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Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
2.
500 hPa ridge positions over the Indian and the West Pacific regions during April are related with the summer monsoon rainfall over India. The ridge position over the Indian region shows better relation with monsoon rainfall than that shown by the ridge over the Pacific region. The multiple correlation of these ridge positions with monsoon rainfall exceeds 0.7. These predictive relationships are better than those shown by other parameters, viz. (1) Northern Hemispheric surface temperature; (2) East-Pacific sea surface tempera-ture; (3) El-Nino events and (4) Tahiti-Darwin pressure difference, and index of southern oscillation, over the 30-year samples analysed.  相似文献   
3.
This study analysed the importance of precipitation events from May 2003 to April 2004 on surface water chemistry and solute export from a 696 ha glaciated forested watershed in western New York State, USA. The specific objectives of the study were to determine: (a) the temporal patterns of solutes within individual storm events; (b) the impact of precipitation events on seasonal and annual export budgets; and (c) how solute concentrations and loads varied for precipitation events among seasons as functions of storm intensity and antecedent moisture conditions. Analysis of solute trajectories showed that NH4+, total Al and dissolved organic nitrogen (DON) peaked on the hydrograph rising limb, whereas dissolved organic carbon (DOC) concentrations peaked following the discharge peak. Sulphate and base‐cations displayed a dilution pattern with a minimum around peak discharge. End‐member mixing analysis showed that throughfall contributions were highest on the rising limb, whereas valley‐bottom riparian waters peaked following the discharge peak. The trajectories of NO3? concentrations varied with season, indicating the influence of biotic processes on the generation, and hence flux, of this solute. Storm events had the greatest impact on the annual budgets for NH4+, K+, total dissolved Al, DON and DOC. Storm events during summer had the greatest impact on seasonal solute budgets. Summer events had the highest hourly discharges and high concentrations of solutes. However, NO3? and DOC exports during a spring snowmelt event were considerably more than those observed for large events during other periods of the year. Comparisons among storms showed that season, precipitation amount, and antecedent moisture conditions affected solute concentrations and loads. Concentrations of solutes were elevated for storms that occurred after dry antecedent conditions. Seven of the largest storms accounted for only 15% of the annual discharge, but were responsible for 34%, 19%, 64%, 13%, 39% and 24% of the annual exports of NH4+, K+, Al, NO3?, DON and DOC respectively. These results suggest that the intense and infrequent storms predicted for future climate‐change scenarios will likely increase the exports of solutes like DOC, DON, NH4+, Al and K+ from watersheds. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
4.
We present a critical modification to improved dark object technique for correcting hyperspectral data (EO1-Hyperion). The modification is required in improved dark object technique as the original method does not take into account overlap of spectral response functions of two adjacent bands of hyperspectral sensor. We used weighted deconvolution for correcting the original overlap affected path radiance correction propagation factors. Further, we compared the reduction in correction factors—in different conditions—because of the overlap. We calculated the path radiance for April 22 Hyperion image and compared it with other methods such as 6SV. We found noticeable difference in corrected and uncorrected path radiance propagation factors with “clear” to “very clear” atmospheric models. For the other models (“moderate”, “hazy”, “very hazy”), the difference is negligible and can be ignored and improved dark object technique can be applied without any overlap correction.  相似文献   
5.
Summary In this study a search for teleconnection is made between the Northern Hemisphere lower stratospheric geopotential heights and Indian Monsoon Rainfall (IMR) through the correlation analysis approach. Monthly grid-point 50 hPa geopotential height data and the June to September IMR are used for the period 1958–1990.Analysis reveal that there are domains over the Northern Hemisphere where the variation of the geopotential heights during the preceding months of the monsoon period are related with the interannual behaviour of the IMR. During January and February significant positive correlations are seen along the lower latitudes (10°–20° N). However, the maximum relationship is seen during March, with high positive correlations over the Canadian sector and negative correlations over the east Asian sector. The correlation configuration weakens considerably, once the ENSO (El Niño Southern Oscillation) cases are excluded, suggesting that the correlation pattern obtained may be a manifestation of the ENSO cycle. Implications of these results in the long range forecasting of IMR are also discussed.With 5 Figures  相似文献   
6.
Relationships of three Southern Oscillations and a few other large-scale atmospheric indices, like Stratos-pheric Quasi-Biennial Oscillation, Northern Hemispheric surface air temperature, 50 hPa subtropical ridge po-sition, Indian monsoon rainfall, with the movement and formation of the tropical cyclones over the Bay of Ben-gal during the post-monsoon season are examined. In general, these relationships are not very satisfactory. However, there is some indication that the low phase of the Southern Oscillation is associated with lower mean latitude of the track of cyclones.  相似文献   
7.
Seagrass meadows from the Lakshadweep islands were mapped with the help of black and white aerial photographs. A maximum of 40 ha seagrass cover was estimated in the lagoon of Minicoy, followed by Kavaratti (34 ha). The total seagrass cover from six major islands of Lakshadweep was estimated to be 112 ha with standing crop of ca 800 metric tonnes. The dominant seagrass species observed wasThalassia hemprichii whileCymodocea rotundata, Halophila ovata, Syringodium isoetifolium andHalodule uninervis were common to these islands.  相似文献   
8.
While the role of groundwater in flushing of solutes has long been recognized, few studies have explicitly studied the within‐event changes in groundwater chemistry. We compared the changes in groundwater chemistry during storm events for a wetland and hillslope position in a small (1·5 ha) glaciated, forested catchment in western New York. Flushing responses for dissolved organic carbon (DOC) and nitrogen (DON), nitrate (NO3) and sulfate (SO4) in wetland and hillslope groundwaters were also compared against the corresponding responses in stream water. Eight storm events with varying intensity, amount, and antecedent moisture conditions were evaluated. Solute flushing patterns for wetland and hillslope groundwaters differed dramatically. While DOC concentrations in wetland groundwater followed a dilution trend, corresponding values for hillslope groundwater showed a slight increase. Concentrations for NO3 in wetland groundwater were below detection limits, but hillslope groundwaters displayed high NO3 concentrations with a pronounced increase during storm events. Flushing responses at all positions were also influenced by the size of the event and the time between events. We attributed the differences in flushing to the differences in hydrologic flow paths and biogeochemical conditions. Flushing of the wetland did appear to influence storm‐event stream chemistry but the same could not be said for hillslope groundwaters. This suggests that while a variety of flushing responses may be observed in a catchment, only a subset of these responses affect the discharge chemistry at the catchment outlet. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
9.
Emerald, the green gem variety of beryl (Be3Al2Si6O18), is the third most valuable gemstone after diamond and ruby. The green colour appearance of the crystal is due to trace of Cr3+ and V3+, which replaces Al3+ ions in the crystal lattice of beryl. The hue of green colour of emerald depends on the quantity of Cr3+ and V3+ present in the crystal. Be is incorporated along with Cr and/or V during the process of crystallization. Since Be is relatively rare in the upper continental crust, therefore specific geological and geochemical parameters are required for Be to be incorporated in the crystal lattice of emerald.The present work was carried out to understand the lithological and structural control of emerald occurrences in and around Gurabanda area within the Singhbhum shear zone (SSZ) of Singhbhum crustal province, eastern India. The biotite and serpentine schist belong to the Paleoproterozoic Dhanjori Group and constitute the major lithology of the area. Pegmatite and biotite schist contains a variety of gem minerals in abundance in the area and the gem quality emerald occur at the contact zone of quartz vein and mica-schist. Lithology and structure are the main controlling factors of gem-mineralization in the study area. The study indicates that regional metamorphism and deformation processes along the shear zone played a significant role in the formation of emerald deposits. It is inferred that Singhbhum shear zone facilitated a favourable condition, where the Be bearing pegmatites interacted with Cr bearing mica schist or ultramafic rocks to produce emerald crystal.  相似文献   
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