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1.
Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup. 相似文献
2.
JOHN P. BLUEMLE LEE CLAYTON 《Boreas: An International Journal of Quaternary Research》1984,13(3):279-299
Large-scale thrusting by the glacial ice occurred in many parts of the Interior Plains of North Dakota, Alberta, and Saskatchewan in late Wisconsinan time. Thrust features are especially prominent in parts of North Dakota. Many of the topographic features of the glaciated landscape of North Dakota formed, either entirely or in part, by the thrusting mechanism, and many individual ice-thrust features have been recognized. The ice-thrusting process was also related to fluting by the glacier, and, as a result, drumlins and other types of fluted features are commonly closely associated with ice-thrust topography. Thrusting by the glacier was dependent primarily on groundwater conditions beneath the ice; thrusting occurred only where hydrologic conditions were appropriate. Most of the individual ice-thrust features that have been recognized are located over discrete aquifers, and the sizes and shapes of the thrust features are dependent upon the sizes and shapes of the aquifers. 相似文献
3.
Black shales and carbon isotopes in pelagic sediments from the Tethyan Lower Jurassic 总被引：5，自引：1，他引：5
Detailed sampling and analysis of Jurassic pelagic limestones and marls from Italy, Hungary and Switzerland have enabled construction of an isotope stratigraphy across the Pliensbachian-Toarcian boundary with resolution to the zonal level. The oxygen-isotope record is unremarkable. The carbon isotopes, however, show two positive excursions: one, relatively minor, during the Pliensbachian, margaritatus Zone, subnodosus Subzone, the other, more major, during the Toarcian. early falciferum Zone, where a maximum δ13C value of 4·52%PDB is attained. These intervals are known to be favoured periods of organic-rich sedimentation in diverse parts of the globe and the isotopic excursions are interpreted as a response to abnormally high rates of storage of organic carbon in the sedimentary record. A comparable phenomenon has been documented from the Cenomanian-Turonian boundary in the Cretaceous where it has been referred to the influence of an ‘Oceanic Anoxic Event’. Some Italian sections spanning this Lower Jurassic interval contain organic-rich shales in the falciferum Zone; the isotopic signatures from their included, locally manganiferous carbonate betray a considerable diagenetic overprint and they cannot therefore be incorporated in a composite isotopic curve. Carbon isotopes from the organic carbon itself are extremely negative, falling to –33δPDB and, in one section examined in detail, correlate with the calcium-carbonate content of the shales; they may reflect a partial change to a non-calcified planktonic biota during deposition of this lime-poor interval, possibly responding to upwelling and increased fertility of near-surface waters. The onset of upwelling may have been as early as spinatum-tenuicostatum Zone time, that is, at the Pliensbachian-Toarcian boundary. 相似文献
4.
MARK D. JOHNSON DAVID M. MICKELSON LEE CLAYTON JOHN W. ATTIG 《Boreas: An International Journal of Quaternary Research》1995,24(2):97-116
Glacial hummocks associated with the Superior Lobe in western Wisconsin are stagnant-ice features composed of melt-out till, meltwater-stream sediment, and flow till. The greater proportion of melt-out till in these hummocks than in hummocks described elsewhere suggests that a model of extensive, supraglacial reworking of supraglacially released debris does not apply to the western Wisconsin hummocks. Interpretation of melt-out till in hummock exposures is based on its strong fabric oriented parallel to regional ice-flow direction. Other features of this melt-out till include poorly developed stratification (color banding and discontinuous thin sandy lenses), and minor faulting, both of which support a melt-out origin. We suggest that as stagnant, debris-rich ice began to melt, supraglacially released debris was deposited as flow till and meltwater-stream sediment (with some debris-flow sediment and lake sediment), but as the thickness of supraglacial debris increased, debris melting out at depth was stabilized, allowing features characteristic of melt-out till to be retained. Because the supraglacial debris was sandy and the stagnant ice was likely at the pressure-melting point, the supraglacial debris was well drained and did not readily fail and flow. Debris volume in the glacier generally was greater at the glacier margin, but lateral and longitudinal variations within this zone were caused by thrusting, freezing-on, or ice-margin fluctuations, which in turn resulted in variations in hummock relief. Ice-walled-lake plains are commonly associated with the hummocks and developed where debris volume was small. 相似文献
5.
A. BISCHOFF D. WEBER R. N. CLAYTON T. FAESTERMANN I. A. FRANCHI U. HERPERS K. KNIE G. KORSCHINEK P. W. KUBIK T. K. MAYEDA S. MERCHEL R. MICHEL S. NEUMANN H. PALME C. T. PILLINGER L. SCHULTZ A. S. SEXTON B. SPETTEL A. B. VERCHOVSKY H. W. WEBER G. WECKWERTH D. WOLF 《Meteoritics & planetary science》1998,33(6):1243-1257
Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm3and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio 40Ar/36Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived. 相似文献
6.
A new method of Vibroseis deconvolution has been recently proposed by the authors. This discussion describes the effects of noise on the application of this method. The initial deconvolution step involves estimating the spectrum of the Vibroseis wavelet by homomorphic filtering. It is shown that noise causes problems with phase estimation. Hence, the Vibroseis wavelet is assumed to be zero phase. Examples demonstrate that zero phase cepstral filtering is a robust wavelet estimation approach for noisy data. The second step of the deconvolution method forms an impulse response model by a spectral extension method. Although this step can improve the resolution of seismic arrivals, it must be applied with caution in view of the deleterious effects of noise. 相似文献
7.
David L. COOK Meenakshi WADHWA Robert N. CLAYTON Nicolas DAUPHAS Philip E. JANNEY Andrew M. DAVIS 《Meteoritics & planetary science》2007,42(12):2067-2077
Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ～0.4‰ amu?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (～0.0 to ～0.3‰ amu?1) and chondrites (～0.0 to ～0.2‰ amu?1) are similar, whereas the range in pallasite metal (～–0.1 to 0.0‰ amu?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (～0.0 to ～0.3‰ amu?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ～0.4‰ amu?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern. 相似文献
8.
Edward J. OLSEN Robert N. CLAYTON Toshiko K. MAYEDA Andrew M. DAVIS Roy S. CLARKE John T. WASSON 《Meteoritics & planetary science》1996,31(5):633-639
Abstract— The Mbosi iron meteorite contains millimeter size silicate inclusions. Mbosi is an ungrouped iron meteorite with a Ge/Ga ratio >10, which is an anomalous property shared with the five-member IIF iron group, the Eagle Station pallasites and four other ungrouped irons. Neither the IIF group nor the four other ungrouped irons are known to have silicate inclusions. Chips from three Mbosi inclusions were studied, but most of the work concentrated on a whole 3.1 mm circular inclusion. This inclusion consists of a mantle and a central core of different mineralogies. The mantle is partially devitrified quartz-normative glass, consisting of microscopic crystallites of two pyroxenes and plagioclase, which are crystalline enough to give an x-ray powder diffraction pattern but not coarse enough to permit analyses of individual minerals. The core consists of silica. The bulk composition does not match any known meteorite type, although there is a similarity in mode of occurrence to quartz-normative silicate inclusions in some HE irons. Mbosi silicate appears to be unique. The bulk rare earth element (REE) pattern of the mantle is flat at ? 7×C1; the core is depleted in REE but shows a small positive Eu anomaly. The O-isotope composition of bulk silicate lies on a unit slope mixing line (parallel and close to the C3 mixing line) that includes the Eagle Station pallasites and the iron Bocaiuva (related to the IIF irons); all of these share the property of having Ge/Ga ratios >10. It is concluded that Mbosi silicate represents a silica-bearing source rock that was melted and injected into metal. Melting occurred early in the history of the parent body because the metal now shows a normal Widmanstätten structure with only minor distortion that was caused when the parent body broke up and released meteorites into interplanetary space. The cause of Ge/Ga ratios being >10 in these irons is unknown. The fact that silicates in Mbosi, Bocaiuva (related to IIF irons) and the Eagle Station trio of pallasites, all characterized by a Ge/Ga ratio >10, lie on a unit slope mixing line in the O-isotope diagram suggests that their origins are closely related. The C3 chondrites appear to be likely precursors for silicates in Mbosi, Bocaiuva and the Eagle Station pallasites. 相似文献
9.
TH. STELZNER K. HEIDE A. BISCHOFF D. WEBER P. SCHERER L. SCHULTZ M. HAPPEL W. SCHR
N U. NEUPERT R. MICHEL R. N. CLAYTON T. K. MAYEDA G. BONANI I. HAIDAS S. IVY-OCHS M. SUTER 《Meteoritics & planetary science》1999,34(5):787-794
Abstract— Weathering effects on meteorite finds from the Acfer region were studied by various analytical techniques and in dependence on the depth of sampling. In thin sections of weathered meteorites, weathering effects usually decrease from the outside to the interior of the meteorite. The results of evolved gas analysis indicate that variation in weathering between surface and core is not significant in respect to the formation of Fe-oxyhydroxides. The secondary alteration effects in the noble gases are distributed unevenly throughout the specimens, as seen in the nonsystematic differences observed for the heavy noble gases. Chemical analyses show significant enrichment of Ba and Sr in the outer parts of the weathered samples due to element contamination through aqueous solution. Iron, Ni, and Co are partly flushed from the system as the metal oxidation proceeds. Oxygen isotopes show increases in δ18O and δ17O with increasing terrestrial age. For a set of H3 chondrites, the degree of weathering determined from the water content was correlated with terrestrial ages and is discussed with respect to possible weathering mechanisms. 相似文献
10.
IMPLICATIONS FROM CHEMICAL,STRUCTURAL AND MINERALOGICAL STUDIES OF MAGNETIC MICROSPHERULES FROM AROUND THE LOWER YOUNGER DRYAS BOUNDARY (NEW MEXICO,USA) 
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下载免费PDF全文 ALEXANDRE V. ANDRONIKOV IRINA E. ANDRONIKOVA CLAYTON W. LOEHN BARBARA LAFUENTE JESSE A. M. BALLENGER GEORGE T. CRAWFORD DANTE S. LAURETTA 《Geografiska Annaler: Series A, Physical Geography》2016,98(1):39-59
Hollow magnetic microspherules from along the lower Younger Dryas boundary (c. 12.9 ka bp ) in New Mexico (USA) were studied using scanning electron microscopy, electron probe microanalysis, X‐ray diffraction, and laser‐ablation inductively coupled‐plasma mass spectrometry methods. The shell of the microspherules (10–15% of the spherule's diameter) displays dendritic surface textures, which are likely due to quenching during rapid cooling of molten material. Structurally, multiple single‐magnetite crystals attached together form the bulk of the microspherules. Iron dominates the microspherules’ composition (～90% FeOtot), Mn is the second most abundant element (up to 0.4% MnO), Al is detected in low concentrations (<0.30% of Al2O3). Among the trace elements, the rare earth elements display slightly fractionated patterns with concentrations of 0.1–1.0× CI chondrite. The microspherules contain elevated concentrations of Ni relative to detrital magnetite (up to 435 ppm) and very low concentrations of Ti (down to 5 ppm). Chemical, structural and mineralogical features of the microspherules do not contradict the existing models of the formation during ablation while a meteoroid goes through the Earth's atmosphere. Elevated concentrations of the magnetic microspherules in sediments can be a stratigraphic marker for the lower Younger Dryas boundary in North America. 相似文献