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1.
Tracing leachates at landfills is usually carried out using either geophysical methods or chemical analyses of groundwater.
There are often problems with fingerprinting pollution sources or clarifying the spreading pattern due to a wide variety of
possibilities giving similar anomalies. The aims of the project were to evaluate the advantages of combining results from
multigeophysical modelling and statistical/chemical modelling in order to identify pollution sources and the spreading pattern
and to test a new technique for chemical fingerprinting. The project was carried out at a landfill in central Sweden using
geophysical measurements and modelling of CVES, GPR and VLF as well as chemical modelling using M3 (multivariate mixing and
mass balance calculations). The results indicate that by combining geophysical modelling and chemical calculations, the possibilities
of fingerprinting the origin of pollution as well as delineating the spreading pattern are significantly increased. 相似文献
2.
I. Th. Rosenqvist 《Lithos》1970,3(4):327-334
Concretions of vivianite attaining 0.5 g occur in the upper 4 m of the bottom sediments of the Åsrum lake, Vestfold, S. Norway. The vivianite-bearing zone is of lacustrine origin. Vivianite is absent in the underlying lagunal and marine sediments. Electro-chemical and chemical data are given for the interstitial water and the clay.
Solubility product of vivianite is determined. The equilibrium constant is K = 10−40 for the reaction 3 Fe++ + 2 HPO4− + 2 OH− = vivianite. The concretions grew by diffusion from a slightly supersaturated interstitial water phase. The degree of supersaturation is calculated. The stability relations of vivianite and hydroxyl apatite are discussed. 相似文献
3.
An experimental investigation has been carried on the solubility of CO2 in water and 1 M NaCl between 0.3 and 4 MPa, in order to test the validity of the results given by various modelling codes. In addition to experiments with pure fluids, the effect of a range of likely reservoir minerals on CO2–water interactions, including K-feldspar, kaolinite, calcite, Ca-montmorillonite and Na-montmorillonite were also investigated. In addition to measurements of CO2 solubility, the pH of the CO2-saturated suspensions was also measured directly at pressures of up to 1 MPa. The results demonstrate that predictions of CO2 solubility made with PHREEQC and Geochemist’s Workbench agree to within 20% with the experimental value, provided corrections are first made off-line for the fugacity coefficient of CO2, while predictions from standalone models are slightly more accurate. In the presence of mineral suspensions, PHREEQC and Geochemist’s Workbench give good results for calcite and kaolinite but underestimate the pH of montmorillonite-bearing assemblages while slightly overestimating the pH of K-feldspar suspensions. These results are significant because they indicate that CO2-charged fluids reacted with clays may be less acidic than indicated by the models, which will impact predictions of the potential for dissolution of reservoir and cap rock minerals, as well as the potential for leaching of toxic metals. 相似文献
4.
Michael C. Davis Jörgen Rosenqvist Susan L. Brantley 《Geochimica et cosmochimica acta》2011,75(2):401-415
The dissolution-precipitation of quartz controls porosity and permeability in many lithologies and may be the best studied mineral-water reaction. However, the rate of quartz-water reaction is relatively well characterized far from equilibrium but relatively unexplored near equilibrium. We present kinetic data for quartz as equilibrium is approached from undersaturation and more limited data on the approach from supersaturated conditions in 0.1 molal NaCl + NaOH + NaSiO(OH)3 solutions with pH 8.2-9.7 at 398, 423, 448, and 473 K. We employed a potentiometric technique that allows precise determination of solution speciation within 2 kJ mol−1 of equilibrium without the need for to perturb the system through physical sampling and chemical analysis. Slightly higher equilibrium solubilities between 423 and 473 K were found than reported in recent compilations. Apparent activation energies of 29 and 37 kJ mol−1 are inferred for rates of dissolution at two surface sites with different values of connectedness: dissolution at Q1 or Q2 silicon sites, respectively. The dissolution mechanism varies with ΔG such that reactions at both sites control dissolution up until a critical free energy value above which only reactions at Q1 sites are important. When our near-equilibrium dissolution rates are extrapolated far from equilibrium, they agree within propagated uncertainty at 398 K with a recently published model by Bickmore et al. (2008). However, our extrapolated rates become progressively slower than model predictions with increasing temperature. Furthermore, we see no dependence of the postulated Q1 reaction rate on pH, and a poorly-constrained pH dependence of the postulated Q2 rate. Our slow extrapolated rates are presumably related to the increasing contribution of dissolution at Q3 sites far from equilibrium. The use of the potentiometric technique for rate measurement will yield both rate data and insights into the mechanisms of dissolution over a range of chemical affinity. Such measurements are needed to model the evolution of many natural systems quantitatively. 相似文献
5.
Rosenqvist J Drossart P Combes M Encrenaz T Lellouch E Bibring JP Erard S Langevin Y Chassefiere E 《Icarus》1992,98(2):254-270
Global Martian atmospheric results derived from the infrared imaging spectrometer ISM flown aboard the Phobos 2 Soviet spacecraft are presented. Over low altitude regions the expected CO mixing ratio of (8 +/- 3) x 10(-4) is measured. Variations of the 2.35-micrometers feature are inconsistent with this value over the Great Martian Volcanoes. If the 2.35-micrometers band is entirely attributable to carbon monoxide, the CO mixing ratio is typically depleted by a factor of 3 over these high altitude areas. Orography should play a major role in the existence of this CO "hole." If, however, these spectral variations at 2.35 micrometers are due to the surface composition, the fraction of the surface covered by the responsible mineral must smoothly decrease as the surface elevation decreases. This phenomenon implies a strong interaction between the surface and the atmosphere for the Great Martian Volcanoes. Diurnal behavior and latitudinal variations of water vapor are globally consistent with Viking measurements. During the Phobos observations, the water vapor amounts over the bright equatorial regions range around 11 pr-micrometers during the day. These amounts are slightly larger than those inferred from 1976 to 1979. The lack of global dust storms during 1988-1989 could explain the enhancement of H2O in the atmosphere. 相似文献
6.
Almeida-Filho R. Rosenqvist A. Shimabukuro Y.E. dos Santos J.R. 《Geoscience and Remote Sensing Letters, IEEE》2005,2(4):409-412
Japanese Earth Resources Satellite 1 (JERS-1) synthetic aperture radar (SAR) data were evaluated to map areas of deforestation in a Brazilian Amazo/spl circ/nia test-site. The results were compared with information derived from a Landsat TM multitemporal series. Unambiguous detection of deforested areas was observed only when the entire deforestation process (slash, burning, and terrain clearing) had already occurred. This result recommends further investigations on the effectiveness of horizontal polarization SAR data to map deforestation in a consistent basis. The cross-polarized (horizontal-vertical) channel designed to be in the ALOS/PALSAR system is expected to improve the distinction between forested and recently deforested areas. 相似文献
7.
A simple steady-state photochemical model is developed in order to determine typical molecular oxygen concentrations for a comprehensive range of primitive abiotic atmospheres. Carbon dioxide is assumed to be the dominant constituent in these atmospheres since CO2 photodissociation may potentially result in the enhancement of the O2 partial pressure. The respective effects of the H2O content, temperature, eddy diffusion coefficient and UV flux on the results are investigated. It is shown that for any pressure at the surface, the partial pressure of molecular oxygen does not exceed 10 mbar. The peculiar case of a runaway greenhouse which has possibly taken place on Venus is qualitatively envisaged. Although O2 is basically absent in the present Venus atmosphere, a transient presence in a primitive stage cannot be ruled out. Possible mechanisms for O2 removal in such an atmosphere are reviewed. At the present stage, we think that the detection of large O2 amounts would be at least a good clue for the presence of life on an extrasolar planet. 相似文献
8.
X-ray difffaction and differential thermal (DTA) techniques were applied to evaluate the semi-quantitative mineralogical composition of a deep black soil profile from India. X-ray investigations revealed the predominance fo a smectic mineral throughout the profile. The mineral gave its main dehydroxylation peak between 532°C (Mg-sat.) and 550° (K-sat.), indicating that it belonged to the nontronite-beidellite series. The concentration of this mineral decreased with increasing particle size, i.e. increasing concentration of feldspars and amphiboles. In addition, illite, iron-rich chlorite, quartz, attapulgite, sepiolite and some mixed-layer minerals were detected.
The effect of cation (Mg++, Ca++, K+) saturation on the intensity, symmetry and temperature of the DTA peaks is discussed. Abnormal behaviour of double dehydroxylation in two clay fractions was found to be due to the abundance of Mg++ cations in the exchangeble positions K+ and Ca++-saturation of the clays did not produce this effect. 相似文献
9.
Philippe Paillou Mathieu Schuster Stephen Tooth Tom Farr Ake Rosenqvist Sylvia Lopez Jean-Marie Malezieux 《Earth and Planetary Science Letters》2009,277(3-4):327-333
Over the last few decades, remote sensing has revealed buried river channels in a number of regions worldwide, in many cases providing evidence of dramatic paleoenvironmental changes over Cenozoic time scales. Using orbital radar satellite imagery, we mapped a major paleodrainage system in eastern Libya, that could have linked the Kufrah Basin to the Mediterranean coast through the Sirt Basin, possibly as far back as the middle Miocene. Synthetic Aperture Radar images from the PALSAR sensor clearly reveal a 900 km-long river system, which starts with three main tributaries (north-eastern Tibesti, northern Uweinat and western Gilf Kebir/Abu Ras) that connect in the Kufrah oasis region. The river system then flows north through the Jebel Dalmah, and forms a large alluvial fan in the Sarir Dalmah. The sand dunes of the Calanscio Sand Sea prevent deep orbital radar penetration and preclude detailed reconstruction of any possible connection to the Mediterranean Sea, but a 300 km-long link to the Gulf of Sirt through the Wadi Sahabi paleochannel is likely. If this connection is confirmed, and its Miocene antiquity is established, then the Kufrah River, comparable in length to the Egyptian Nile, will have important implications for the understanding of the past environments and climates of northern Africa from the middle Miocene to the Holocene. 相似文献
10.
In this paper an explicit pseudo-linear estimator for Doppler-bearing tracking is proposed. It overcomes the problems with the bias of earlier pseudo-linear estimators and with the nonlinear frequency measurement equation by using another representation than the Cartesian one and by using the logarithm of the frequency, respectively. It is fast, inherently stable, and easy to implement. The Doppler shift is, for a nonmoving own-ship, determined by the target velocities, while the bearing rate is determined by the same velocities divided by the range. The special representation in this paper uses this difference in behavior to give fast and bias free estimation of the range. Instead of iterating a weighted feast squares problem using bearing and frequency measurements simultaneously, the true bearings and the course are estimated in a bearings only step followed by a frequency only step, which estimates range and frequency. The range estimate then gives the speed estimate. Modifications for scenarios with multiple emitted frequency lines and/or for frequency lines that disappear during parts of a scenario are shown 相似文献