SWAS observations of water vapor in the Venus mesosphere     

Mark A. Gurwell  Gary J. Melnick  Edwin A. Bergin 《Icarus》2007,188(2):288-304

We present the first detections of the ground-state H₂¹⁶O (₁₁₀-₁₀₁) rotational transition (at 556.9 GHz) and the ¹³CO (5-4) rotational transition from the atmosphere of Venus, measured with the Submillimeter Wave Astronomy Satellite (SWAS). The observed spectral features of these submillimeter transitions originate primarily from the 70-100 km altitude range, within the Venus mesosphere. Observations were obtained in December 2002, and January, March, and July 2004, coarsely sampling one Venus diurnal period as seen from Earth. The measured water vapor absorption line depth shows large variability among the four observing periods, with strong detections of the line in December 2002 and July 2004, and no detections in January and March 2004. Retrieval of atmospheric parameters was performed using a multi-transition inversion algorithm, combining simultaneous retrievals of temperature, carbon monoxide, and water profiles under imposed constraints. Analysis of the SWAS spectra resulted in measurements or upper limits for the globally averaged mesospheric water vapor abundance for each of the four observation periods, finding variability over at least two orders of magnitude. The results are consistent with both temporal and diurnal variability, but with short-term fluctuations clearly dominating. These results are fully consistent with the long-term study of mesospheric water vapor from millimeter and submillimeter observations of HDO [Sandor, B.J., Clancy, R.T., 2005. Icarus 177, 129-143]. The December 2002 observations detected very rapid change in the mesospheric water abundance. Over five days, a deep water absorption feature consistent with a water vapor abundance of 4.5±1.5 parts per million suddenly gave way to a significantly shallower absorption, implying a decrease in the water vapor abundance by a factor of nearly 50 in less that 48 h. In 2004, similar changes in the water vapor abundance were measured between the March and July SWAS observing periods, but variability on time scales of less than a week was not detected. The mesospheric water vapor is expected to be in equilibrium with aerosol particles, primarily composed of concentrated sulfuric acid, in the upper haze layers of the Venus atmosphere. If true, moderate amplitude (10-15 K) variability in mesospheric temperature, previously noted in millimeter spectroscopy observations of Venus, can explain the rapid water vapor variability detected by SWAS.  相似文献   

Utilizing Natural Liner Materials for Heavy Metal Removal in Simulated Landfill Conditions     

Nurdan Gamze Turan  E. Beril Gümüşel 《洁净——土壤、空气、水》2013,41(4):403-410

Inorganic industrial waste landfills have the potential to contaminate subsurface groundwater supplies through migration of leachates down to the water table and into groundwater aquifers, despite the use of compacted low permeability clay or polyethene liners. This paper aims the removal of Cu²⁺ and Zn²⁺ in the leachate from an industrial waste landfill using natural materials (natural zeolite, expanded vermiculite, pumice, illite, kaolinite, and bentonite) as a liner material. Cu²⁺ and Zn²⁺ concentrations for all treatments decreased during the process. Of all the different natural materials, natural zeolite, expanded vermiculite and pumice, with bentonite, were effective in removing Cu²⁺ and Zn²⁺ present in the leachate. However, the use of illite and kaolinite with bentonite as liner materials could be of disadvantage in Cu²⁺ and Zn²⁺ removal from leachate. The adsorption kinetic models were also tested for the validity. The second order kinetics with the high correlation coefficients best described adsorption kinetic data.  相似文献   

Spectroscopic Observations of Comet C/1996 B2 (Hyakutake) with the Caltech Submillimeter Observatory     

D.C. Lis  J. Keene  K. Young  T.G. Phillips  D. Bockelée-Morvan  J. Crovisier  P. Schilke  P.F. Goldsmith  E.A. Bergin 《Icarus》1997,130(2):355-372

The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H¹³CN, HNC, HNCO, CO, CH₃OH, and H₂CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H¹³CN (4–3) and HNCO (16_0,16–15_0,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H¹³CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System¹²C/¹³C ratio. The low HCN/H¹³CN abundance ratio may be in part due to contamination by an SO₂line blended with the H¹³CN (4–3) line. In addition, chemical models suggest that the HCN/H¹³CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H¹³CN ratio observed in a comet is not inconsistent with the solar system¹²C/¹³C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10⁻⁴. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H₂CO, and CH₃OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H₂CO emission suggests production of this species from dust grains.  相似文献   

Water and related chemistry in the solar system. A guaranteed time key programme for Herschel     

P. Hartogh  E. Lellouch  M. Banaszkiewicz  E.A. Bergin  N. Biver  M.I. Blecka  D. Bockelée-Morvan  J. Cernicharo  G. Davis  P. Encrenaz  A. González  T. de Graauw  D. Hutsemékers  E. Jehin  M. Kidger  A. de Lange  D.C. Lis  J. Manfroid  R. Moreno  G. Orton  M. Rengel  M. Sánchez-Portal  S. Sidher  B. Swinyard  N. Thomas  B. Vandenbussche  C. Waelkens 《Planetary and Space Science》2009,57(13):1596-1606

“Water and related chemistry in the Solar System” is a Herschel Space Observatory Guaranteed-Time Key Programme. This project, approved by the European Space Agency, aims at determining the distribution, the evolution and the origin of water in Mars, the outer planets, Titan, Enceladus and the comets. It addresses the broad topic of water and its isotopologues in planetary and cometary atmospheres. The nature of cometary activity and the thermodynamics of cometary comae will be investigated by studying water excitation in a sample of comets. The D/H ratio, the key parameter for constraining the origin and evolution of Solar System species, will be measured for the first time in a Jupiter-family comet. A comparison with existing and new measurements of D/H in Oort-cloud comets will constrain the composition of pre-solar cometary grains and possibly the dynamics of the protosolar nebula. New measurements of D/H in giant planets, similarly constraining the composition of proto-planetary ices, will be obtained. The D/H and other isotopic ratios, diagnostic of Mars’ atmosphere evolution, will be accurately measured in H₂O and CO. The role of water vapor in Mars’ atmospheric chemistry will be studied by monitoring vertical profiles of H₂O and HDO and by searching for several other species (and CO and H₂O isotopes). A detailed study of the source of water in the upper atmosphere of the Giant Planets and Titan will be performed. By monitoring the water abundance, vertical profile, and input fluxes in the various objects, and when possible with the help of mapping observations, we will discriminate between the possible sources of water in the outer planets (interplanetary dust particles, cometary impacts, and local sources). In addition to these inter-connected objectives, serendipitous searches will enhance our knowledge of the composition of planetary and cometary atmospheres.  相似文献   

Timescales for the evolution of oxygen isotope compositions in the solar nebula     

J.R. Lyons  E.A. Bergin  A.M. Davis  K. Hashizume 《Geochimica et cosmochimica acta》2009,73(17):4998-6266

We review two models for the origin of the calcium-, aluminum-rich inclusion (CAI) oxygen isotope mixing line in the solar nebula: (1) CO self-shielding, and (2) chemical mass-independent fractionation (MIF). We consider the timescales associated with formation of an isotopically anomalous water reservoir derived from CO self-shielding, and also the vertical and radial transport timescales of gas and solids in the nebula. The timescales for chemical MIF are very rapid. CO self-shielding models predict that the Sun has Δ¹⁷O_SMOW ∼ −20‰ (Clayton, 2002), and chemical mass-independent fractionation models predict Δ¹⁷O_SMOW ∼0‰. Preliminary Genesis results have been reported by McKeegan et al. (McKeegan K. D., Coath C. D., Heber, V., Jarzebinski G., Kallio A. P., Kunihiro T., Mao P. H. and Burnett D. S. (2008b) The oxygen isotopic composition of captured solar wind: first results from the Genesis. EOS Trans. AGU 89(53), Fall Meet. Suppl., P42A-07 (abstr)) and yield a Δ¹⁷O_SMOW of ∼ −25‰, consistent with a CO self-shielding scenario. Assuming that subsequent Genesis analyses support the preliminary results, it then remains to determine the relative contributions of CO self-shielding from the X-point, the surface of the solar nebula and the parent molecular cloud.The relative formation ages of chondritic components can be related to several timescales in the self-shielding theories. Most importantly the age difference of ∼1-3 My between CAIs and chondrules is consistent with radial transport from the outer solar nebula (>10 AU) to the meteorite-forming region, which supports both the nebular surface and parent cloud self-shielding scenarios. An elevated radiation field intensity is predicted by the surface shielding model, and yields substantial CO photolysis (∼50%) on timescales of 0.1-1 My. An elevated radiation field is also consistent with the parent cloud model. The elevated radiation intensities may indicate solar nebula birth in a medium to large cluster, and may be consistent with the injection of ⁶⁰Fe from a nearby supernova and with the photoevaporative truncation of the solar nebula at KBO orbital distances (∼47 AU). CO self-shielding is operative at the X-point even when H₂ absorption is included, but it is not yet clear whether the self-shielding signature can be imparted to silicates. A simple analysis of diffusion times shows that oxygen isotope exchange between ¹⁶O-depleted nebular H₂O and chondrules during chondrule formation events is rapid (∼minutes), but is also expected to be rapid for most components of CAIs, with the exception of spinel. This is consistent with the observation that spinel grains are often the most ¹⁶O-rich component of CAIs, but is only broadly consistent with the greater degree of exchange in other CAI components. Preliminary disk model calculations of self-shielding by N₂ demonstrate that large δ¹⁵N enrichments (∼ +800‰) are possible in HCN formed by reaction of N atoms with organic radicals (e.g., CH₂), which may account for ¹⁵N-rich hotspots observed in lithic clasts in some carbonaceous chondrites and which lends support to the CO self-shielding model for oxygen isotopes.  相似文献   

Observation of water vapor in the stratosphere of Jupiter with the Odin space telescope     

T. Cavalié  F. Billebaud  M. Dobrijevic  J. Brillet  Å. Hjalmarson  U. Frisk  E.A. Bergin  The Odin Team 《Planetary and Space Science》2008,56(12):1573-1584

The water vapor line at 557 GHz has been observed with the Odin space telescope with a high signal-to-noise ratio and a high spectral resolution on November 8, 2002. The analysis of this observation as well as a re-analysis of previously published observations obtained with the submillimeter wavelength astronomy satellite seem to favor a cometary origin (Shoemaker-Levy 9) for water in the stratosphere of Jupiter, in agreement with the ISO observation results. Our model predicts that the water line should become fainter and broader from 2007. The observation of such a temporal variability would be contradictory with an IDP steady flux, thus supporting the SL9 source hypothesis.  相似文献   

Mars surface and atmospheric temperature during the 2001 global dust storm     

Mark A. Gurwell  Edwin A. Bergin  Volker Tolls 《Icarus》2005,175(1):23-31

The dramatic growth and evolution of the 2001 martian global dust storm were captured using the Submillimeter Wave Astronomy Satellite (SWAS). While the lower and middle atmosphere (pressures greater than 50 μbar, up to ∼45 km altitude) showed rapid heating of up to 40 K, the average surface brightness temperature plummeted by ∼20 K at the peak of the storm. The storm appears to have had little impact on the global temperature structure at altitudes above ∼ 10 μbar (∼ 60 km).  相似文献   

The HNC/HCN Ratio in Comets     

Irvine  W. M.  Dickens  J. E.  Lovell  A. J.  Schloerb  F. P.  Senay  M.  Bergin  E. A.  Jewitt  D.  Matthews  H. E. 《Earth, Moon, and Planets》1997,78(1-3):29-35

The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4−3 rotational transitions of both species for heliocentric distances 0.93 < r < 3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced insignificant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Hco+ in the Coma of Comet Hale–Bopp     

Lovell  A. J.  Schloerb  F. P.  Bergin  E. A.  Dickens  J. E.  Devries  C. H.  Senay  M. C.  Irvine  W. M. 《Earth, Moon, and Planets》1997,77(3):253-258

Maps of comet C/1995 O1 (Hale-Bopp) in the millimeter-wave emission of the ion HCO⁺ revealed a local minimum near the nucleus position, with a maximum about 100,000 km in the antisolar direction. These observed features of the HCO⁺ emission require a low abundance of HCO⁺ due to enhanced destruction in the inner coma of the comet, within a region of low electron temperature (T_e). To set constraints on the formation of HCO⁺ in the coma, as well as the location and magnitude of the transition to higher T_e, the data are compared with the results of ion-molecule chemistry models. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The Class 0 source Barnard 1c     

Brenda Matthews  Edwin Bergin  Antonio Crapsi  Michiel Hogerheijde  Jes Jørgensen  Dan Marrone  Ramprasand Rao 《Astrophysics and Space Science》2008,313(1-3):65-68

We present our most recent results from an ongoing study of the Class 0 source Barnard 1c in Perseus. This source is of particular interest because it exhibits evidence of strong alignment of grains all the way to the core’s centre, which is contrary to all other low-mass protostellar cores observed to date. Our goal is to clarify the source of poor alignment in other sources by identifying the source of strong alignment in B1c. A central cavity has been identified in N₂H⁺ emission; its anticorrelation with C¹⁸O emission suggests that heating in the centre has released CO from grain mantles, in turn destroying N₂H⁺. We present sensitivity-limited, high spatial resolution polarimetry data from the SubMillimeter Array and discuss the potential implications of these data.  相似文献