A study on the exchange additivity of zinc in solid mixtures in seawater——Ⅱ.Stepwise exchange in δ-MnO₂/montmorrillonite mixture     

Meng Xiaoguang  Zhang Zhengbin  Liu Liansheng 《海洋学报(英文版)》1988,7(2):261-265

In this study the zinc exchange process and the reason for the non-additive exchange of δ-MnO2/montmorrillonite have been investigated. The results suggest that with pH increasing from 2 to 8, the stepwise exchange of zinc occurs on δ-MnO. and montmorrillonite in their mixture.At low pH zinc ions are bound on δ-MnO2, while at high pH, the exchange on montmorrillonite dominates the surface interaction in the mixture. The study demonstrates that the stepwise exchange and the heterogeneity of the binding sites on δ-MnO2 surface are the reason for the non-additive exchange. It is also shown that when δ-MnO2 amounts to 5 %, zinc exchange on sea sediments is controlled by 8-MnO2.  相似文献   

海水中磷酸盐在固体粒子上阴离子交换作用　海水中磷酸盐-固体粒子相互作用的台阶型等温线     

赵宏宾  刘莲生  张正斌 《海洋与湖沼》1997,28(2):172-178

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。  相似文献   

Study on copper complexing ligand concentrations in several China’s coastal waters     

GONG Haidong  ZHANG Zhengbin  LIU Chunying  LIU Liansheng 《海洋学报(英文版)》2006,25(1):64-77

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.  相似文献   

海水中液-固界面的台阶型动力学曲线 Ⅰ.动力学曲线之台阶的消长和变化规律          下载免费PDF全文

刘莲生  张正斌  蔡卫君  潘纲  杜恒清 《海洋与湖沼》1993,(2)

对海水中Zn(Ⅱ),Ca(Ⅱ),Cd(Ⅱ)与高岭石、伊利石和蒙脱石等粘土矿物;无定形水合氧化铁、α-FeOOH等铁的水合氧化物;δ-MaO_2,γ-MnOOH,水锰矿等锰的水合氧化物等30个左右实验体系的液-固界面台阶型动力学曲线进行了系统的实验测定和全面的条件研究。在实验测定上提出两种方法、互为校核。对动力学曲线之台阶的消长和变化规律作了系统研究,确定主要影响因素是:金属离子初始浓度、固体交换剂量、体系的pH值和温度,以及搅拌速度等。  相似文献   

海洋中液-固界面作用的分形研究Ⅰ.SAXS法测量固体交换剂的分维     

张正斌  管清录  郭国霖  刘莲生  王超英 《海洋与湖沼》1992,23(2):138-143

本文将分形作为一个新概念,应用到海洋化学的液-固界面作用的一系列的研究上。根据用SAXS法测定一些常见的粘土矿物(高岭石,蒙脱石)和水合氧化物(水锰矿、δ-MnO_2、氧化铁凝胶、针铁矿、无定形氧化铁)的分维结果,可将这些结果划分成三类:(1)小尺度模量下具有表面分形;大尺度模量下具有质量分形。(2)只有一种分维值的表面分形。(3)在小尺度模量下和大尺度模量下分别具有不同分维值的表面分形。  相似文献   

Study of Adsorption Isotherm Curves of Amino Acids on the Kaolinite     

刘效兰  张正斌 《海洋通报(英文版)》2002,4(1):52-60

This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ） exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ） added.It can be explained in terms of formation of the type(Ⅰ） ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system.  相似文献   

砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响     

赵卫红  张正斌 《中国海洋大学学报(自然科学版)》1997,(2)

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系  相似文献   

海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下     

张正斌  李子江 《海洋学报》1979,1(1):77-89

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。  相似文献   

海水中一氧化氮的极谱法测定     

任春艳  张正斌  邢磊  刘春颖  刘莲生 《中国海洋大学学报(自然科学版)》2003,33(5):801-808

本文首次采用 Nafion和 Co(salen) /Nafion修饰铂电极测定海水中的 NO,对实验条件进行了选择 ,确定了最佳实验条件 ,即反应池通氮除氧 30 min,富集时间为 4min。同时用线性扫描法对海水中的 NO进行测定 ,测得海水中 NO的浓度与氧化峰电流之间有一定线性关系。对 Nafion修饰电极而言 ,线性范围 1～ 76.9μmol/L,R2 =0 .991 6,检出限为 1 μmol/L。同时对 2种方法修饰的铂电极进行了比较 ,即当 NO浓度在 1 0 -6mol/L数量级时 2种电极基本上无差别 ,而在 1 0 -7mol/L数量级时 Co(salen) /Nafion修饰电极要明显优于 Nafion修饰电极  相似文献   

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER     

张正斌  杨长春  刘莲生 《中国海洋湖沼学报》1992,(2)

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c  相似文献