Mineralogy and composition of Kuroko deposits from northeastern Honshu and their possible modern analogues from the Izu-Ogasawara (Bonin) Arc south of Japan: Implications for mode of formation     

G.P. Glasby  K. Iizasa  M. Hannington  H. Kubota  K. Notsu 《Ore Geology Reviews》2008,34(4):547-560

The Kuroko deposits of NE Honshu are a key type deposit for the study of volcanogenic massive sulfide deposits. However, these deposits have not been studied in detail since the early 1980's and knowledge of their mode of formation is now dated. In this study, we present the analysis of 12 samples of the Kuroko deposits, 12 samples of submarine hydrothermal minerals from the Sunrise deposit and 6 samples from Suiyo Seamount, both of which are located on the Izu-Ogasawara (Bonin) Arc, for 27 elements. For the Kuroko deposit, Cd>Sb>Ag>Pb>Hg>As>Zn>Cu are highly enriched, Au>Te>Bi>Ba>Mo are moderately enriched, In>Tl are somewhat enriched and Fe is not significantly enriched relative to the average continental crust. Within each of these deposits, a similar pattern of element associations is apparent: Zn–Pb with As, Sb, Cd, Ag, Hg, Tl and Au; Fe–Cu–Ba with As, Sb, Ag, Tl, Mo, Te and Au; Si–Ba with Ag and Au; CaSO₄. The enrichment of the chalcophilic elements in these deposits is consistent with hydrothermal leaching of these elements from the host rocks which are dominantly rhyolite–dacite in the case of the Kuroko deposits, rhyolite in the case of the Sunrise deposit and dacite–rhyolite in the case of the Suiyo Seamount deposit. However, this pattern of element enrichment is also similar to that observed in fumarolic gas condensates from andesitic volcanoes. This suggests that there may be a significant magmatic contribution to the composition of the hydrothermal fluids responsible for the formation of the Kuroko deposits, although it is not yet possible to quantify the relative contributions of these two sources of elements.The compositional data show that Sunrise and Suiyo Seamount deposits are much closer compositionally to the Kuroko deposits from NE Honshu than are the submarine hydrothermal deposits from the JADE site in the Okinawa Trough which contain, on average, significantly higher concentrations of Pb, Zn, Sb, As and Ag than each of these deposits. In spite of the greater similarity in tectonic setting of the Hokuroku Basin in which the Kuroko deposits formed to the Okinawa Trough (intracontinental rifted back-arc basin) compared to Myojin Knoll and Suiyo Seamount (active arc volcanoes), it appears that submarine hydrothermal deposits from Myojin Knoll and Suiyo Seamount are closer analogues of the Kuroko deposit than are those from the Okinawa Trough. The present data are consistent with the magmatic hydrothermal model for the formation of Kuroko-type deposits as formulated by Urabe and Marumo [Urabe, T., Marumo, K., 1991. A new model for Kuroko-type deposits of Japan. Episodes 14, 246–251].  相似文献   

Mechanisms of enrichment of the rarer elements in marine manganese nodules     

G.P. Glasby 《Marine Chemistry》1973,1(2):105-125

The rare-earth distribution has been determined in five manganese nodules from a range of marine environments. Manganese nodules from Loch Fyne, Scotland, and the Gulf of Aden are characterized by a low absolute abundance of the rare-earth elements and a low Ce/La ratio compared with deep-sea nodules. This difference is interpreted in terms of the diagenetic remobilization of manganese in the high sedimentation regimes leading to the effective fractionation of manganese from the rare-earth elements and the resultant depletion of the rare earths in nodules from these environments. The mechanism of incorporation of the rare-earth elements into manganese nodules is thought to be either the direct adsorption of these elements from seawater or the scavenging of the elements by colloidal iron oxide prior to their incorporation into the authigenic phase of nodules. There appears to be no evidence for the surface transfer of these elements from inorganic detritus into the authigenic phase of nodules as suggested by previous authors. The distribution of U and Th in the nodules is controlled by factors similar to those controlling the rare-earth abundance in nodules. The higher U/Th ratios in nodules from Loch Fyne and the Gulf of Aden is considered to be due to the preferential reduction of UO₂(CO₃)₃^4? to some lower-valency uranium species such as U₃O₈ in nodules from less oxidizing environments.  相似文献   

Co–rich Mn crusts from the Magellan Seamount cluster: the long journey through time     

Geoffrey P. Glasby  Xiangwen Ren  Xuefa Shi  Irina A. Pulyaeva 《Geo-Marine Letters》2007,27(5):315-323

The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific (10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time.  相似文献   

Submarine hydrothermal mineralization in the Okinawa Trough, SW of Japan: an overview   总被引：3，自引：0，他引：3  

G. P. Glasby  K. Notsu   《Ore Geology Reviews》2003,23(3-4):299-339

The Okinawa Trough is a heavily sedimented, rifted back-arc basin formed in an intracontinental rift zone. Submarine hydrothermal activity is located within the six back-arc rifts located in the middle and southern Okinawa Trough and its distribution is controlled principally by tectonic factors. Subduction of the Daito and Gagua Ridges beneath the Ryukyu Arc has resulted in fracturing of the brittle lithosphere beneath the Okinawa Trough. Hydrothermal activity is strongest in the volcanic arc-rift migration phenomenon (VAMP) area plus the JADE site and Southernmost Part of the Okinawa Trough (SPOT) area which form the prolongation of these two ridges. These areas are characterized by extremely high heat flow locally. Submarine hydrothermal fluids from the Okinawa Trough tend to be strongly influenced by interaction of the hydrothermal fluids with organic matter in the sediment resulting in high alkalinity and NH₄⁺ concentrations of the fluids. The fluids also contain high concentrations of CO₂ of magmatic origin. Submarine hydrothermal mineralization in the trough is diverse. The CLAM site consists principally of carbonate chimneys. Interaction of the hydrothermal fluid with organic matter in the sediment is particularly strong at this site. This is most probably a sediment-hosted deposit in which sulphide minerals have deposited within the sediment column leaving ‘spent ore-fluids’ to emerge at the seafloor. The JADE site consists of active and inactive sulphide–sulphate chimneys and mounds. The Zn–Pb-rich sulphides at this site contain the highest concentrations of Pb, Ag and Au so far recorded in submarine hydrothermal sulphide deposits. At Minami-Ensei Knoll and Hatoma Knoll, active and inactive chimneys consist principally of anhydrite and barite as a result of phase separation of the hydrothermal fluids beneath the seafloor. An intense black smoker has recently been discovered at Yonaguni Knoll in the SPOT area. If it is confirmed that sulphide mineralization is dominant at this site, this could be a highly prospective area. The most prospective areas for economic-grade minerals in the Okinawa Trough appear to be the JADE site and the SPOT area.  相似文献   

An appraisal of an iterative construction of the endmembers controlling the composition of deep-sea manganese nodules from the Central Indian Ocean Basin     

R M Renner  B N Nath  G P Glasby 《Journal of Earth System Science》2014,123(6):1399-1411

This paper describes an estimation of endmember compositions followed by the assessment of those results by log-ratio variance analysis. As an appraisal, it deals only with the first objective of an endmember analysis namely, to identify endmembers if they exist by estimating their compositions. Following the creation of the endmember estimates, the computation of an array of log-ratio variances was a key innovation in this type of study. Log-ratio variances revealed intrinsic linear associations between the dominant elements on each of the estimated endmember compositions, largely confirming the endmember analysis. The dataset under study contained the concentrations of 16 elements in 93 samples of deep-sea manganese nodules from the Central Indian Ocean Basin. Many previous analyses of these nodules were undertaken to assess the economic potential of the deposits. This study by contrast, quantified the inter-element associations that account for the nodule compositions. Four endmembers were identified. The elements loaded on each were: (1) Mn, Zn, Ni, Cu, Mn-rich, (2) Fe, Ti, P, Co, Fe-rich, (3) Si, Al, Na, K, clay minerals, (3) Mg, ultramafic material, possibly including Mn, Cr, V, Ca, Na. These latter elements were also detected by their log-ratio variances to be associated with Mg on the 4th endmember.  相似文献   

Single close encounters in the planetary problem     

GP. Horedt 《Celestial Mechanics and Dynamical Astronomy》1972,6(2):232-241

We consider a large massM and two small massesm ₁ andm ₂ (m ₁ m ₂;m ₁,m ₂M). The orbit ofm ₁ is initially circular and the motion ofm ₂ hyperbolic with respect toM. The orbital elements of the small masses are strongly modified after a close, single encounter betweenm ₁ andm ₂.An approximative method, similar to the theory of stellar encounters, is used to determine the probabilities of collisions, hyperbolas, direct and retrograde ellipses, as well as the mean values of the semimajor axes and their root mean square deviation after the encounter.The results are close to those which are obtained if the massm ₂ is negligibly small, (Mm ₁m ₂;m ₂ 0), as should be also expected on general grounds.  相似文献   

Deep Seabed Mining: Past Failures and Future Prospects     

G. P. Glasby 《Marine Georesources & Geotechnology》2013,31(2):161-176

The first attempt to exploit deep-sea manganese nodules ended in failure as a result of the collapse of world metal prices, the onerous provisions imposed by the U.N. Convention on the Law of the Sea (UNCLOS), and the overoptimistic assumptions about the viability of nodule mining. Attention then focused on Co-rich manganese crusts from seamounts. Since the mid-1980s, a number of new players have committed themselves to long-term programs to establish the viability of mining deep-sea manganese nodules. These programs require heavy subsidy by the host governments. Au-rich submarine hydrothermal deposits located at convergent plate margins are now emerging as a more promising prospect for mining than deep-sea manganese deposits.  相似文献   

The effects of suspended sediment on brown trout (Salmo trutta) feeding and respiration after macrophyte control     

MJC Greer  SK Crow  AS Hicks  GP Closs 《新西兰海洋与淡水研究杂志》2013,47(2):278-285

Sediment resuspension during and after mechanical excavation of macrophytes may have a significant impact on resident fish populations. Unfortunately, little is known about the influence of this sediment on the respiratory performance and feeding abilities of fishes in New Zealand waterways. We examined the effects of suspended sediment (SS) concentrations previously observed after a large-scale macrophyte removal operation on oxygen consumption (MO₂) and feeding rates of brown trout (Salmo trutta). MO₂ at 0 mg L^?1, 150 mg L^?1, 300 mg L^?1, 450 mg L^?1 and 600 mg L^?1 of SS was measured using semi-closed respirometry. Feeding rates at the same SS concentrations were also measured using laboratory tank experiments. Results suggest that SS concentrations up to 600 mg L^?1 have no effect on MO₂. Conversely, feeding rates were significantly reduced at 450 mg L^?1 (22% reduction) and 600 mg L^?1 (31% reduction), indicating that sediment concentrations above 450 mg L^?1 may negatively affect brown trout populations.  相似文献   

Infrared spectra of manganese nodules and ferromanganese sediments     

H. Elderfield  G.P. Glasby 《Chemical Geology》1973,11(2):117-122

Differential infrared studies indicate that interlayer hydroxyl ions are present in some manganese nodules where δMnO₂ or 10Å manganite form the predominant mineralogical phase. In fossil ferromanganese sediments δMnO₂ appears to be essentially dehydrated. Due to the poor spectral resolution and band overlap caused by mineral impurities, infrared spectroscopy offers little promise for identifying nodule mineralogy.  相似文献   

Deep Seabed Mining: Past Failures and Future Prospects   总被引：8，自引：0，他引：8  

G. P. Glasby 《Marine Georesources & Geotechnology》2002,20(2):161-176

The first attempt to exploit deep-sea manganese nodules ended in failure as a result of the collapse of world metal prices, the onerous provisions imposed by the U.N. Convention on the Law of the Sea (UNCLOS), and the overoptimistic assumptions about the viability of nodule mining. Attention then focused on Co-rich manganese crusts from seamounts. Since the mid-1980s, a number of new players have committed themselves to long-term programs to establish the viability of mining deep-sea manganese nodules. These programs require heavy subsidy by the host governments. Au-rich submarine hydrothermal deposits located at convergent plate margins are now emerging as a more promising prospect for mining than deep-sea manganese deposits.  相似文献