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Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.  相似文献   
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The blue crab,Callinectes sapidus, is an abundant and widely distributed species in the Chesapeake Bay. It also supports a valuable fishery. Minimal information concerning concentrations of toxic organic compounds in crustaceans of the southern Chesapeake Bay is currently available. As a consequence, a study to determine the tissue burdens and behavior of lipophilic polycylic aromatic compounds (PACs) in these organisms was undertaken. Highest concentrations of PACs were detected in hepatopancreas, followed by ovarian and muscle tissues. Extractable lipid levels in the tissues were positively correlated with organic xenobiotic concentrations. The major contaminants detected in blue crabs sampled from the southern bay were alkylated PACs, as opposed to unsubstituted polynuclear aromatic hydrocarbons which have been reported to predominate in molluscs and sediments of the bay. This dichotomy may be due to differences in contaminant bioavailability or in the relative abilities of the organisms to eliminate xenobiotics. Crabs from both heavily industrialized and relatively undeveloped areas, showed evidence of exposure. These data suggest that localized areas of contamination and episodic contaminant releases may result in xenobiotic body burdens in mobile/migratory species. Crabs acutely exposed to radiolabeled benzo(a)pyrene in the laboratory were capable of rapid bioaccumulation. After transfer to clean water, the organisms efficiently eliminated this material, although at a rate slower than that observed for accumulation. Evidence that ecdysis in crustaceans may affect the disposition of PACs was also witnessed in these experiments. Differences in tissue concentrations of benzo(a)pyrene derived material were observed between crabs of various sex, maturity, and molt stages.  相似文献   
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Paleointensity measurements have been carried out on 3.5 Ga samples from the Komati Formation type locality using both the Thellier and Van Zijl methods. These samples contain a single steeply-directed negative TRM component acquired during metamorphism of the Komati lavas. Thellier experiments yielded values ranging from 12 to 37 μT but an average paleofield intensity for the four best determinations is 20 ± 3 μT. A slightly lower average paleointensity of 15 ± 3 μT was obtained using Van Zijl experiments. Preheating was used to chemically stabilize seven samples used in Van Zijl determinations and these produced nearly ideal plots with an average paleointensity of 13 ± 2 μT. A single basaltic komatiite sample gave a nearly ideal Van Zijl plot indicating about 21 μT, nearly the same paleointensity as the peridotitic komatiite samples even though its NRM intensity was several orders of magnitude lower. Since the Komati characteristic remanence was acquired during a slow cooling, the data must be reduced by a factor of 1.55 to account for the difference between laboratory and natural cooling rates. Calculation of an equivalent equatorial paleointensity using the paleolatitude implied by the steep Komati characteristic remanence then gives value of 5 μT for the intensity of the geomagnetic field at 3.5 Ga, lower than the present value of about 30 μT.  相似文献   
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Mussels, Mytilus trossulus (average shell length 43+/-0.8 mm), were sampled from a beach in Alaska that received untreated sewage for several years, a second beach adjacent to a secondary wastewater outfall, and two nearby reference beaches. Survival time in air, byssal thread production rate, and prevalence of trematode parasites were determined for each group. Tolerances to aerial exposure was significantly lower (P<0.05) at both sewage outfall sites than at the reference sites. Mussels exposed to untreated sewage produced fewer byssal threads and had a significantly higher prevalence of encysted trematodes than mussels from the other beaches, including the secondary wastewater site. Survival in air, byssal thread production, and trematode prevalence in mussels may be useful indicators in evaluating the longterm health of beaches exposed to sewage.  相似文献   
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In this paper, we describe new fuzzy models for predictive mineral potential mapping: (1) a knowledge-driven fuzzy model that uses a logistic membership function for deriving fuzzy membership values of input evidential maps and (2) a data-driven model, which uses a piecewise linear function based on quantified spatial associations between a set of evidential evidence features and a set of known mineral deposits for deriving fuzzy membership values of input evidential maps. We also describe a graphical defuzzification procedure for the interpretation of output fuzzy favorability maps. The models are demonstrated for mapping base metal deposit potential in an area in the south-central part of the Aravalli metallogenic province in the state of Rajasthan, western India. The data-driven and knowledge-driven models described in this paper predict potentially mineralized zones, which occupy less than 10% of the study area and contain at least 83% of the model and validation base metal deposits. A cross-validation of the favorability map derived from using one of the models with the favorability map derived from using the other model indicates a remarkable similarity in their results. Both models therefore are useful for predicting favorable zones to guide further exploration work.  相似文献   
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The potential applications of As, Sb and Bi as pathfinder elements in geochemical exploration have been researched using a new, rapid technique for the simultaneous determination of the three elements. Following a warm hydrochloric acid sample leach, the volatile hydrides of the elements are generated and flushed into an inductively-coupled plasma linked to an emission spectrometer. The technique offers a combination of good analytical precision and detection limits of 100 ppb for each of the elements.The principal sulphide ore minerals commonly contain traces of As, Sb and Bi, and concentrations of more than 1% of any one of these have been found in some sulphide specimens. During sub-aerial oxidation of sulphides, any As, Sb and Bi present is released and forms dispersion patterns in the surficial environment. Geochemical surveys of localities in the United Kingdom have demonstrated that anomalous dispersion trains of these elements can be detected in the sediments of streams draining the mineralized localities. In a geochemical mapping programme covering 16,000 km2 of central Nepal, over 3500 stream sediment samples were analyzed for As, Sb and Bi, and many known occurrences of Cu, Pb and Zn mineralization are reflected by As, Sb and Bi anomalies. However, bedrock lithology appears to be an important factor influencing Sb and Bi dispersion patterns.In the areas studied, some or all of the elements As, Sb and Bi produce stream sediment anomalies that compare favourably in terms of contrast and extent with the heavy metal expressions, even though none of the three elements have been reported as important constituents of the mineralization with which they occur.  相似文献   
10.
位于西天山别珍套-科古琴晚古生代岛弧西段的喇嘛苏铜矿床是区内最大的铜矿床,与成矿作用有着密切关系的斑岩体为英云闪长斑岩、花岗闪长斑岩,是同源岩浆分异演化的产物,且花岗闪长斑岩可能属于岩浆演化晚期的产物。本区成矿斑岩的主量、微量元素和Sr-Nd同位素地球化学特征表明,其富集大离子亲石元素,而相对亏损高场强元素,出现了较为明显的Ta、Nb负异常,初始锶同位素ISr和εNd(t=390Ma)值分别为0.7072~0.7076和-0.32~0.17,显示壳幔混合源的特征,利用Sr和Nd同位素估算其源区物质约有50%来源于地壳。岩石地球化学特征指示了其为典型钙碱性火山弧花岗岩,暗示其形成于大陆弧环境。结合区域地质背景,推测本区成矿斑岩是在洋壳俯冲作用下发生部分熔融,交代原先的地幔楔,并混合了部分下地壳的物质,经历分离结晶作用的产物,其形成可能与晚古生代准噶尔洋板块向南的俯冲作用有关。结合东西天山的成矿斑岩的地球化学特征对比研究,岩浆源区的差别可能导致不同类型斑岩型矿床的形成,斑岩型铜矿床的形成较斑岩型钼矿床可能有更少的地壳物质贡献。  相似文献   
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