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1.
Understanding groundwater–surface water exchange in river banks is crucial for effective water management and a range of scientific disciplines. While there has been much research on bank storage, many studies assume idealized aquifer systems. This paper presents a field‐based study of the Tambo Catchment (southeast Australia) where the Tambo River interacts with both an unconfined aquifer containing relatively young and fresh groundwater (<500 μS/cm and <100 years old) and a semi‐confined artesian aquifer containing old and saline groundwater (electrical conductivity > 2500 μS/cm and >10 000 years old). Continuous groundwater elevation and electrical conductivity monitoring within the different aquifers and the river suggest that the degree of mixing between the two aquifers and the river varies significantly in response to changing hydrological conditions. Numerical modelling using MODFLOW and the solute transport package MT3DMS indicates that saline water in the river bank moves away from the river during flooding as hydraulic gradients reverse. This water then returns during flood recession as baseflow hydraulic gradients are re‐established. Modelling also indicates that the concentration of a simulated conservative groundwater solute can increase for up to ~34 days at distances of 20 and 40 m from the river in response to flood events approximately 10 m in height. For the same flood event, simulated solute concentrations within 10 m of the river increase for only ~15 days as the infiltrating low‐salinity river water drives groundwater dilution. Average groundwater fluxes to the river stretch estimated using Darcy's law were 7 m3/m/day compared with 26 and 3 m3/m/day for the same periods via mass balance using Radon (222Rn) and chloride (Cl), respectively. The study shows that by coupling numerical modelling with continuous groundwater–surface water monitoring, the transient nature of bank storage can be evaluated, leading to a better understanding of the hydrological system and better interpretation of hydrochemical data. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
2.
Indian Ocean humpback dolphins Sousa plumbea inhabit nearshore waters from South Africa to eastern India. Humpback dolphins are vulnerable to conservation threats due to their naturally small population sizes and use of nearshore habitats, where human activities are highest. We investigated the abundance and residency of this species inhabiting Mossel Bay, South Africa, using photographic mark-recapture. Data were collected during 81 surveys in Mossel Bay between 2011 and 2013. Open population modelling using the POPAN parameterisation produced a ‘super-population’ estimate of 125 individuals (95% CI: 61–260) and within-year estimates of between 33 and 86 individuals (2011: 71 [95% CI: 30–168]; 2012: 33 [15–73], 32 [15–70]; 2013: 46 [20–108]). Although less appropriate, closed capture models were also run for comparison with previous studies in the region and generated similar, but slightly smaller, population estimates within each year. We compared our catalogue with opportunistic data collected from East London, Plettenberg Bay, De Hoop and Gansbaai. The only catalogue matches attained were between Plettenberg Bay (n = 44 identified) and Mossel Bay (n = 67 identified), separated by 140?km. Population exchange was moderate, with nine individuals resighted in multiple years between these two areas. This study supports previous findings of long-range movements for this species and provides a baseline from which to assess future impacts on the population.  相似文献   
3.
Lake Constance is one of Europe’s largest oligotrophic lakes and provides a water source for more than 4.5 million people in Germany and Switzerland. We present here a 12 month study on iodine concentrations, speciation and fluxes to and from the lake to gain a quantitative understanding of the limnic iodine cycle. Monthly water samples were obtained from all major tributaries (14) and the outflow to construct a mass-balance model. Sediment traps were also deployed in the lake for two years at two different stations. Total soluble iodine (TSI) in aqueous samples were analysed by ICP-MS and speciation (iodide, iodate and soluble organically bound iodine, SOI) by ion chromatography-ICP-MS. Iodine concentrations in the Alpine tributaries (1-2 μg l−1) decreased over the summer months due to increasing proportions of snow and glacial melt water from the Alps, while iodine levels in the lowland rivers (∼2-10 μg l−1) increased over the summer. Deposition of TSI to the catchment (16,340 kg I yr−1) was similar to the TSI out-flux by rivers (16,000 kg I yr−1). By also including the particulate riverine iodine flux out of the catchment (∼12,350 kg I yr−1) it is shown that the catchment is a net source of iodine, with the highest particulate fluxes coming from the Alpine rivers. The total TSI flux to the lake was 16,770 kg I yr−1, the largest proportion coming from the Alpenrhein (43%), followed by the Schussen (8%) and Bregenzer Ach (7.7%). Overall the mass-balance for TSI in the lake was negative, with more iodine flowing out of the lake than in (−2050 kg I yr−1; 12% of TSI in-flux). To maintain mass-balance, 8.8 μg I m−2 d−1 from the Obersee and 23 μg I m−2 d−1 from the Untersee must be released from the sediments into the water column. Thus, in comparison with the total iodine flux to the sediments measured by the sediment traps (4762-8075 kg I yr−1), up to 39% of the deposited iodine may be mobilised back into the lake. SOI was the dominant iodine fraction entering the lake, with a total flux of 10,290 kg I yr−1 (64% of TSI input), followed by iodate (3120 kg I yr−1) and iodide (2760 kg I yr−1). Net formation of SOI from iodide and iodate was also noted within the lake, with an estimated production of 6560 kg I yr−1, suggesting a strong role for biology in iodine cycling. In conclusion, organically bound iodine was the dominant iodine species in aqueous and solid phases in Lake Constance, despite low DOC concentrations (<2 mg l−1), and thus is expected to play an important role in iodine cycling in most freshwater environments.  相似文献   
4.
Reforestation of cleared land has the potential to reduce groundwater recharge, salt mobilization and streamflow. Stream salinity change is the net result of changes in stream salt load and streamflow. The net effect of these changes varies spatially as a function of climate, terrain and land cover. Successful natural resource management requires methods to map the spatial variability of reforestation impacts. We investigated salinity data from 2000 bores and streamflow and salinity measurements from 27 catchments in the Goulburn–Broken region in southeast Australia to assess the main factors determining stream salinity and opportunities for management through reforestation. For groundwater systems of similar geology, relationships were found between average annual rainfall and groundwater salinity and between groundwater salinity and low‐flow salinity. Despite its simplicity, we found that the steady‐state component of a simple conceptual coupled water–salt mass balance model (BC2C) adequately explained the spatial variation in streamflow and salinity. The model results suggest the efficiency of afforestation to reduce stream salinity could be increased by more than an order of magnitude through spatial planning. However, appreciable reductions in stream salinity in large rivers through land cover change alone would still require reforestation on an unprecedented scale. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
5.
Analysis of multivariate response data by modelling the principal components of the response has beenapplied to two sets of data. In both cases principal components analysis revealed the relationships amongthe response variables and exploited them to simplify the problem of modelling and optimizing themultivariate response. The models and optima obtained from the principal components comparedfavourably with the individual models and simultaneous optima.  相似文献   
6.
1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.  相似文献   
7.
Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human-impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon-222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady-state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP-derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in-stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m3 s−1), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.  相似文献   
8.
Ocean Dynamics - The complicated pattern of the chaotic ocean surface depends strongly on the interaction between wind and waves. An accurate representation of momentum and energy exchange at...  相似文献   
9.
A background indoor air study has been completed which includes the collection of indoor air samples from office buildings and schools. The anonymous study was designed with input from the U.S. Environmental Protection Agency and the Massachusetts Department of Environmental Protection. The sampling was implemented in 2013, 2014, and 2015 and included the collection of 25 school building samples and 61 office building samples. The study generated 14,668 new indoor air background data points, with samples collected from buildings located in 26 cities in 18 states, including Arizona, California, Connecticut, Indiana, Kansas, Maine, Massachusetts, Minnesota, Montana, New Hampshire, New Jersey, New York, Nevada, North Carolina, Ohio, Texas, Utah, and Washington. Indoor air background concentrations of target compound volatile organic compounds (VOCs) ranged from less than the laboratory method reporting limit of 0.044 μg/m3 to concentrations up to 1190 μg/m3, with hydrocarbon ranges from less than the reporting method limit of 10 μg/m3 to concentrations up to 3000 μg/m3. Some VOCs were identified ubiquitously in indoor air background, and some were identified at concentrations which exceeded risk-based regulatory screening levels. These study results provide useful and updated information on indoor air background and air quality in offices and schools and can be used in future regulatory guidance update considerations, for further examination of relationships between these data and residential study data, in human health risk assessments and risk communication, and in planning future studies.  相似文献   
10.
Citizen science (CS) information requires systematic review that incorporates a range of interests and concerns. Yet, there has been little research on what might constitute reviewing best practice to ensure CS is trusted by contributors and users of the data. Insights from a survey of all 1134 reviewers who curate the global eBird Project highlight the knowledge-brokering work involved to ensure CS data are trusted by both citizens and science. Drawing on scholarship focused on key drivers of useable knowledge for natural resource decision-making, we consider CS reviewing best practice to ensure CS can be useful to the producers and users of this knowledge. We find that CS reviewers need to be motivated to provide appropriate feedback to improve CS data, commit to reviewing practice that is respected by citizens, and ensure the information published is credible and be reviewed by a supportive and accountable network of fellow reviewers.  相似文献   
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