Manganese-rich brown layers in Arctic Ocean sediments: Composition, formation mechanisms, and diagenetic overprint   总被引：4，自引：0，他引：4  

C. März  A. Stratmann  A.-K. Meinhardt  B. Schnetger  R. Stein 《Geochimica et cosmochimica acta》2011,75(23):7668-7687

We present inorganic geochemical analyses of pore waters and sediments of two Late Quaternary sediment cores from the western Arctic Ocean (southern Mendeleev Ridge, RV Polarstern Expedition ARK-XXIII/3), focussing on the composition and origin of distinct, brown-colored, Mn-rich sediment layers. Carbonate enrichments occur in association with these layers as peaks in Ca/Al, Mg/Al, Sr/Al and Sr/Mg, suggesting enhanced input of both ice-rafted and biogenic carbonate. For the first time, we show that the Mn-rich layers layers are also consistently enriched in the scavenged trace metals Co, Cu, Mo and Ni. Distinct bioturbation patterns, specifically well-defined brown burrows into the underlying sediments, suggest these metal enrichments formed close to the sediment-water interface. The geochemical signature of these metal- and carbonate-rich layers most probably documents formation under warmer climate conditions with an intensified continental hydrological cycle and only seasonal sea ice cover. Both rivers and sea ice delivered trace metals to the Arctic Ocean, while enhanced seasonal productivity exported reactive organic matter to the sea floor. The coeval deposition of organic matter, Mn (oxyhydr)oxides and trace metals triggered intense diagenetic Mn cycling at the sediment-water interface. These processes resulted in the formation of Mn and trace metal enrichments, and the degradation of labile organic matter. With the onset of cooler conditions, reduced riverine runoff and/or a solid sea ice cover terminated the input of riverine trace metal and fresh organic matter, resulting in deposition of grayish-yellowish, metal-poor sediments. Oxygen depletion of Arctic bottom waters under these cooler conditions is not supported by our data, and did not cause the sedimentary Mn distribution. While the original composition and texture of the brown layers resulted from specific climatic conditions and corresponding diagenetic processes, pore water data show that diagenetic Mn redistribution is still affecting the organic-poor deeper sediments. Given persistent steady state conditions, purely authigenic Mn-rich brown layers may form, while others may be partly or completely dissolved. The degree of diagenetic Mn redistribution largely depends on the depositional environment, the Mn and organic matter availability, and apparently affected the Co/Mo ratios of Mn-rich layers. Thus, brown Arctic layers are not necessarily synchronous features, and should not be correlated across the Arctic Ocean without additional age control.  相似文献   

Testing the Response of Mycenaean Terracotta Figures and Vessels to Earthquake Ground Motions     

Klaus‐G. Hinzen  Melissa Vetters  Tatiana Kalytta  Sharon K. Reamer  Ursula Damm‐Meinhardt 《Geoarchaeology》2015,30(1):1-18

In the late 1970s, the hypothesis originated that earthquakes played a decisive role in the decline of the Mycenaean civilization at the end of the Late Bronze Age. The late excavator of Tiryns in the Argolid/Greece, Klaus Kilian, presented evidence for earthquake‐related damage to Mycenaean structures and considered four terracotta figures and two ceramic vessels lying on a floor of a potential cult room (later 12th century B.C.) in the Lower Citadel as “earthquake victims.” The broken figures were confined to a small area on the cult room's floor in front of a bench. We assess the archaeological data and test the plausibility of earthquake‐induced toppling of the objects with engineering seismological models. Dimensions and physical properties of the models were taken from the originals. In our simulations the models are virtually placed on a bench, and are exposed to earthquake ground motions based on records from recent Greek earthquakes. We test the artifacts’ toppling behavior and compare the final position of the fallen objects with the original find spots. Statistical analysis of 74,250 model calculations with highly varied ground motion parameters and bench heights reveal only a small probability that the find situation of the objects was caused by an earthquake.  相似文献   

Development of a long-term wellbore sealing concept based on numerical simulations and in situ-testing in the Altmark natural gas field     

Zhengmeng Hou  Lars Wundram  Robert Meyer  Meinhardt Schmidt  Steffen Schmitz  Patrick Were 《Environmental Earth Sciences》2012,67(2):395-409

This paper presents an innovative well abandonment concept developed for the long-term containment of CO₂ in depleted Rotliegend gas reservoirs. The new concept aims at amending the conventional standard well abandonment procedure, taking advantage of the natural creeping ability of the thick, homogeneous Zechstein rock salt formation located around 3,000?m in depth (Altmark area) and consists of four main sealing units: (1) a standard sealing element with cement from the reservoir to the impermeable caprock, (2) a salt plug created in the formerly reamed section of casing within the plastic Zechstein (Upper Permian) rock salt formation, (3) two bridge plugs at the bottom and top of the salt plug and (4) a standard sealing element with cement from the top bridge plug until the ground surface. This site-specific study mainly lays emphasis on the development and field testing of the naturally created salt plug, as a key component of the long-term wellbore sealing concept. Comprehensive numerical simulations conducted prior to and during the field test in 2010 and 2011 successfully predicted the evolution of convergence using downhole measurement data. Preliminary results comprise (1) proven convergence of the rock salt formation, (2) a successful coring and (3) restored integrity of Zechstein salt formation, as proven by the formation integrity test. Based on these results, the new long-term sealing concept has been successfully tested at the Altmark natural gas field and successful application of the concept on other sites with similar geological conditions is foreseen to be likely.  相似文献