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1.
Algal pigments in sediments as a measure of eutrophication in the Baltic environment 总被引：2，自引：0，他引：2
Gra
yna Kowalewska 《Quaternary International》2005,130(1):141
A method of quantitative comparison of eutrophication of an area is proposed for the Baltic Sea, based on pigment content in sediments. The pigments concerned were chlorins a (i.e. chlorophylls a, b and selected chlorophyll a derivatives) and chlorophylls c. The analyses were performed on 300 samples from different layers of recent (0–10 cm) sediments, collected from about 50 stations, at different sites of the southern Baltic, including the estuaries of the two largest Polish rivers, in different seasons between 1992 and 2001, before and after the great flood of July 1997. The results are related to sampling site, sediment layer and hydrological conditions and also to organic carbon and Eh in sediments, oxygen and salinity in near-bottom waters. Depending on different chlorin a content in 0–1 and 0–10 cm layers, the sampling sites are classified into one of three groups: 1. Szczecin Lagoon and the Deep of Gda
sk stations (permanently eutrophic, chl a in 0–1 cm >40 nmol/g, Σchlns a in 0–1 in 0–10 cm layer, Σchlns aA in Σchlns a=55–65%), 2. Open sea stations (mesotrophic/oligotrophic, chl a in 0–1 cm <10 nmol/g, Σchlns a in 0–1 in 0–10 cm layer, Σchlns aA in Σchlns a 50%; and 3. Coastal stations (periodically eutrophic, chl a in 0–1 cm 10–40 nmol/g, Σchlns aA in Σchlns a 40%). The correlation coefficient between chlorophyll a and chlorophylls b and c indicates the classes of algae, which could be the main source of organic matter in the sediments. A high correlation with chlorophylls c is a marker of diatoms; a high correlation with chlorophyll b is a marker of green algae; and low correlation both with chlorophylls b and c—indicates a high blue–green algae input. 相似文献
2.
Schmidt H Bich Ha N Pfannkuche J Amann H Kronfeldt HD Kowalewska G 《Marine pollution bulletin》2004,49(3):229-234
The laboratory characterization of a field-operable surface-enhanced Raman scattering sensor (SERS optode) is presented for the detection of aromatic hydrocarbons in seawater. The sensor has been developed for deployment with a robust underwater spectrograph. To meet the demands of the harsh seawater application, sol-gel derived SERS substrates were used. The calibration curves of six PAHs were determined to be of Langmuir adsorption isotherm type with limits of detection ranging from the microg l(-1) to ng l(-1) level. The experimentally determined adsorption constants varied strongly with the molecular weight of the analytes and correlated with their solubility. A mixture of five PAHs dissolved in seawater was investigated to demonstrate the utility of this method for screening. Emphasis was put on the interference from suspended particulate matter (SPM). The Raman measurement with backscattering configuration was shown to be immune against turbidities up to 1000 NTU. The physico-chemical interference arising from adsorption by the sediment was measured on-line by adding sediment to a PAH-spiked solution. According to the calibration curve, the PAH concentration decrease corresponded to more than 98% of the analyte being scavenged by the sediment. 相似文献
3.
Robert Hodyss Paul V. Johnson Grazyna E. Orzechowska Jay D. Goguen Isik Kanik 《Icarus》2008,194(2):836-842
The mid-infrared spectra of mixed vapor deposited ices of CO2 and H2O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO2 segregating within the ice matrix into pure CO2 domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO2:H2O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO2 is observed. The kinetics of the segregation process is also examined. The segregation of the CO2 as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO2 on the icy bodies of the outer Solar System can be considered. 相似文献
4.
There are about 50 galactic planetary nebulae know to have [WR] type nuclei. We have compared their nebular properties with those of the other planetary nebulae in the Galaxy. We have found that the nebular morphological types are similarly distributed in the two groups. Bipolar nebulae constitute only 20% of the total in each group. The distribution of the nebular electron densities and abundance ratios N/O, He/H and C/O are the same in the two groups. The only marked difference is that nebular expansion velocities are larger in the group of planetary nebulae with [WR] central stars. We argue that the WR phenomenon does not preferentially occur in more massive central stars of planetary nebulae, contrary to what has been suggested in some former studies. We demonstrate that, for most of the observed [WR] type objects, the WR phenomenon cannot be triggered by a late helium shell flash event.The results of our investigation are published inAstronomy & Astrophysics
303, 893 (1995) and in the proceedings of the 2nd International Colloquium on Hydrogen-deficient Stars, C.S. Jeffery & U. Heber (eds), Astronomical Society of the Pacific Conference Series, Vol. 96, p. 209 (1996). 相似文献
5.
The Gulf of Gdańsk receives the waters of the Wis?a (Vistula), the largest Polish river and the second largest river flowing into the Baltic Sea. Chloropigments a (chlorophyll a and its derivatives) were determined in water and sediments from the Gulf. Samples were collected during cruises of R.V. 'Oceania' at 19 stations located at different water depths and distances from the shore, in May (2003) and October (2004), i.e., at the beginning and at the end of the growing season, respectively. Seawater was also sampled on the beach at Sopot in June, July and August 2004, i.e., during the height of the growing season. All water samples were collected with a bathometer and passed through Whatman GF/F filters. Recent sediments (0-10 cm) were collected with a core sampler and divided into sub-samples (0-1, 1-5 and 5-10 cm). The pigments were determined using HPLC-DAD. The results were first correlated with a set of parameters measured in situ during sample collection (salinity, temperature, oxygen content of seawater) and determined in the same material (organic carbon content, granulometry), then worked up statistically. Although this investigation shows that particular chloropigments a in recent sediments are indicative of the prevailing environmental conditions in the study area and the trends in their variations, they should be treated as a relative and not an absolute measure, since this is the first such study based on a large and coherent set containing both chloropigment a and environmental data. In addition, a chlorophyll a budget is estimated for the Gulf of Gdańsk on the basis of the literature and the authors' own data. Only c. 10% of the chlorophyll a produced annually in the Gulf of Gdańsk is transferred to sediments in the form of chloropigments a; 2.8% is in the form of undecomposed chlorophyll a and 7.2% in the form of chlorophyll a derivatives. About 90% of chlorophyll a is decomposed to colourless products. 相似文献
6.
This study summarizes the results of micropaleontological, sedimentological, and isotope geochemical analyses of cuttings from five deep wells drilled in the Great Salt Lake (Utah, USA). Spanning the last 5.0 million yrs, our environmental history of the Great Salt Lake distinguishes four intervals based on paleobiological and sedimentological characteristics, using a previously developed tephrochronology for age control. For most of its history, the Great Salt Lake Basin has been occupied by a mixture of marsh, shallow lacustrine and sand flat conditions. In contrast, open lake conditions, typical of the Bonneville cycles and the modern Great Salt Lake apparently have only dominated the basin for the past 0.6-0.8 Ma. The two main structural basins in the study area (the North and South Basins) experienced different lacustrine histories. Large but frequently saline lakes occupied the North Basin after about 0.6 Ma. In the South Basin, ephemeral, saline lacustrine conditions started at 2.1 Ma and developed to full lacustrine conditions at 0.3 Ma. Our paleoenvironmental interpretations are broadly consistent with the aquatic palynological records from the same wells, as well as with the prior core- and outcrop-based lines of evidence. However, the differences in lake history between the North and South Basin have not been previously recognized. 相似文献
7.
Li-Shan?HuangEmail authorView author&#;s OrcID profile Deborah?A.?Cory-Slechta Christopher?Cox Sally?W.?Thurston Conrad?F.?Shamlaye Gene?E.?Watson Edwin?van Wijngaarden Grazyna?Zareba J.?J.?Strain Gary?J.?Myers Philip?W.?Davidson 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(4):893-904
The Seychelles Child Development Study has been examining the relationship between prenatal methylmercury (MeHg) exposure from consuming fish during pregnancy and child development. This study re-analyzes seven outcomes in the 17 year Main Cohort data to determine if there are nonlinear or non-homogeneous (subgroup) associations that were not identified in the linear analysis. We adopted two statistical approaches. First, we carried out an additive nonlinear analysis assuming homogeneous prenatal MeHg-outcome relationships to explore overall associations. Second, we applied the regression tree to the Woodcock–Johnson Calculation subtest (it was significantly associated in earlier analyses) and identified 4 clusters based on covariates. Then we used additive models to assess the prenatal MeHg association in each of the four clusters for all seven outcomes. This approach assumes nonlinear associations in each cluster and non-homogeneous associations between clusters. The additive nonlinear analysis yielded prenatal MeHg curves similar to the linear analysis. For the regression tree analysis, the curves relating prenatal MeHg to outcomes between the 4 clusters differed and some crossed at higher prenatal MeHg levels, suggesting non-homogeneity in the upper range of exposure. Additionally, some of the curves suggested a possible non-linear relationship within the range of exposure we studied. This non-linear analysis supports the findings from the linear analysis. It shows little evidence to support an adverse association of prenatal MeHg exposure through maternal consumption of fish contaminated with natural background levels. However, the tree analysis suggests that the prenatal exposure/outcome relationship may not be homogeneous across all individuals and that some subpopulations may have an adverse association in the upper range of the exposures studied. More robust data in the higher levels of exposure in this cohort are needed to confirm this finding. 相似文献
8.
Grazyna E. Orzechowska Jay D. Goguen Paul V. Johnson Alexandre Tsapin Isik Kanik 《Icarus》2007,187(2):584-591
We report the rates of decomposition by ultraviolet (UV) photolysis of four amino acids in millimeter-thick crystalline water ice matrices at 100 K to constrain the survivability of these important organic molecules within ice lying near the surfaces of outer Solar System bodies. We UV-irradiated crystalline ice samples containing known concentrations of the amino acids glycine, aspartic acid, glutamic acid, and phenylalanine, then we measured the surviving concentrations using high performance liquid chromatography (HPLC) with fluorescence detection. From these experiments, we determine photolytic decomposition rates and half-lives. The half-life varies linearly with the ice thickness for all acids studied here. For example, glycine is the most resistant to photolytic destruction with a half-life of 50, 12, and 3.7 h in 1.6, 0.28, and 0.14 mm thick ices, respectively. We explain this linear variation of half-life with thickness as a consequence of extinction, mostly due to scattering, within these macroscopically thick ice samples. Applied to low latitude surface ice on Jupiter's satellite Europa, this analysis indicates that the concentration of any of these amino acids within the top meter of similar ice will be halved within a ∼10 year timescale. 相似文献
9.
Kowalewska G Konat-Stepowicz J Wawrzyniak-Wydrowska B Szymczak-Zyła M 《Marine pollution bulletin》2003,46(6):703-718
This paper describes the transfer of organic contaminants to the sea, using PAHs (12 compounds) and PCBs (11 congeners) as examples, through a eutrophicated coastal lagoon (Szczecin Lagoon, on the Polish-German border). The transfer of contaminants study was based on their concentration in recent sediments (0-10 cm), in relation to different environmental conditions such as temperature, salinity, turbidity, oxygen and nutrients in water, hydrological conditions, organic carbon and biomarkers (pigments and their derivatives) in sediments. Results include the data obtained between 1994 and 2000, also those on before and afterwards the great flood in July 1997, at different stations in the Lagoon and the adjacent Pomeranian Bay. The results indicated that the eutrophic estuary of the shape of lagoon acts as an effective trap for the hydrophobic organic pollutants. The abundance and taxonomy of plankton as well as detritus derived from it play an important role in bonding the studied compounds. The salinity gradient in the lagoon has a significant influence upon deposition of the pollutants from the water column to the sediments and the residence time of the compounds there depends strongly on oxic-anoxic status of the sediments and the strength of interaction with sediments resulting from polarity, the type and stability of associates formed, as well as on hydrological conditions. We conclude that eutrophication in this area prevents pollution of the sea to some extent. 相似文献
10.
Chlorophyll a and its selected derivatives, as well as chlorophylls b and c have been determined in samples of recent (0-10 cm) sediments, collected at 30 stations in the Szczecin Lagoon, Pomeranian Bay and the Bornholm Deep. Samples were retrieved in different seasons between 1992 and 2001, including the time before and after the great flood of July 1997. Regarding the content of chlorophyll a and its derivatives in sediments, the Szczecin Lagoon may be classified as permanently eutrophic and the Pomeranian Bay and Bornholm Deep as mesotrophic. A lack of correlation between chlorophylls b, c and chlorophyll a indicated that intensive blooms of cyanobacteria occur in the Szczecin Lagoon, which is a characteristic of eutrophic zones. The chlorin a results are related to selected parameters characterizing the aquatic environment. The values for nutrients, salinity and temperature in near-bottom waters, as well as granulometry and organic carbon in the sediments verify the above conclusions. 相似文献