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Observations have been made of the ice-crystal morphology of snow which fell at two sampling sites during a warm front followed by a cold front in the Sierra Nevada of the western United States. The snow sampling and ice crystal observations were conducted at Kingvale (KV) and Hobart Mills (HM), California, which are located at almost identical elevations on the upwind and down wind sides of the Sierra Nevada crest, respectively.These observations and several mesoscale features of one of the storms, have been used to study the substantial changes which occurred in the stable oxygen isotopic composition (δ18O) of the precipitation at the two sites.At the beginning of the period of observation, a low level warm front lay across the region and its elevation lowered with time from 2.5 km to 1.7 km. This decrease of the frontal surface height was accompanied by a steady increase in the δ18O values.In the pre-cold frontal passage time periods, the δ18O values at the upwind site signified warmer origin ice crystal morphology than the downwind site. This is explained by orographic effects and the production of supercooled liquid water at low elevations on the upslope side of the Sierra Nevada.During the passage of the surface cold front, the differences in δ18O at the two sites were quite small probably because the orography plays a less significant role in the precipitation production process during such events.The δ18O peaked around −13% which translates to an “equivalent temperature” of −10.7°C for ice phase water capture at the upwind site KV. At site HM downwind of the Sierra crest, and 25 km east of KV, the weighted mean ice phase water capture occurred at elevations some 5 to 6°C colder than at KV, because of subsidence and loss of supercooled liquid water in the lower elevations on the lee side.  相似文献   
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Large numbers of soil samples are routinely analyzed using methylene blue (MB) titration to determine clay content. Although, the MB filter paper spot test titration is simple, it is labor-intensive, subjective, and leaves no record for subsequent re-examination. Preliminary thermometric monitoring of the titration indicated a switch from endothermic to exothermic reaction during titration. We examined this nearly universal property of physicochemical processes as a potential replacement method to automate the MB clay titration, making use of literature data.We translated the isothermal enthalipmetric titration of montmorillonite using MB by Rytwo and Ruiz-Hitzky to an adiabatic thermometric titration (2003). The plot of temperature versus titrant volume gave two intersecting linear segments dependent on the titrated percentage of the clay's cation exchange capacity (CEC). The MB filter paper spot test endpoint reflects the first excess MB that persists in the solid suspension, which also happens to be a function of the clay's CEC. The spot test endpoint is correlated to the thermometric indicator point and, for montmorillonite, the two are related by an exact factor of two. Although this factor will naturally be dependent on the clay minerals in the samples, the analyses show that the thermometric indicator titration method is a viable replacement for the spot test. The proposed automation is commonplace as it is practiced with other types of titrations.  相似文献   
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Over the past decade, the chemical compositions of fogs and intercepted clouds have been investigated at more than a dozen locations across the United States. Sampling sites have been located in the northeast, southeast, Rocky Mountain, and west coast regions of the US. They include both pristine and heavily polluted locations. Frontal/orographic clouds (warm and supercooled), intercepted coastal stratiform clouds, and radiation fogs have all been examined. Sample pH values range from below 3 to above 7. Major ions also exhibit a wide concentration range, with clouds at some locations exhibiting high sea salt concentrations, while composition at other locations is dominated by ammonium and sulfate or nitrate.  相似文献   
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An observational analysis of boundary layer moisture evolution during the dryline on 22 May 2002 is presented. This dryline occurred during the International H2O Project (IHOP) and was well observed by a variety of instruments at the intensive observing region (IOR), Homestead site. Although the observed strong upward air motion and the well-mixed boundary layer favored convection, the dryline did not trigger a convective storm. Several operational and research forecast models predicted deep convection at the IOR. High spatial and temporal resolution observational data from National Aeronautics and Space Administration (NASA) lidar instruments, Atmospheric Emitted Radiance Interferometer (AERI), sounding profiles and simulation results are used to investigate the role of moisture during this dryline. It is hypothesized that in addition to convection and lifting, abundant, deep and persistent moisture is required for a dryline to trigger convection. The possible reason why the dryline failed to trigger convection over the IOR is discussed.  相似文献   
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Geotechnical and Geological Engineering - Fluid fine tailings (FFT) comprising clayey-silt solids pose environmental and financial challenges. Currently, mining operators are depositing thickened...  相似文献   
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