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1.
Cathleen E. McGinnis Jinesh C. Jain Clive R. Neal 《Geostandards and Geoanalytical Research》1997,21(2):289-305
High sensitivity and low detection limits would seem to make inductively coupled plasma-mass spectrometry (ICP-MS) an ideal analytical tool for determining low (sub-μg g-1 ) concentrations of the rare earth elements (REE), Y, Zr, Nb, Hf, Ta, Sn, W, Mo, Th, and U in most mafic materials (e.g. Hall and Plant 1992). However, the generally "sticky" nature exhibited by most of the high field strength elements (HFSEs: Zr, Nb, Hf, Ta, Th and U) as well as Sn, W and Mo can result in spurious results due to memory effects transmitted between unknowns and calibration samples. This, in turn, can seriously compromise the sensitivity, accuracy, and precision of ICP-MS analyses for these elements in geological materials. Data resulting from analyses with poor accuracy and precision can lead to erroneous interpretation and misleading petrogenetic modelling. To resolve this problem, we propose an effective wash protocol for these critical trace elements. 相似文献
2.
David L. McGinnis 《The Professional geographer》1997,49(1):117-125
This study develops observed climate-based downscaling transfer functions that are used with general circulation model (GCM) output to assess potential global-change impacts on Upper Colorado Plateau, USA, water resources. Daily automated snow water equivalent stations are used with 700 mb atmospheric circulation to determine empirical transfer functions. Downscaling methodologies using multiple regression and neural networks are evaluated, with the neural network results explaining approximately 70%of the daily snowfall variance. The neural network-based transfer functions are used with the GENESIS GCM to simulate snowfall characteristics in both a 1xCO2 and a 2xCO2 climate. While the total precipitation simulated by the 2xCO2 analysis remains nearly the same as today, less will fall as snow; specifically, snow water equivalence shows significant reduction (except in the Green River Basin) as the snow season is reduced by 58 days on average. 相似文献
3.
K. F. Tiampo J. B. Rundle W. Klein Y. Ben-Zion S. McGinnis 《Pure and Applied Geophysics》2004,161(9-10):1991-2003
— Earthquake fault systems are now thought to be an example of a complex nonlinear system (Bak, et al., 1987; Rundle and Klein, 1995). The spatial and temporal complexity of this system translates into a similar complexity in the surface expression of the underlying physics, including deformation and seismicity. Here we show that a new pattern dynamic methodology can be used to define a unique, finite set of deformation patterns for the Southern California Integrated GPS Network (SCIGN). Similar in nature to the empirical orthogonal functions historically employed in the analysis of atmospheric and oceanographic phenomena (Preisendorfer, 1988), the method derives the eigenvalues and eigenstates from the diagonalization of the correlation matrix using a Karhunen-Loeve expansion (KLE) (Fukunaga, 1970; Rundle et al., 2000; Tiampo et al., 2002). This KLE technique may be used to determine the important modes in both time and space for the southern California GPS data, modes that potentially include such time-dependent signals as plate velocities, viscoelasticity, and seasonal effects. Here we attempt to characterize several of the seasonal vertical signals on various spatial scales. These, in turn, can be used to better model geophysical signals of interest such as coseismic deformation, viscoelastic effects, and creep, as well as provide data assimilation and model verification for large-scale numerical simulations of southern California. 相似文献
4.
海拉尔盆地基底晚古生代adakite的发现及其地质意义 总被引：5，自引：1，他引：4
海拉尔盆地的前中生代基底隶属中亚造山带东段的兴蒙造山带。 在盆地基底地层中发现了具有adakite成分特征的粗面安山岩、英安岩和闪长玢岩。 这些火成岩与晚古生代沉积地层交互或伴生, 共同构成晚中生代裂陷盆地的基底。 地球化学研究表明, 这些火成岩基本上属于高钾钙碱性和准铝质岩石系列, 具有高SiO2和Al2O3含量, 高Sr、Sr/Y和La/Yb值, 富集轻稀土(LREE), 亏损重稀土(HREE)、Y和高场强元素(HFSE),Eu表现弱的负异常或轻微的正异常, 相容元素Mg、Cr和Ni含量低, 这些特征与增厚下地壳部分熔融成因的adakite非常相似, 而明显不同于典型的由俯冲洋壳熔融形成的adakite。 样品的(87Sr/86Sr)i值基本一致,为0.7041, (143Nd/144Nd)i值为0.51243~0.51247, εNd (t)为正值(+3.7~+4.5), 显示其岩浆源区可能源于弱亏损地幔, 或亏损地幔受到地壳物质混染。 本文认为海拉尔地区晚古生代adakite型岩浆很可能是由当时新底侵的玄武质下地壳在角闪岩相向榴辉岩相过度或榴辉岩相条件下部分熔融形成。 这些adakite岩石的出现反映了兴蒙造山带晚古生代受到了古亚洲洋的俯冲消减引起的强烈的地幔玄武质岩浆底侵作用, 并由此导致地壳垂向上显著的增生加厚过程。 相似文献
5.
Climate change projections of the North American Regional Climate Change Assessment Program (NARCCAP) 总被引：2，自引：1，他引：1
L. O. Mearns S. Sain L. R. Leung M. S. Bukovsky S. McGinnis S. Biner D. Caya R. W. Arritt W. Gutowski E. Takle M. Snyder R. G. Jones A. M. B. Nunes S. Tucker D. Herzmann L. McDaniel L. Sloan 《Climatic change》2013,120(4):965-975
We investigate major results of the NARCCAP multiple regional climate model (RCM) experiments driven by multiple global climate models (GCMs) regarding climate change for seasonal temperature and precipitation over North America. We focus on two major questions: How do the RCM simulated climate changes differ from those of the parent GCMs and thus affect our perception of climate change over North America, and how important are the relative contributions of RCMs and GCMs to the uncertainty (variance explained) for different seasons and variables? The RCMs tend to produce stronger climate changes for precipitation: larger increases in the northern part of the domain in winter and greater decreases across a swath of the central part in summer, compared to the four GCMs driving the regional models as well as to the full set of CMIP3 GCM results. We pose some possible process-level mechanisms for the difference in intensity of change, particularly for summer. Detailed process-level studies will be necessary to establish mechanisms and credibility of these results. The GCMs explain more variance for winter temperature and the RCMs for summer temperature. The same is true for precipitation patterns. Thus, we recommend that future RCM-GCM experiments over this region include a balanced number of GCMs and RCMs. 相似文献
6.
Since 1999, Ohio EPA hydrogeologists have used two analytic element models (AEMs), the proprietary software GFLOW and U.S. EPA's WhAEM, to delineate protection areas for 535 public water systems. Both models now use the GFLOW2001 solution engine, integrate well with Geographic Information System (GIS) technology, have a user-friendly graphical interface, are capable of simulating a variety of complex hydrogeologic settings, and do not rely upon a model grid. These features simplify the modeling process and enable AEMs to bridge the gap between existing simplistic delineation methods and more complex numerical models. Ohio EPA hydrogeologists demonstrated that WhAEM2000 and GFLOW2000 were capable of producing capture zones similar to more widely accepted models by applying the AEMs to eight sites that had been previously delineated using other methods. After the Ohio EPA delineated protection areas using AEMs, more simplistic delineation methods used by other states (volumetric equation and arbitrary fixed radii) were applied to the same water systems to compare the differences between various methods. GIS software and two-tailed paired t-tests were used to quantify the differences in protection areas and analyze the data. The results of this analysis demonstrate that AEMs typically produce significantly different protection areas than the most simplistic delineation methods, in terms of total area and shape. If the volumetric equation had been used instead of AEMs, Ohio would not have protected 265 km2 of critical upgradient area and would have overprotected 269 km2 of primarily downgradient land. Since an increasing number of land-use restrictions are being tied to drinking water protection areas, this analysis has broad policy implications. 相似文献
7.
Tectonic significance of syn-rift sediment packages across the Gabon-Cabinda continental margin 总被引：1，自引：0，他引：1
Garry D. Karner Neal W. Driscoll John P. McGinnis William D. Brumbaugh Nick R. Cameron 《Marine and Petroleum Geology》1997,14(7-8)
The tectonic development of a continental margin is recorded in the stratigraphic successions preserved along and across the margin in terms of stratal relationships (e.g., onlap, downlap, truncation), lithofacies, biostratigraphy, and paleo-water depths. By using these observations coupled to a kinematic and flexural model for the deformation of the lithosphere, we have elucidated the tectonic significance of the preserved stratigraphy that comprises the Gabon-Cabinda margin of west Africa. Two hinge zones, an Eastern and Atlantic, formed along the Gabon-Cabinda margin in response to three discrete extensional events occuring from Berriasian to Aptian time. The Eastern hinge zone demarcates the eastern limit of a broadly distributed Berriasian extension that resulted in the formation of deep anoxic, lacustrine systems as evidenced by the silts and shales of the Sialivakou and lower Djeno Formations and the regressive packages of the upper Djeno Formation. Approximately 1.5 to 2 km of asymmetric footwall uplift was induced across the Eastern hinge zone in response to the mechanical unloading of the lithosphere during this first phase of rifting. In contrast, the Atlantic hinge, located approximately 90 km west of the Eastern hinge, marks the eastern limit of a second phase of extension that began in the Hauterivian. Footwall uplift and rotation exposed earlier syn-rift and pre-rift sediments to at least wavebase causing varying amounts of erosional truncation across the Atlantic hinge zone along much of the Gabon-Cabinda margins. We interpret the thickness variations of reworked clastic sediment of this age (e.g. the Melania Formation) between the hinge zones as indicative of variations in the degree of uplift and erosional truncation of the Atlantic hinge. For example, the absence of Melania Formation across the Congo margin implies that uplift of the Atlantic hinge was relatively minor compared to that across the Cabinda and Gabon margins, the latter being characterized by significant thicknesses of Melania Formation (or equivalent). Material eroded from the Cabinda and Gabon Atlantic hinge zone may in part account for the thick wedge of sediment deposited seaward of the Gabon-Cabinda Atlantic hinge (the Erva Formation). Our modelling suggests that this wedge of reworked elastics represents deposition by along-axis gravity flows within a deep water (≈2 km) environment. A third and final phase of extension in the late Barremian-early Aptian was responsible for breaching the continental lithosphere to form the ocean/continent boundary and thus the installation of open marine conditions. Elsewhere, the environments will tend to be marginal marine to brackish, depending on the efficiency of the Atlantic hinge zone to act as a barrier to marine enchroachment. This third rift phase reactivated both the Eastern and Atlantic hinge0zones thereby creating accomodation for the Marnes Noires Formation (and equivalent) source rock deposition between the hinges and the Falcão source rock equivalent seaward of the Atlantic hinge. Two possible scenarios exist for the lateral distribution of the Marnes Noires Formation. If the reactivated rift flank topography across the Atlantic hinge was significant, then sedimentation would be restricted between the hinge zones within discrete lacustrine settings (e.g., Congo margin). Alternatively, if hinge zone uplift was relatively minor, then a coral-rimmed archipelago may have developed parallel to the margin with restricted communication across the Atlantic hinge zone (e.g., Cabinda margin). In this latter scenario, dilution of the Marnes Noires source rocks by terrigenous input from the eroding Atlantic hinge zone should be relatively minor thereby enhancing source rock quality. Furthermore, potential marine upwelling outboard of the Atlantic hinge zone is likely the cause for the production and accumulation of organic-rich material associated with the Falcão source rock of the Kwanza basin. By late Aptian time, the remaining accomodation between the hinge zones was partially filled by across- and along-axis prograding deltaic systems of the Argilles Vertes and Tchibota Formations. The progradation and interaction of the Argilles Vertes depositional lobes resulted in the formation of residual paleo-relief. Subsequent marine incursions and flooding of this paleo-relief led to the development of basal conglomerates (the Chela ‘lag’ unconformity) grading upward into fine-grained sands and evaporites. Consequently, an inverse relationship should exist betweeb evaporite thickness (in particular, the lower members) and the thickness of the underlying Argilles Vertes and Tchibota Formations. Variations in Loeme evaporite thickness is a consequence of stratigraphic and structural control with salt instability influencing local variability.Our modelling suggests the occurrence of two distinct evaporite sequences on the Congo margin, an earlier evaporite deposited seaward (west) of the Atlantic hinge during the second and third rift phases and the late Aptian Loeme Formation deposited between the hinge zones. An evaporite sequence seaward of the Atlantic hinge is inferred on the basis of extensive diapirs and salt tectonic structures observed in seismic data. In order to match the distribution and thickness of the observed post-salt stratigraphy across the basin, however, we require large paleowater depths west of the Atlantic hinge during the later Aptian. The existence of large paleowater depths precludes the formation of thick evaporite sequences within the outer basin. Consequently, we propose that the evaporites seaward of the Atlantic hinge were formed during the syn-rift development of the margin and are not contemporaneous with the post-rift Loeme salts deposited between the hinge zones. This double salt hypothesis is consistent with observations from the conjugate Brazilian margin. 相似文献
8.
Common-depth-point seismic reflection profiling indicates that the crust beneath western McMurdo Sound is capped by a thin veneer of layered reflectors. The absence of deep, layered reflectors suggests the crust beneath the coast is made up primarily of intrusions which we associate with plutons generated during the Ross Orogeny. The layered reflectors dip and thicken to the east, away from the coast, where they are found at two-way reflection times of 7 s, corresponding to depths of 14–16 km. Reflection data support earlier refraction, gravity, and magnetic interpretations that indicate fundamental differences in the crust beneath McMurdo Sound and the Transantarctic Mountains. Differences may be due to early Paleozoic subduction of the Ross Embayment crust beneath the Transantarctic Mountains during the Ross Orogeny. Orogeny has produced an over-thickened crust beneath the Ross orogenic belt which was followed by several periods of reactivation including the Jurassic thermal event and the uplift of the present-day Transantarctic Mountains in early Tertiary time. The presence of the McMurdo Volcanics and preliminary interpretations of reflection data suggest that the Sound is now being thinned by processes of extension. 相似文献
9.
K. F. Tiampo J. B. Rundle S. A. McGinnis W. Klein 《Pure and Applied Geophysics》2002,159(10):2429-2467
—Large, extended fault systems such as those in California demonstrate complex space-time seismicity patterns, which include repetitive events, precursory activity and quiescence, and aftershock sequences. Although the characteristics of these patterns can be qualitatively described, a systematic quantitative analysis remains elusive. Our research suggests that a new pattern dynamics methodology can be used to define a unique, finite set of seismicity patterns for a given fault system. In addition, while a long-sought goal of earthquake research has been the reliable forecasting of these events, very little progress has been made in developing a successful, consistent methodology. In this report, we document the discovery of systematic space-time variations in seismicity from southern California using a new technique. Here we present examples of this analysis technique on data obtained prior to events in seismically active areas that show coherent regions associated with the future occurrence of major earthquakes in the same areas. These results strongly support the hypothesis that seismic activity is highly correlated across many space and time scales within large volumes of the earth's crust. 相似文献
10.