Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

试论新世纪地理信息科学的发展   总被引：1，自引：0，他引：1  

黄雪樵  陈昱 《地球信息科学学报》2002,4(2):32-37

本文重点分析了当前国内外地理信息科学的形成与发展趋势和地理信息科学不断发展的历程 ,提出近期发展的前沿 ,以及当前地理信息产业化面临的一些重要问题。最后提出对地理信息科学发展的意见。  相似文献   

广西海洋资源概况及开发刍议     

傅中平  黄巧 《南方国土资源》2002,15(2):61-64

广西海洋资源丰富 ,品种繁多 ,为了更好开发 ,建议从法制、宣传教育、普及海洋资源有关知识 ,提高人们整体素质做起 ,进一步抓住机遇 ,合理开发 ,才能取得良好效益 ,达到预定目标  相似文献   

双酶法制备低黏度辛烯基琥珀酸淀粉钠的工艺条件   总被引：4，自引：0，他引：4  

阳元娥  罗发兴  黄强  谭伟 《广东海洋大学学报》2004,24(4):49-53

对双酶法制备用作微胶囊壁材的低黏度辛烯基琥珀酸淀粉钠的工艺路线与工艺条件进行了研究。正交实验结果表明 ,在酯化淀粉乳质量浓度 2 0 %、每 g淀粉α 淀粉酶的用量为 6SKBU的条件下 ,影响产品性能的各因素中 ,糖化酶的用量对产品的DE值和流度的影响最大 ,各因素的重要性依次是 :糖化酶的用量、糖化酶作用时间、α 淀粉酶保温作用时间。最佳工艺条件是 :α 淀粉酶保温作用时间 4min ,每 g淀粉糖化酶用量 0 .2GAU ,糖化酶作用时间 2 .5h ,此时产品的DE值为 30 ,流度为 80左右  相似文献   

小波分析理论在GPS技术中的应用     

ZHENG Zuoya HUANG Cheng LU Xiushan 《中国科学院上海天文台年刊》2003,(1)

在GPS数据处理中 ,存在着误差影响、影响波的干扰、周跳和数据量大等问题。误差影响和影响波的干扰实质是在接收卫星信号时受到其它因素的影响 ;周跳是由于卫星信号的失锁而造成信号的不连续 ;数据量大是因为GPS观测需要采样间隔小又连续观测所致。由于小波理论具有时频分析、波形分解、特征提取和快速小波变换等特性 ,应用小波变换和波形分解可以解决误差影响和影响波的干扰的问题 ;应用特征提取可以解决周跳检测问题 ;应用快速小波变换可进行数据压缩  相似文献   

试论企业组织结构--电子商务企业与传统企业的比较     

何兴贵  黄宗捷 《成都信息工程学院学报》2002,17(3):196-199

网络时代的到来，对传统企业的组织结构、运作模式、管理方法均提出了严峻的挑战。传统的企业组织结构是适应大工业生产而形成的等级组织结构形式，它有很大的局限性；电子商务企业的组织结构是适应网络社会而形成扁平化、双向多对多、以信息为基础的新型组织结构形式。电子商务企业以其组织结构扁平化和中空化，决策分散化，运作虚拟化，灵活高效为特点，它将成为传统企业在电子商务发展阶段变革的方向和目标。  相似文献   

差分法周跳探测与修复方法改进     

郑作亚  程宗颐  黄珹 《中国科学院上海天文台年刊》2004,(1)

在目前常用的周跳探测与修复方法基础上 ,提出了首先将观测资料按照观测历元不连续分成若干小弧段 ,然后利用差分法进行周跳探测 ,根据差分后周跳放大的特性判断周跳和野值 ,并确定其位置利用宽带组合和电离层组合的方法解算周跳大小。通过实例验证了其有效性。  相似文献   

Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction     

Megan FULLER  Yongsong HUANG 《Meteoritics & planetary science》2003,38(3):357-363

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.  相似文献   

贵州织金煤矿区龙潭组岩石特征及其意义     

陶述平  谭西德  黄昔容 《国土资源导刊(湖南)》2001,20(4):247-249

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.  相似文献   

广西森林旅游资源的特色及其开发意义     

傅中平  黄载环 《南方国土资源》2001,14(3):27-29

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。  相似文献