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Heavy metal characterization of waste portable rechargeable batteries used in mobile phones 总被引：1，自引：1，他引：0
I. C. Nnorom M.Sc. O. Osibanjo Ph.D. 《International Journal of Environmental Science and Technology》2009,6(4):641-650
Ten brands of spent portable rechargeable batteries used in mobile phones (lithium-ion and nickel metal hydride) were collected and disassembled and the battery electrode and printed wiring board prepared using the EPA Method 3050B. The metal concentrations were determined by atomic absorption spectrometry. The mean (± standard deviation) concentrations and range of cobalt, chromium, nickel and cadmium in the battery electrodes were 361284±32281mg/kg (range 20870–575330 mg/kg); 25.3 ± 4.6 mg/kg (7.9–149 mg/kg); 75272 ± 14630 mg/kg (3589–266607 mg/kg) and 2.8 ± 0.6 mg/kg (0.2–16.3 mg/kg), respectively. Similarly, the mean values of cobalt, chromium, nickel and cadmium in the PWB were 564 ± 165 mg/kg (56.1–4068 mg/kg); 28.1 ± 4.0 mg/kg (ND-97.2 mg/kg); 735 ± 188 mg/kg (22.7–2727 mg/kg) and 1.8 ± 0.3 mg/kg (ND-7.2 mg/kg), respectively. The Li-ion battery electrodes contained significantly higher levels of cobalt (p < 0.01) whereas, the NiMH battery contained significantly higher nickel (P < 0.01). All the results for the cobalt and nickel levels in the battery electrodes exceeded the toxicity threshold limit concentration used in the toxicity characterization of solid wastes (cobalt, 8000 mg/kg; nickel, 2000 mg/kg). In fact, the mean cobalt level of the battery electrode is about 45 times the toxicity threshold limit concentration limit for cobalt while the mean nickel result is about 38 times the toxicity threshold limit concentration. Spent portable rechargeable batteries should be handled as toxic materials that require special treatment. Implementation of a well-coordinated management strategy for spent batteries is urgently required to check the dissipation of large doses of toxic heavy metals and rare earth into the environment. 相似文献
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The concentration ranges of chlorinated hydrocarbons in marine fish were HCB (0.03–9.5 ppb), Lindane (0.02–5.3 ppb), Endosulphan (0.21–4.9 ppb), DDT (0.50–18.6 ppb), Aldrin (0.05–54.6 ppb) and PCB (4.78–225 ppb). Fish contained higher concentrations of Aldrin, Heptachlor, HCB and Lindane than shellfish, while a reverse trend was observed for DDT and PCBs. The concentrations of residues obtained were found to be lower than those reported in literature for industrialized countries. Predator fish species were found to concentrate more residues in muscle tissue than plankton feeders. The DDT/PCB values were less than 1 indicating a predominance of industrial activities over agricultural activities as the source of contamination of the marine environment. The fish Galeoides decadactylus is a potential bio-indicator for chlorinated hydrocarbons pollution monitoring in the study area. 相似文献
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The interpretation of the geomagnetic data covering the Nigerian Sector of the hydrocarbon elusive Chad Basin has been carried out with the aim of evaluating its hydrocarbon prospectivity. The geomagnetic data was subjected to transformation and enhancement techniques such as reduction to the equator, band-pass filtering, analytic signal, pseudogravity, Source Parameter Imaging (SPI), and Euler deconvolution (ED). The 2-D forward modeling was done using the GM-SYS? software. The results revealed two subbasins, separated by basement high, where the thickness of sedimentary succession of source rocks, reservoirs, and seals attained about 5 km. Two sets of laterally persistent NE-SW and NW-SE fracture systems capable of forming migratory routes were identified within the study area. Euler solutions show basement fractures that propagate through the sedimentary column at 1000 to 5000 m. Characteristic alternation of positive and negative pseudogravity anomalies exposed basement configuration to be of horst and graben architecture. Constructed models revealed drape anticlines that could act as structural traps in the event of hydrocarbon generation. Analytic signal anomalies indicative of igneous intrusive were mapped within the subbasins. This study concluded that elements that favour hydrocarbon occurrence are present in the Chad Basin and was therefore considered to be of high hydrocarbon prospectivity provided the occurrence and timing of the igneous intrusions had not adversely affected hydrocarbon accumulation. 相似文献
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