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Hidetoshi Asanuma Eiji Ohtani Takeshi Sakai Hidenori Terasaki Seiji Kamada Tadashi Kondo Takumi Kikegawa 《Physics and Chemistry of Minerals》2010,37(6):353-359
The melting temperature of Fe–18 wt% Si alloy was determined up to 119 GPa based on a change of laser heating efficiency and
the texture of the recovered samples in the laser-heated diamond anvil cell experiments. We have also investigated the subsolidus
phase relations of Fe–18 wt% Si alloy by the in-situ X-ray diffraction method and confirmed that the bcc phase is stable at
least up to 57 GPa and high temperature. The melting curve of the alloy was fitted by the Simon’s equation, P(GPa)/a = (T
m(K)/T
0)
c
, with parameters, T
0 = 1,473 K, a = 3.5 ± 1.1 GPa, and c = 4.5 ± 0.4. The melting temperature of bcc Fe–18 wt% Si alloy is comparable with that of pure iron in the pressure range
of this work. The melting temperature of Fe–18 wt% Si alloy is estimated to be 3,300–3,500 K at 135 GPa, and 4,000–4,200 K
at around 330 GPa, which may provide the lower bound of the temperatures at the core–mantle boundary and the inner core–outer
core boundary if the light element in the core is silicon. 相似文献
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Y. ?KudohEmail author T. ?Kuribayashi A. ?Suzuki E. ?Ohtani T. ?Kamada 《Physics and Chemistry of Minerals》2004,31(6):360-364
The space group and hydrogen positions of -(Al0.84Mg0.07Si0.09)OOH are investigated using a single crystal synthesized using a multi-anvil apparatus under conditions of 1000 °C and 21 GPa. The space group determined by single-crystal X-ray diffraction is to Pnn2, with unit-cell parameters of a=4.6975(8) Å, b= 4.2060(6) Å, c=2.8327(4) Å, and V=55.97(1) Å3. Partial occupancy of the Al site by Mg and Si suggests the possibility of a limited solid solution between -AlOOH, stishovite, and a hypothetical CaCl2-type Mg(OH)2 that is 16% denser than brucite. Difference-Fourier maps reveal two small but significant Fourier peaks attributable to hydrogen atoms. Atomic distances and angles around the first peak indicate a hydrogen bond with O···O distances of 2.511 Å, while those around the second peak are suggestive of a bifurcated hydrogen bond with O···O distances of 2.743 and 2.743 Å. 相似文献
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Yuki Shibazaki Eiji Ohtani Hiroshi Fukui Takeshi Sakai Seiji Kamada Daisuke Ishikawa Satoshi Tsutsui Alfred Q.R. Baron Naoya Nishitani Naohisa Hirao Kenichi Takemura 《Earth and Planetary Science Letters》2012
We have determined the density evolution of the sound velocity of dhcp-FeHx (x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of VP with density is different for the ferromagnetic and nonmagnetic dhcp-FeHx, and that only nonmagnetic dhcp-FeHx follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core. 相似文献
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Charles E. Skupniewicz Ray F. Kamada Gordon E. Schacher 《Boundary-Layer Meteorology》1989,48(1-2):109-128
Horizontal turbulence measurements obtained from 22 wind sensors located on 9 towers in a mountainous coastal area are described and categorized by stability and terrain. Vector wind time series are high-pass filtered, and lateral and longitudinal wind speed variance is calculated for averaging times ranging from 15 s to 2 h. Parameterizations of the functional dependence of variance on averaging time are discussed, and a modification of Panofsky's (1988) uniform terrain technique applicable to complex terrain is presented. The parameterization is applied to the data and shown to be more realistic than a less complicated power law technique. The parameter values are shown to be different than the flat terrain cases of Kaimal et al. (1972), and are primarily a function of sensor location within the complex terrain. The parameters are also examined in terms of their dependence upon season, stability, marine boundary-layer height, and measurement height. 相似文献
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From the magmatic emanations differentiation point of view it is possible to calculate some ratios such as F/CO2, Cl/CO2, SO2/CO2, SO2/H2S, H2S/CO2 and CO2/N2 in the tumarolic gases for the forecasting of volcanic activity. In order to predict the cruptions of a volcano it is needed to select several fumaroles or hot springs having different regimes of variation of the above ratios. The study of some fumaroles composition at the Asama. Mihara, Kirishima and other volcanoes in Japan showed a close connection between volcanic gas compositions and state of the volcanoes. 相似文献
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I. Iwasaki T. Ozawa M. Yoshida T. Katsura B. Iwasaki M. Kamada 《Bulletin of Volcanology》1964,27(1):79-80
Chemical properties of magmatic emanation can be estimated roughly by i) volatiles from rocks by heating at various temperatures, ii) volcanic emanations, iii) residual magmatic emanations, iv) calculation from chemical equilibrium between volatile matters and magmas. Magmatic emanation is assumed to consist all of the volatile matters in magmas such asH 2 O, HCl, HF, SO 2 H 2 S, H 2,CO 2,N 2 and others (halides, etc.) at about 1200°C, although various kinds of magmatic emanations can be formed at different conditions. Magmatic emanation separated from magmas will change their chemical properties by many factors such as changes of temperature and pressure (displacement of chemical equilibrium), and reactions with other substances and it will differentiate into volcanic gases, volcanic waters, volcanic sublimates, and hydrothermal deposits (hot spring deposits). At temperatures above the critical point of water, separation of solid phase (sublimates), liquid phase, and displacement of chemical equilibrium may take place, and gaseous phase will gradually change their chemical properties as will be seen at many fumaroles. Chloride, hydrogen, andSO 2 contents will gradually decrease along with lowering temperature. Once aqueous liquid phase appears below the critical point of water, all the soluble materials may dissolve into this hydrothermal solution. Consequently, the gaseous phase at this stage must have usually a little hydrogen chloride as is observed at many fumaroles. Aqueous solutions must be of acidic nature by dissolution of acid forming components, and by hydrolysis (Chloride type). When a self-reduction-oxidation reaction of sulfurous acid takes place, an aqueous solution of sulfate type will be formed. At this stage, solid phases consist of the remained sublimates which are difficultly soluble in aqueous solution, and deposits formed by reaction in the hydrothermal solutions. The gaseous phases below the boiling point of water, have usually a little water, and consist mainly ofCO 2 type,H 2 S type,N 2 type, and mixed type owing to elimination or addition of components by reactions with waters or wall rocks according to their geological conditions. Aqueous solutions which was of acidic nature must be changed into alkaline solutions by reaction with wall rocks for a long time. When the oxidation of sulfur compounds takes place, an aqueous solution of sulfate type will be formed. Hydrogen sulfide type of water will be formed by reaction of sulfides with acid waters or absorption of hydrogen sulfide. Carbonate type of water will be formed whenCO 2 is absorbed. Solid phases at this stage consist usually of hydrothermal deposits except for that at solfatara or mofette. The course of differentiation of magmatic emanation could take place in more complicated ways than that of magmatic differentiation. 相似文献
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A new phase of AlOOH (tentatively called δ-AlOOH) was synthesized at 21?GPa and 1000?°C and its crystal structure was identified by a powder X-ray diffraction method. Rietveld refinement revealed that this aluminum oxide hydroxide has an orthorhombic unit cell, a?=?4.7134(1) Å, b?=?4.2241(1) Å, c?=?2.83252(8) Å, V?=?56.395 (5) Å3, and Z?=?2 in the space group of P21?nm. A calculated density is 3.533?g?cm?3, which is about 4.48 and 15.04% denser than that of diaspore and boehmite, respectively. The δ-[Al0.86Mg0.07Si0.07]OOH is also stable at 21?GPa and 1000?°C, coexisting with majorite and phase egg, and its cell parameters are a?=?4.710(1) Å, b?=?4.215(1) Å, c?=?2.839(1) Å, and V?=?56.37(1) Å3. 相似文献
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