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1.
The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ 18O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ 18O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ 18O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ 18O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ 18O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
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This article provides an analysis of the EU Emissions Trading Scheme (ETS) and the harmonized benchmark-based allocation procedures by comparing two energy-intensive sectors with activities in three Member States. These sectors include the cement industry (CEI) and the pulp and paper industry (PPI) in the UK, Sweden, and France. Our results show that the new procedures are better suited for the more homogeneous CEI, in which the outcome of stricter allocation of emissions allowances is consistent between Member States. For the more heterogeneous PPI – in terms of its product portfolios, technical infrastructures, and fuel mixes – the allocation procedures lead to diverse outcomes. It is the lack of product benchmark curves, and the alternative use of benchmark values that are biased towards a fossil fuel-mix and are based on specific energy use rather than emission intensity, which leads to allocations to the PPI that do not represent the average performance of the top 10% of GHG-efficient installations. Another matter is that grandfathering is still present via the historically based production volumes. How to deal with structural change and provisions regarding capacity reductions and partial cessation is an issue that is highly relevant for the PPI but less so for the CEI.

Policy relevance

After an unprecedented amount of consultation with industrial associations and other stakeholders, a harmonized benchmark-based allocation methodology was introduced in the third trading period of the EU ETS. Establishing a reliable and robust benchmark methodology for free allocation that shields against high direct carbon costs, is perceived as fair and politically acceptable, and still incentivizes firms to take action, is a significant challenge. This article contributes to a deeper understanding of the challenges in effectively applying harmonized rules in industrial sectors that are heterogeneous. This is essential for the debate on structural reformation of the EU ETS, and for sharing experiences with other emerging emissions trading systems in the world that also consider benchmark methodologies.  相似文献   

4.
Aviation constitutes about 2.5% of all energy-related CO2 emissions and in addition there are non-CO2 effects. In 2016, the ICAO decided to implement a Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) and in 2017 the EU decided on faster emission reductions in its Emissions Trading System (EU ETS), which since 2012 includes the aviation sector. The effects of these policies on the expected development of air travel emissions from 2017 to 2030 have been analyzed. For the sample country Sweden, the analysis shows that when emissions reductions in other sectors are attributed to the aviation sector as a result of the EU ETS and CORSIA, carbon emissions are expected to reduce by ?0.8% per year (however if non-CO2 emissions are included in the analysis, then emissions will increase). This is much less than what is needed to achieve the 2°C target. Our analysis of potential national aviation policy instruments shows that there are legally feasible options that could mitigate emissions in addition to the EU ETS and CORSIA. Distance-based air passenger taxes are common among EU Member States and through increased ticket prices these taxes can reduce demand for air travel and thus reduce emissions. Tax on jet fuel is an option for domestic aviation and for international aviation if bilateral agreements are concluded. A quota obligation for biofuels is a third option.

Key policy insights
  • Existing international climate policies for aviation will not deliver any major emission reductions.

  • Policymakers who want to significantly push the aviation sector to contribute to meeting the 2°C target need to work towards putting in place tougher international policy instruments in the long term, and simultaneously implement temporary national policy instruments in the near-term.

  • Distance-based air passenger taxes, carbon taxes on jet fuel and quota obligations for biofuels are available national policy options; if they are gradually increased, and harmonized with other countries, they can help to significantly reduce emissions.

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Archive aerial photos have been used to create a skeletal history for several toxic waste sites currently under investigation in the United States. Because many of the sites are very small in area, and the majority of the historical aerial photography is not large scale, specialized methods have, through experience, been developed to do this work. The result of the work is a series of standard format film stereograms and a detailed report. The report includes several unique methods for presenting the airphoto findings.  相似文献   
7.
Two methods, both using data from fixed-interval-length hydraulic tests and geological mapping on different scales, have been utilised to estimate transmissivity distributions of individual fractures. Individual fracture properties are of importance in estimating transport of water and solutes; they influence the spreading of grout when sealing tunnels. One of the methods is non-parametric, while the other is based on combinatorics and the multiplication principle. The study verified the usefulness of both methods for estimating the probability of conductive and non-conductive fractures, and the transmissivity distributions. Data for estimating transmissivity distributions originate from flow logging of a borehole in Sweden. Fracture frequency data are from core logging and images using a borehole image processing system (BIPS). Estimated transmissivity distributions, based on flow log data from 3-m sections (test scale length, L: 3 m, and step length, dL: 3 m), were compared with transmissivities obtained directly from detailed, overlapping flow logging which identify individual conductive fractures (test scale, L: 0.5 m, step length, dL: 0.1 m). The latter data are considered to be an acceptable approximation of the individual fracture transmissivities; the agreement, compared with the calculated transmissivity distributions based on 3-m section data, is good for both methods.
Resumen Se han utilizado dos métodos, ambos procesando datos de pruebas hidráulicas de longitud e intervalo fijo y mapas geológicos en distintas escalas, para estimar las distribuciones de transmisividad de fracturas individuales. Las propiedades de fracturas individuales son de importancia para estimar el transporte de agua y solutos; las propiedades influyen en la propagación de lechada al sellar túneles. Uno de los métodos es no paramétrico mientras que el otro se basa en el principio de multiplicación y combinatorio. El estudio verifica la utilidad de ambos métodos para estimar la probabilidad de fracturas conductivas y no conductivas y las distribuciones de transmisividad. Los datos para estimar las distribuciones de transmisividad se originan del registro de flujo de un pozo en Suecia. Los datos de frecuencia de fracturas provienen de registros de núcleo e imágenes usando un Sistema de Procesamiento de Imágenes de Pozo (BIPS). Se compararon las distribuciones estimadas de transmisividad basadas en datos del registro de flujo en secciones de 3 m (longitud de escala de la prueba L: 3 m, y escalón de longitud dL: 3 m), con transmisividades obtenidas directamente de registros detallados de flujo superpuesto el cual identifica fracturas conductivas individuales (escala de la prueba, L: 0.5 m, escalón de longitud, dL: 0.1 m). Los últimos datos se consideran una aproximación aceptable de las transmisividades de fracturas individuales; la consistencia, comparada con las distribuciones de transmisividad calculada basadas en datos de sección de 3 m, es buena para ambos métodos.

Résumé Deux méthodes ont été testées afin d’estimer la distribution des transmissivités de fractures unitaires; toutes deux utilisent des données issues de tests hydrauliques effectués à intervalles réguliers et de cartographies géologiques à plusieurs échelles. La connaissance des propriétés des fractures unitaires est importante pour estimer le transport d’eau et de solutés; elles influencent en outre l’étalement du coulis lors du scellement des tunnels. La première méthode est non-paramétrique, et la seconde repose sur l’analyse combinatoire et le principe de multiplication. Cette étude a vérifié l’utilité des deux méthodes pour estimer la probabilité d’occurrence de fractures conductrices et non-conductrices, et la distribution des transmissivités. Les distributions des transmissivités ont été estimées à partir de diagraphies effectuées sur un forage situé en Suède. Les densités de fracturation proviennent de carottages et d’imagerie BIPS (Borehole Image Processing System). Les distributions estimées des transmissivités, basées sur des diagraphies de flux effectuées sur des sections de 3 m (échelle du test L:3 m; pas dL:3 m), ont été comparées aux transmissivités obtenues sur des diagraphies de flux détaillées et se chevauchant, identifiant les fractures conductrices unitaires (échelle du test L: 0.5 m ; pas dL: 0.1 m). Il est admis que ces dernières données représentent une approximation satisfaisante des transmissivités des fractures unitaires; les deux méthodes sont en accord avec les distributions des transmissivités calculées à partir des données acquises sur des sections de 3 m.
  相似文献   
8.
Downscaling a twentieth century global climate simulation to the North Sea   总被引:2,自引:1,他引:2  
The regional ocean model system (ROMS) is used to downscale a 26-year period of the twentieth century 20C3M experiment from the global coupled Bergen climate model (BCM) for the North Sea. Compared to an observational-based climatology, BCM have good results on the mean temperature, except for too low winter temperature. This is connected to a too weak inflow of Atlantic water. The downscaling gives added value to the BCM results by providing regional details, doubling the Atlantic inflow, and improving the mean winter temperature. For mean salinity, BCM has values very close to the climatology, whereas the downscaling becomes too fresh. The downscaling, however, improves the sea surface salinity, the vertical structure, and the Norwegian Coastal Current. It is concluded that the downscaling procedure as presented here is a suitable tool for assessing the future Atlantic inflow and sea temperature in the North Sea based on a global climate projection.  相似文献   
9.
 The major aim was to increase our knowledge on the behaviour of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric oxygen. Samples of this type of sediment collected in a previous investigation at eight sites in western Finland were digested in HClO4-HNO3-HCl-HF at 200  °C and in HCl:HNO3:H2O at 95  °C (aqua regia), and subjected to extractions with ammonium acetate and hydrogen peroxide. Metals and S in the leachates were determined with ICP-AES. The results of the chemical analyses are compared with previously reported experimental data. The concentrations of Al and Fe in the sulphide-bearing fine-grained sediments are about 7% and 5%, respectively. Of the trace metals studied, Mn is most abundant followed in decreasing order by V>Cr>Ni>Cu>Co. On oxidation of the sediments, high proportions of Co, Mn and Ni, intermediate proportions of Cu but low proportions of Fe, Al, Cr and V are released. The extent of the release of a metal on oxidation is controlled either by (1) the level to which the pH of the sediments drops on oxidation (Al, Cu, Cr, V), (2) the amount of the metal associated with easily reduced phases (metal sulphides) in the sediments (Ni, Co) or (3) the sum of the amount associated with reduced phases and adsorbed on soil compounds (Mn). No control of the release of Fe on oxidation of the sediments was identified. Based on the results of the study it is argued that artificial drainage and the subsequent oxidation of sulphide-bearing sediments will result in extensive leaching of Co, Mn and Ni, moderate leaching of Cu and limited leaching of Cr and V into drainages. The major elements, Fe and Al, have the potential to be mobilised and leached in large amounts, though the proportions mobilised/leached will remain low. It is suggested that the identification of sulphide-bearing sediments with a high potential of metal release should be based on determination of metals in easily mobilised reduced compounds (dissolved e.g. in H2O2) and of the level to which the pH of the sediments drops on oxidation. Received: 16 October 1997 · Accepted: 9 March 1998  相似文献   
10.
Samples collected by the deep submersible “Alvin” from four hot spring fields (T = 3–13°C) on the crest of the Galapagos spreading ridge show pronounced and varied compositional anomalies. If it is assumed that these have a general significance, that they are associated with hydrothermal reactions between seawater and basalt wherever new oceanic crust is being produced then global fluxes can be computed. These are large. For Mg and SO4 they balance the river input. For Li and Rb they exceed it by factors of between five and ten. Calcium is supplied at a rate equivalent to that of non-carbonate Ca from the continents. The additions of K, Ba and Si are between one third and two thirds of the river load. There are large positive and negative anomalies for Cl and Na indicating that substantial amounts of Cl may be taken up by the newly formed crust and transported deep into the subduction zones.Where there are data in common, the field measurements agree with the experimental findings at low (<5) water/rock ratios.  相似文献   
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