Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

A STUDY ON LAND SYSTEM INNOVATIONS IN THE CONSTRUCTION OF SMALL TOWNS IN CHINA     

LIANGLin－ke  CHANGJiang 《中国地理科学(英文版)》2002,12(1):80-85

The economic development in China and the rising of the living standard need to speed up the urbanisa-tion.The development of small towns is an important way to Chinese urbanization.Land use plays a very important role in the development of small towns.However there are many problems in the development of small towns,esp.in land use.The paper first discusses the land problems in the development of small towns.Such as much cultivated land lies idle,under-utilization and waste of land,increasing illegal use of land,unstable contractural relationship for land use.The relationship between the development of small towns and land use is also studied.Then the guidelines for the land system innovations of small towns are put forward.Namely the sustainability of social and economic development,the bal-ance between land reservation and land utilization,the provision of service to village ,agriculture and farmer,the manage-ment of land resource and land assets,the parsimonious andlegal use of land.The basic framework of land system innova-tions of small towns is put forward finally.It include the land replacement policy for small towns and the permanent tenan-cy of farmland,the overall plan for land uses and other plans in harmony,the establishment of a flexible system of land supplies,using land with payments ,the transfer of agricultural land and refining the land law related to the construction of small towns.  相似文献   

A CASE STUDY ON CONCENTRATION AND DECENTRALIZATION：BEHAVIOR AND DYNAMIC MECHANISM OF SPATIAL EVOLUTION IN METROPOLITAN AREA，NANJING，CHINA   总被引：1，自引：1，他引：0  

ZHUXi－gang  ZHANGJing－xiang 《中国地理科学(英文版)》2002,12(3):212-217

In rapid socio-economic development,the process of concentration and dispersal of various elements tends to be more dramatic,tremendously influencing the shaping and transformation of the space in metropolitan area.Survey of spatial concentration and decentralization has thus become a basic method in examining metropolitan spatial evolution.In this research,three elements were selected as the essential indicators of the process:demographic density distribu-tion,employment density distribution and business office location.Performance of these elements in Nanjing City was exam-ined historically.As Nanjing City could be regarded as a representative of metropolitan areas in China,its situation large-ly suggestes the general characteristics in similar areas of China.Hence based on the investigation of Nanjing City,four general implications were highlighted.First ,metropolitan areas in China are in a violent process and shift of spatial concentra-tion and decentralization.Second,from now to at least the near future,concentration will continue to be the central fea-ture.Third,the landscape of metropolitan areas basically exhibits a dual structure character.The gap in environmental and ecological qualities among different districts will continue for a long time.Fourth,Central Business District (CBD) is playing an important role in helping to convert the traditionally single-centered city structure into a polycentric one.  相似文献   

Discovery of 13 New Variable Stars in the Field of the Open Cluster NGC 2168 （M35）     

Juei-Hwa Hu  Wing-Huen Ip 《中国天文和天体物理学报》2005,5(4):356-362

A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars.  相似文献   

关于改进的Encke方法中参考轨道的选择和校正     

刘林  胡松杰 《天文学报》1996,37(3):285-293

对于改进的Ｅｎｃｋｅ方法，选择适当的参考轨道是一个关键．然而，对于人造地球卫星长弧轨道计算，目前所给出的几种参考轨道均需要逐段校正，这将给定轨问题带来附加的复杂性．本文将仔细探讨如何选择参考轨道和减少校正次数．  相似文献   

BRINGING FORWARD OF THE CONCEPT OF COGIS AND ITS ARCHITECUTRE RESEARCH     

HUXue-lian CHENGCheng-qi WUDe-wen MAAi-nai 《中国地理科学(英文版)》2003,13(1):84-90

Based on the analysis of the development of GIS technology and application,this paper brought forward the concept of GoGIS,namely Cooperative GIS ,CoGIS is GIS facing group-users and supporting human-human interaction,which makes it differ from the former GISs,Then,the characteristics of general Computer Spport Cooperative Work (CSCW)applications and the complexity of Geographic Information Science were analyzed,and the conclusion the CoGIS was not a simple GIS layer on CSCW was reached,Further,this paper gaver the hierarchical architecture of CoGIS,and analyzed the coperative platform in detail from the following:1)basic elements;2) collaboration patterns;3) cooperation control mechanism;4) synchronization mechanism;5) security and 6) group communication and so on.With those,the problems about GIS applications are discussed,such as 1)distributed multi-source GIS information and knowledge sharing platform;2)the fusion and visualization of GIS information;3)virtual reality cooperative modeling;4) dymamic simulation;5)expert system and 6) decision-making.Finally,this paper analyzed CoGIS application mode in brief.  相似文献   

Isolation of Protoplasts from Undaria pinnatifida by Alginate Lyase Digestion     

HU Xiaoke  JIANG Xiaolu*  GUAN Huashi Fishery College  Ocean University of China  Qingdao  P..R.China 《中国海洋大学学报(英文版)》2003,2(1)

1　Introduction　Protoplastsserveasabasicandversatiletoolforge neticengineeringandbiochemicalresearchforseveralreasons :theymayregeneratetheirwallsandprovideamodelsystemforstudyingwallbiogenesis ,theirlysisprovidesagentlemeansofpreparingsubcellularor ganelles ,andthemembraneexpositionallowsgeneticmanipulationsinvolvingfusionoruptakeofnucleicacidstobepossible .Theseadvantagesarelessachiev ablewhenusingintactcells (Liciaetal.,1999) .Incomparisonwithlandplantsandunicellularalgae ,on lylimitedrepo…  相似文献   

Optimal Filtering Algorithm for Stochastic 2-D FMM Ⅱ with Multiplicative Noise     

CHUDongsheng LIANGMeng SHIXin ZHANGLing 《中国海洋大学学报(英文版)》2004,3(1):106-110

1　Introduction　Inrecentyearstherehasbeengrowingresearchin terestinthetwo dimensional (2 D )systemtheory .The 2 Dsystemsmayfindapplicationsinareassuchasmarineseismicdataprocessingandimageprocessing .Althoughmoreandmorevaluableresultshavebeengained ,mos…  相似文献   

台湾海峡西岸重力场变化梯度场图像分析     

梁全强  刘序俨  黄声明  吴维日  陈新泽 《大地测量与地球动力学》2006,26(4):82-85

讨论了应用曲面拟合技术和利用离散的重力观测点的重力变化对特定研究区的重力场变化进行数值模拟以获取该区重力变化空间梯度场图像的具体方法;并应用该方法获得了2004年3月福建安溪3.6级地震前的重力变化空间梯度场图像,发现空间梯度场图像能清晰地反映出地震前重力场群体性变化的差异性;利用此方法对2005年6月~2006年3月间台湾海峡西岸重力场变化进行数值模拟,获得其空间梯度场图像。  相似文献   

APPLICATION OF ANALYTIC HIERARCHY PROCESS TO ASSESSING THE ECOLOGICAL VULNERABILITY OF WETLANDS IN THE JIANGHAN PLAIN   总被引：5，自引：1，他引：4  

WANGXue-lei NINGLong-mei HUWang-bin 《中国地理科学(英文版)》2003,13(3):272-276

Wetlands in the Jianghan Plain are important components of wetland types in lake area in the middle and lower reaches the Changjiang (Yangtze) River and they fulfill many uses and functions related to hydrology,waste assimilation, ecosystem productivity and biodiversity. Owing to natural factors and human activities, especially excessive reclamation from lakes, the shrinking process of the lakes has been accelerated. Wetland ecosystem has shown the characteristics of vulnerability. According to the analysis of wetland ecological function in the Jianghan Plain, this paper presented an index system related to productivity, stability and environmental capacity. By using the method of Analytic Hierarchy Process, we computed the values of the relative weights of the indexes, and evaluated the vulnerability level of the wetland ecosystem by the method of multi-indexes. The case study showed that the fragile extent of wetland ecosystem in the Jianghan Plain is 5.6. This means that the wetland ecosystem in the Jiang-han Plain is laid to the state of middle vulnerability. Therefore, the wetland conservation and eco-rehabilitation in the JiangJaan Plain should be paid attention to.  相似文献