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1.
The compositions of parental melts of Tolbachinsky Dol (Kamchatka) basalts were estimated from the compositions of olivine-hosted (Fo90.5-83.1) primitive melt inclusions in the rocks of the Northern breakthrough of the Great Tolbachik Fissure Eruption (1975 A.C.) and of the late-Holocene cone “1004”. The parental melts contain 100–150 ppm Cu and 0.16–0.30 wt % S. These concentrations are much higher than those determined for the initial magmas of mid-ocean ridge basalts (MORB), for example of the Juan de Fuca ridge (Cu = 55–105 ppm, S=0.09–0.12 wt %). Modeling of mantle melting under variable redox conditions demonstrated that the high Cu and S contents in the Tolbachinsky Dol melts can be obtained by 6–12% melting of DMM-like source under oxidized conditions (ΔQFM = +1.2 ± 0.1) and do not require a significant (>30–35% for S) subduction-related influx of these elements to the mantle source. The high contents of Cu and S in the Tolbachinsky Dol melts are largely explained by the increase of sulfide solubility in a silicate melt under oxidized conditions. In contrast, relatively reduced (ΔQFM ~ 0) conditions of MORB generation result in low contents of Cu and S in their initial magmas. The estimated ΔQFM values agree well with the data obtained using the Cr-spinel–olivine oxybarometer. The high oxygen potential of Tolbachinsky Dol primary magmas is inherited by more evolved magmas, thus favouring Cu enrichment up to 270 ppm during magma fractionation, approaching maximum copper contents in the global systematics of island-arc rocks.  相似文献   
2.
The paper presents data on plutonic and metamorphic rocks dredged during Cruise 249 of the German R/V Sonne to the Stalemate Ridge, Northwest Pacific Ocean and the Shirshov Rise, western Bering Sea. Dredges in the northwestern sector of the Stalemate Ridge and central portion of the Shirshov Rise show that the plutonic and metamorphic rocks obtained here are amazingly similar. Our petrologic and geochemical data led us to view the rocks as members of a mafic–ultramafic assemblage typical of cumulate portions of ophiolite complexes and backarc spreading centers. The plutonic complexes of the Shirshov Rise and Stalemate Ridge show similarities not only in the petrography and mineralogy of their protoliths but also in the character of their metamorphic transformations. Plutonic rocks from both areas display mineralogical evidence of metamorphism within a broad temperature range: from the high-temperature amphibolite facies to the greenschist facies. Relations between the index mineral assemblages indicate that the metamorphic history of plutonic complexes in the Stalemate Ridge and Shirshov Rise proceeded along a retrograde path. Hornblende schists accompanying the plutonic rocks of the Stalemate Ridge and Shirshov Rise are petrographically close to foliated amphibolites in subophiolitic metamorphic aureoles. Within the framework of geodynamic interpretations of our results, it is realistic to suggest that the examined plutonic complexes were exhumed from subduction zones of various age.  相似文献   
3.
The shift of lava geochemistry between volcanic front to rear-arc volcanoes in active subduction zones is a widespread phenomenon. It is somehow linked to an increase of the slab surface depth of the subducting oceanic lithosphere and increasing thickness of the mantle wedge and new constraints for its causes may improve our understanding of magma generation and element recycling in subduction zones in general. As a case study, this paper focuses on the geochemical composition of lavas from two adjacent volcanic centres from the volcanic front (VF) to rear-arc (RA) transition of the Southern Kamchatkan subduction zone, with the aim to examine whether the shift in lava geochemistry is associated with processes in the mantle wedge or in the subducted oceanic lithosphere or both. The trace element and O-Sr-Nd-Hf-Pb (double-spike)-isotopic composition of the mafic Mutnovsky (VF) and Gorely (RA) lavas in conjunction with geochemical modelling provides constraints for the degree of partial melting in the mantle wedge and the nature of their slab components. Degrees of partial melting are inferred to be significantly higher beneath Mutnovsky (∼18%) than Gorely (∼10%). The Mutnovsky (VF) slab component is dominated by hydrous fluids, derived from subducted sediments and altered oceanic crust, eventually containing minor but variable amounts of sediment melts. The composition of the Gorely slab component strongly points to a hydrous silicate melt, most likely mainly stemming from subducted sediments, although additional fluid-contribution from the underlying altered oceanic crust (AOC) is likely. Moreover, the Hf-Nd-isotope data combined with geochemical modelling suggest progressive break-down of accessory zircon in the melting metasediments. Therefore, the drastic VF to RA shift in basalt chemistry mainly arises from the transition of the nature of the slab component (from hydrous fluid to melt) in conjunction with decreasing degrees of partial melting within ∼15 km across-arc. Finally, systematic variations of key inter-element with high-precision Pb-isotope ratios provide geochemical evidence for a pollution of the Mutnovsky mantle source with Gorely melt components but not vice versa, most likely resulting from trench-ward mantle wedge corner flow. We also present a geodynamic model integrating the location of the Mutnovsky and Gorely volcanic centres and their lava geochemistry with the recently proposed thermal structure of the southern Kamchatkan arc and constraints about phase equilibria in subducted sediments and AOC. Herein, the slab surface hosting the subducted sediments suffers a transition from dehydration to melting above a continuously dehydrating layer of AOC. Wider implications of this study are that an onset of (flush-) sediment melting may ultimately be the main trigger for the VF to RA transition of lava geochemistry in subduction zones.  相似文献   
4.
Melt inclusions in olivine Fo83–72 from tephras of 1867, 1971 and 1992 eruptions of Cerro Negro volcano represent a series of basaltic to andesitic melts of narrow range of MgO (5.6–8 wt %) formed by ~46 wt % fractional crystallization of olivine (~6 wt %), plagioclase (~27 wt %), pyroxene (~13 wt %) and magnetite (<1 wt %) from primitive basaltic melt (average SiO2 = 49 wt %, MgO = 7.6 wt %, H2O = 6 wt %) as it ascended to the surface from the depth of about 14 km. The crystallization occurred at increasing liquidus temperature from 1,050 to 1,090 °C in the pressure range from 400 to 50 MPa and was induced by release of mixed H2O–CO2 fluid from the melt at decreasing pressure. Matrix glass compositions fall at the high-Si end of the melt inclusion trend and represent the final stage of melt crystallization during and after eruption. The bulk compositions of erupted Cerro Negro magmas (tephras and lavas) range from high- to low-MgO (3–10 wt %) basalts, which form a compositional array crossing the trend of melt inclusions so that virtually no rock from Cerro Negro has composition akin to true melt represented by the inclusions. The variations of the bulk magma (rocks) and melt (melt inclusions) compositions can be generated in a dyke connecting a deep primitive magma reservoir with the Cerro Negro edifice. While the melt inclusions represent the compositional trend of instantaneous melts along the magma pathway at decreasing pressure and H2O content, occurrence of low-Mg to high-Mg basalts reflects the process of phenocryst re-distribution in progressively evolving melt. The crystallization scenario is anticipated to operate everywhere in dykes feeding basaltic volcanoes and can explain the predominance of plagioclase-rich high-Al basalts in island arc as well as typical compositional variations of magmas during single eruptions.  相似文献   
5.
Melt inclusions and hosting them highly magnesian olivine from rocks of Kamchatka and the Western Aleutian island arc were analyzed for copper content by LA-ICP-MS to determine the copper partition coefficient in primitive island-arc magmas. Based on measurements of 45 olivine–melt pairs, this coefficient was determined to be 0.028 ± 0.009 (2σ), which is the lowest value among previously published data. Mass-balance calculations of copper in a typical mantle peridotite using obtained partition coefficient indicate that its content in peridotite and primary mantle magmas is mainly determined by mantle sulfide. The Cu partition coefficient was also used to calculate the copper content in parental magmas of volcanoes of the Central Kamchatka Depression. Estimates obtained using copper content in phenocrysts of primitive olivine (Fo > 88 mol %) from these rocks are, on average, 139 ± 58 ppm (2σ), which exceed copper contents in primitive basalts (MgO > 8.5 wt %) of mid-ocean ridges (MORB 93 ± 31 ppm). This suggests the primary enrichment of Central Kamchatka magmas in copper and correlates with their more oxidizing conditions of formation as compared to MORB.  相似文献   
6.
Detailed geological and petrological-geochemical study of rocks of the lava complex of Young Shiveluch volcano made it possible to evaluate the lava volumes, the relative sequence in which the volcanic edifice was formed, and the minimum age of the onset of eruptive activity. The lavas of Young Shiveluch are predominantly magnesian andesites and basaltic andesites of a mildly potassic calc-alkaline series (SiO2 = 55.0–63.5 wt %, Mg# = 55.5–68.9). Geologic relations and data on the mineralogy and geochemistry of rocks composing the lava complex led us to conclude that the magnesian andesites of Young Shiveluch volcano are of hybrid genesis and are a mixture of silicic derivatives and a highly magnesian magma that was periodically replenished in the shallow-depth magmatic chamber. The fractional crystallization of plagioclase and hornblende at the incomplete segregation of plagioclase crystals from the fractionating magmas resulted in adakitic geochemical parameters (Sr/Y = 50–71, Y < 18 ppm) of the most evolved rock varieties. Our results explain the genesis of the rock series of Young Shiveluch volcano without invoking a model of the melting of the subducting Pacific slab at its edge.  相似文献   
7.
In this paper we address allivalites, coarse-and giant-textured olivine-anorthite rocks occurring as separate blocks in the eruption products of many volcanoes from the frontal part of the Kuril-Kamchatka arc. New data are reported on the petrography, mineralogy, and composition of melt inclusions in minerals from ten allivalite samples from Ksudach, Il’inskii, Zavaritskii, Kudryavyi, and Golovnin volcanoes. The crystallization temperatures of allivalite minerals were estimated as 970–1080°C at a melt water content of 3.0–3.5 wt % and oxygen fugacity NNO = 1–2. A genetic link was established between the compositions of melt inclusions and interstitial glasses in allivalites and volcano rocks. The cumulate nature of allivalites was demonstrated. Using mass balance calculations, the degree of fractionation of primary melts during the formation of cumulate layers was estimated for various volcanoes as 22–46%.  相似文献   
8.
9.
This paper presents the results from a study of ash compositions that were erupted in 2013–2016. The juvenile component has been identified in the ejecta using data on the morphology and textural features of ash particles and the composition of volcanic glasses. The data set suggests that the activity of the volcano was phreatomagmatic.  相似文献   
10.
Marinova  Yu. G.  Levchenko  O. V.  Portnyagin  M. V.  Werner  R. 《Oceanology》2020,60(5):691-703
Oceanology - The Osborn Plateau is a large intraplate elevation in the eastern Indian Ocean, which has been poorly studied by geological and geophysical methods. On cruise SO258/1 aboard the R/V...  相似文献   
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