Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)     

I.M.H.R. Antunes  A.M.R. Neiva  M.M.V.G. Silva  F. Corfu 《Lithos》2008,103(3-4):445-465

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.  相似文献   

Radiometric constraints on hydrothermal circulation in cooling granite plutons     

A. M. R. Neiva  M. H. Dodson  D. C. Rex  P. G. Guise 《Mineralium Deposita》1995,30(6):460-468

Improved precision of radiometric dating of ore deposits can provide information about the thermal history of hydrothermal circulation in cooling plutons. In Jales a Hercynian porphyritic two-mica granite and pre-Ordovician mica schists are cut and intensely altered by the Campo gold-quartz vein. The unaltered granite must be younger than 320 ± 6 Ma, and gives mica Rb-Sr ages of 308.5 ± 2.4 (1) Ma (muscovite) and 294.5 ± 1.1 Ma (biotite). Alteration muscovites from the granite give a weighted mean Rb-Sr age of 308.1 ± 1.5 Ma, and a mean ³⁹Ar-⁴⁰Ar age of 300.7 ± 2.8 Ma. Alteration muscovites from the mica schists give similar ³⁹Ar-⁴⁰Ar ages, averaging 303.0 ± 2.8 Ma. The results suggest that circulation of the Campo mineralising fluids took place no more than 2–4 Ma after the granite cooled through the muscovite Rb-Sr closure temperature, about 500 °C, and that subsequent cooling to biotite closure at about 300 °C took place at less than 14°C/Ma. The mean cooling rate following emplacement was 15 to 25 °C/Ma. The most detailed comparable published data, for the Cornubian ore field, imply much faster cooling rates.  相似文献   

Geochemistry of Coexisting Biotite and Muscovite of Portuguese Peraluminous Granitic Differentiation Series     

A.M.R. Neiva  M.M.V.G. Silva  M.E.P. Gomes  T.F.C. Campos 《Chemie der Erde / Geochemistry》2002,62(3):197-215

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Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal     

P. C. S. Carvalho  A. M. R. Neiva  M. M. V. G. Silva  I. M. H. R. Antunes 《Environmental Earth Sciences》2014,71(5):2029-2041

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.  相似文献   

Assessment to the potential mobility and toxicity of metals and metalloids in soils contaminated by old Sb–Au and As–Au mines (NW Portugal)     

P. C. S. Carvalho  A. M. R. Neiva  M. M. V. G. Silva 《Environmental Earth Sciences》2012,65(4):1215-1230

The main purpose of this study is to assess arsenic and antimony availability in soils, as well as Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn availability in soils derived from the schist–metagraywacke complex close to old Sb–Au mines and in soils developed from Ordovician slates and close to an old As–Au mine in Portugal. The availability was determined using a European certified sequential extraction procedure (BCR). The results demonstrated that metalloids are not readily bioavailable, because they are mainly associated with the residual fraction. Arsenic and antimony proportions in exchangeable fractions are up to 3 and 1%, respectively. However, arsenic is up to 24% in oxy-hydroxide fractions, while antimony is up to 4% in them, demonstrating the highest bioavailability of arsenic compared to that of antimony, as metalloids are weakly bound to the soils in that fraction. Therefore, arsenic tends to be more toxic than antimony in all soils studied. However, the pseudo-total contents show that both metalloids are above the Italian and Dutch guidelines. Therefore, if physico-chemical changes occur arsenic and antimony will show higher potential environmental risk than evidenced by Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn.  相似文献   

Sequential melting and fractional crystallization: Granites from Guarda-Sabugal area, central Portugal     

Ana Margarida Ribeiro Neiva  Paulo Bravo Silva  Fernando Corfu  João Manuel Farinha Ramos 《Chemie der Erde / Geochemistry》2011,71(3):227-245

Seven distinct phases of Variscan two-mica granite are recognized in the Guarda-Sabugal area. They intruded the Cambrian schist-metagraywacke complex, crystallized in the middle crust, and are syn- to late-D3 (309.2 ± 1.8 Ma), late-D3 (304–300 Ma) and late- to post-D3 (299 ± 3 Ma; ID-TIMS ages on zircon and monazite). Two of the granites, G2 and G5, are close in age and have similar Sr, Nd and O isotope characteristics but contrasting whole rock and mineral features and formed by sequential increasing degree of partial melting of a common metasedimentary protolith. During sequential melting Ti, total Fe, Mg, Ca, Zr, Zn, Sr, Ba and REE contents and (La/Yb)_N increase and Si and Rb contents decrease, plagioclase becomes richer in anorthite and biotite and muscovite richer in Ti and Mg. Each of these granites evolved subsequently by fractional crystallization of quartz, K-feldspar, plagioclase, biotite and ilmenite, defining separate series G2–G3–G7 and G5–G6 containing late Sn-bearing differentiates. Two other granites G1 and G4 represent distinct pulses of magma with individual fractionation trends for major and trace elements and distinct (⁸⁷Sr/⁸⁶Sr)₃₀₀, ?Nd₃₀₀ and δ¹⁸O values.  相似文献   

Petrogenetic links between lepidolite-subtype aplite-pegmatite,aplite veins and associated granites at Segura (central Portugal)     

Isabel Margarida Horta Ribeiro Antunes  Ana Margarida Ribeiro Neiva  João Manuel Farinha Ramos  Paulo Bravo Silva  Maria Manuela Vinha Guerreiro Silva  Fernando Corfu 《Chemie der Erde / Geochemistry》2013

In the Segura area, Variscan S-type granites, aplite veins and lepidolite-subtype granitic aplite-pegmatite veins intruded the Cambrian schist-metagraywacke complex. The granites are syn D3. Aplite veins also intruded the granites. Two-mica granite and muscovite granite have similar ages of 311.0 ± 0.5 Ma and 312.9 ± 2.0 Ma but are not genetically related, as indicated by their geochemical characteristics and (⁸⁷Sr/⁸⁶Sr)₃₁₁ values. They correspond to distinct pulses of magma derived by partial melting of heterogeneous metapelitic rocks. Major and trace elements suggest fractionation trends for: (a) muscovite granite and aplite veins; (b) two-mica granite and lepidolite-subtype aplite-pegmatite veins, but with a gap in most of these trends. Least square analysis for major elements, and modeling of trace elements, indicate that the aplite veins were derived from the muscovite granite magma by fractional crystallization of quartz, plagioclase, K-feldspar and ilmenite. This is supported by the similar (⁸⁷Sr/⁸⁶Sr)₃₁₁ and δ¹⁸O values and the behavior of P₂O₅ in K-feldspar and albite. The decrease in (⁸⁷Sr/⁸⁶Sr)₃₁₁ and strong increase (1.6‰) in δ¹⁸O from two-mica granite to lepidolite-subtype aplite-pegmatite veins, and the behaviors of Ca, Mn and F of hydroxylapatite indicate that these veins are not related to the two-mica granite.  相似文献   

Geochemistry of waters associated with the old mine workings at Fonte Santa (NE of Portugal)     

M.E.P. Gomes  I.M.H.R. Antunes  P.B. Silva  A.M.R. Neiva  F.A.L. Pacheco 《Journal of Geochemical Exploration》2010

The quartz veins containing scheelite from Fonte Santa mine cut the Lower Ordovician quartzites. A muscovite–biotite granite (G1) and a muscovite granite (G2), both S-type, crop out close to the Fonte Santa mine and are related to the Moncorvo–Bemposta shear zone. The most altered samples of G2 show intense muscovitization and microclinization and contain chlorite, columbite–tantalite, wolframite, W-ixiolite and Fe-oxides. The tin-bearing granites contain 18 ppm (G1) and 73 ppm (G2) Sn. The most altered samples of G2 correspond to a tungsten granite. The quartz veins contain muscovite, chlorite, tourmaline, scheelite, pyrrhotite, pyrite, sphalerite, chalcopyrite, galena, arsenopyrite, iron oxides, Fe sulfates, phosphates of Pb, Fe and Al. The Fonte Santa mine area was exploited for W between 1942 and 1982. At the end of November 2006, a flood event damaged the tailings dam of Fonte Santa mine, releasing contaminated material and increasing contaminant levels in water within the area of influence of the mine. The waters related to the Fonte Santa mine are poorly mineralized, with electrical conductivity of < 965 µS/cm, and of a mixed type or HCO₃⁻ and SO₄²⁻ types. Most pH values (5.0−8.5) indicate that there is no significant acidic drainage in the region, as found in other areas. More acidic values (pH = 3.4) were found in the mine's lagoon. Waters associated with mineralized veins and old mine activities have Fe and Mn concentrations that forbid their use for human consumption and agriculture. Natural Na, Mg and K water contents are associated with the alteration of albite, chlorite and muscovite of country rock, while Ca with the W-bearing quartz veins. Weathering agents are carbonic and sulphuric acids and the latter has a strong influence in areas draining fine-grained mine tailings.  相似文献   

Interplay between geochemistry and magma dynamics during magma interaction: An example from the Sithonia Plutonic Complex (NE Greece)     

G. Christofides  D. Perugini  A. Koroneos  T. Soldatos  G. Poli  G. Eleftheriadis  A. Del Moro  A.M. Neiva 《Lithos》2007,95(3-4):243-266

Orogenic granitoids often display mineralogical and geochemical features suggesting that open-system magmatic processes played a key role in their evolution. This is testified by the presence of enclaves of more mafic magmas dispersed into the granitoid mass, the occurrence of strong disequilibrium textures in mineralogical phases, and/or extreme geochemical and isotopic variability.

In this contribution, intrusive rocks constituting the Sithonia Plutonic Complex (Northern Greece) are studied on the basis of mineral chemistry, whole-rock major, trace element geochemistry, and Sr and Nd isotopic composition. Sithonia rocks can be divided into a basic group bearing macroscopic (mafic enclaves), microscopic (disequilibrium textures), geochemical, and isotopic evidence of magma interaction, and an acid group in which most geochemical and isotopic features are consistent with a magma mixing process, but macroscopic and microscopic features are lacking.

A two-step Mixing plus Fractional Crystallization (MFC) process is considered responsible for the evolution of the basic group. The first step explains the chemical variation in the mafic enclave group: a basic magma, represented by the least evolved enclaves, interacted with an acid magma, represented by the most evolved granitoid rocks, to give the most evolved enclaves. The second step explains the geochemical variations of the remaining rocks of the basic group: most evolved enclaves interacted with the same acid magma to give the spectrum of rock compositions with intermediate geochemical signatures. A convection–diffusion process is envisaged to explain the geochemical and isotopic variability and the lack of macroscopic and petrographic evidence of magma interaction in the acid group.

The mafic magma is presumably the result of melting of a mantle, repeatedly metasomatized and enriched in LILE due to subduction events, whereas the acid magma is considered the product of partial melting of lower crustal rocks of intermediate to basaltic composition.

It is shown that Sithonia Plutonic Complex offers the opportunity to investigate in detail the complex interplay between geochemistry and magma dynamics during magma interaction processes between mantle and crustal derived magmas.  相似文献   

The gold area of Jales (northern Portugal)     

J.M. Cotelo Neiva  A.M.R. Neiva 《地学学报》1990,2(3):245-256

The hydrothermal gold quartz veins of Jales cut Hercynian granitic rocks, Pre-Ordovician, Ordovician and Silurian schists. They occur along Hercynian NNE-SSW, NE-SW and WNW-ESE faults and are probably related to the Jales granite. Some are over 2 km long and have a thickness of 0.02–2 m. The only exploited quartz veins are from Campo and Desvio which contain several ore-shoots (25t Au exploited since 1933). The veins from Jales area also have good Au reserves. Quartz and arsenopyrite dominate in the gold quartz veins with a banded structure. Electrum and gold are included in sulphides, sulphosalts and quartz and also in veinlets cutting these minerals. Silver occurs in electrum, argentite, galena, freibergite and polyargyrite. Several minerals were analysed by electron microprobe. The primary minerals, some showing recurrences, belong to six paragenetic stages formed between 550 and 30°C and separated by faulting.  相似文献