下载免费PDF全文

张会堂  刘瑄  刘渝燕  刘晶  巩宝珍 《山东国土资源》2003,19(1):54-56

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果  相似文献   

AR（P）参数估计协方差方法与其改进型方法的对比研究     

楚岩  祝轩 《地球科学与环境学报》1997,(Z1)

定性分析协方差方法及其改进型在ＡＲ（Ｐ）参数估计中的应用，提供了一种估计参数的计算机上机流程图，比较了协方差方法及其改进型谱估计结果。  相似文献   

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

基于专家系统决策的多模式控制及其应用     

宣森 《广东海洋大学学报》1993,(1)

将专家系统技术与常规控制、模糊控制、超前控制、仿人智能操作控制以及计算机控制技术相结合,设计了一种新的基于专家系统决策的多模式控制(MCDBES)。经试验和实际运行结果表明,MCDBES系统对未知数学模型的被控对象,具有良好的控制性能。本文提出的MCDBES已成功地应用于燃油陶瓷窑炉计算机控制系统。  相似文献   

Plant distribution at the mobile dune scale and its relevance to soil properties and topographic features     

Xiaoan Zuo  Halin Zhao  Xueyong Zhao  Yirui Guo  Yulin Li  Yayong Luo 《Environmental Geology》2008,54(5):1111-1120

A survey was conducted in an 11-year recovery mobile dune (RMD11) and a 20-year recovery mobile dune (RMD20), in Horqin Sandy Land, Northern China, to determine plant distribution at the mobile dune scale and its relevance to soil properties and topographic features. The results showed that (1) vegetation cover and species number increased from dune top to bottom in the restoration process of mobile dune; (2) the average value of soil organic C, total N, pH, relative height of sampling site, very fine sand content and soil water contents (40−60 and 60−80 cm) of RMD11 were less than that of RMD20, respectively, and there were significant differences (P < 0.05) between the two dunes; (3) soil resources were redistributed by shrub restoration and relative height of sampling site on dune. The distribution of sand pioneer plant, Agriophyllum squarrosum, was positively related to the relative height of sampling site and soil water content, while that of other herbaceous plants was positively related to soil nutrients in the restoration process of mobile dune. These results suggest that at mobile dune scale, plant distributions are determined by a combination of soil properties and topographic feature. Much effort should be made to preserve the interdune lowland and to improve the level of soil nutrients on mobile dune.  相似文献   

太平洋海域海平面变化的灰色系统分析   总被引：3，自引：1，他引：3  

左军成  陈宗镛  戚建华 《中国海洋大学学报(自然科学版)》1997,(2)

应用灰色系统理论，对太平洋海域４８个长期验潮站的月均海平面分别建立了ＧＭ（１，１）模型。ＧＭ（１，１）模型能较好地反映太平洋海域的海平面变化的趋势，它除了能给出连续的海平面变化速率外，同时能方便地给出海平面变化的加速率。模拟结果表明，在太平洋地壳均衡假设下，太平洋海域的月均海平面以平均速率０．１７ｃｍ／ａ上升。在太平洋海域所取的４８个长期验潮站中，有４０个站在加速上升，全部站的平均加速度为０．０００２９ｃｍ／ａ２。且加速率逐渐增大。当然这些加速率都很小，但作为一种普遍性的趋势，这已足以说明：太平洋海域的海平面在加速上升  相似文献   

Influence of Approach Channel on Wave Propagation with Varying Incident Angles     

Zuo Qihua  Yang Zhengji . Senior Engieer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing 《中国海洋工程》1996,(3)

- The variation of the amplitude of waves with varying incident angles when waves propagate through a typical approach channel is discussed by a numerical calculation method, the result of which shows that the influence of the channel on wave propagation is obvious. When the wave propagation direction is in coincidence with the channel axis, the wave amplitude ratio will decrease with the increase of propagation distance. When the incident angle is 15 - 30 , there appears an area of larger wave amplitude ratio on the side slope facing the waves, but at the another side, the wave amplitude ratio is generally small, indicating that the channel has a shielding effect. When waves propagate across the channel perpendicularly, the wave amplitude ratio can be calculated with the shallow water coefficient.  相似文献   

Biodiversity of meiofauna in the intertidal khe nhan mudflat,can gio mangrove forest,vietnam with special emphasis on free living nematodes     

Quang Ngo Xuan  Ann Vanreusel  Nguyen Vu Thanh  Nic Smol 《Ocean Science Journal》2007,42(3):135-152

The ecological aspect of meiofaunal communities in Can Gio mangrove forest, Ho Chi Minh city, Vietnam has not been investigated before. The composition, distribution, density and biodiversity of meiofaunal communities were studied along an intertidal transect at the Khe Nhan mudflat. Each time, three replicate samples were collected in four stations along a transect following the water line from low tide level up to the mangrove forest edge. In total, 18 meiofaunal taxa were found with the dominant taxa belonging to Nematoda, Copepoda, Sarcomastigophora and Polychaeta. The densities of meiofauna ranged from 1156 inds/10 cm² to 2082 inds/10 cm². The increase in densities from the mangrove forest edge towards the low water line was significant. Along the mudflat transect, the biodiversity (expressed by different indices) was relatively high at different taxonomic levels but did not vary significantly along the mudflat except for taxa richness. Eighty nematode genera belonging to 24 families with Comesomatidae having the highest abundance 33.8 % were found.Theristus andNeochromadora decreased in densities from the lower water line towards the mangrove forest edge, whileParacomesoma andHopperia are typical and more abundant at the middle of the mudflat.Halalaimus increased from high on the mudflat to the low water line.  相似文献   

Influence of air-sea interaction on SSTA in different spacial scales     

Sun Jilin  Zuo Zhongdao 《海洋学报(英文版)》1990,9(2):203-217

-In this paper, the factors for SSTA development in finite sea area of low latitudes are discussed with simpler linearized equations, According to the coupling conditions at the interface of atmosphere and ocean, we studied the horizontal scale relations of air-sea coupled system satisfying the dynamical and thermodynamical requirements, From the fluctuation viewpoint, the relation of horizontal scales and wave numbers are presented for a linear atmosphere-ocean coupled system with the same time scales. At last part of the paper, the state of fluctuations is examined for different sea scales under certain given atmospheric scale with a simpler two-layer coupled model, and some significant results obtained.  相似文献   

Effects of Irregular Wave Groups on Pile Forces     

Yang Zhengji Zuo Qihua Senior Engineer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing Engineer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing 《中国海洋工程》1991,(2)

The wave forces on 1, 2 and 4 vertical circular piles under the action of several wave trains of the same wave parameters, such as Hs,Tp and Mo, but different wave group factor GF are measured in the laboratory. After comparing these forces, it may be concluded that the mean and significant wave forces are almost of no difference for the wave trains with different GF. When GF is larger, the one-tenth of the wave froce extreme is slightly increased and the maximum wave force is much larger than the ones with smaller GF, to which attention must be paid in engineering practice.  相似文献