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1.
In this study, we employ wavelength‐dispersive X‐ray fluorescence (WDXRF) to characterize construction materials from Formative civic architecture (1000 B.C.E.–C.E. 400), ethnographic mudbricks, and off‐site controls from the Taraco Peninsula, Bolivia. The preparation of earthen construction materials for civic buildings can shed light on aspects of community development such as labor organization, resource management, and architectural technologies. We apply geochemical results to reconstructing how public buildings were made as communities moved toward socio‐political complexity in this region. However, there are few geochemical studies in the Andes, and little prior scientific analysis of earthen architecture. We therefore tested the efficacy of WDXRF for this region, and developed control materials. Our archaeological samples were selected from two Formative villages, Chiripa and Kala Uyuni. In this study, we performed WDXRF analyses on 63 archaeological and control samples including archaeological floors, walling, plasters, and mortars, as well as contemporary ethnographic walling and topsoils. Elemental signatures for 28 elements clearly distinguished the archaeological flooring, walling, plaster, and mortars from ethnographic and off‐site controls. More subtle variations were detected that distinguish study sites and the different material types. Laboratory‐calibrated multi‐element XRF effectively supports efforts to reconstruct the pathways to social complexity in the Titicaca Basin. 相似文献
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J.?M.?F.?NogueiraEmail author B.?Simplício M.?H.?Floréncio A.?M.?M.?Bettencourt 《Estuaries and Coasts》2003,26(3):798-802
Concentrations of tributyltin in sediments from 9 selected stations located in the upper Tagus River estuary nature reserve, Portugal, were determined. Tributyltin (TBT) concentrations in the sediments ranged from 5 to 35 ng g−1 on a dry weight basis. The persistent TBT contamination observed in the sediments from this important European ecosystem is primarily related to shipping activities as well as the naval industrial complexes located downstream. This exploratory survey suggests that both dumping and dredging, or the effects of tidal transport of resuspended sediments, are likely the main sources for the TBT contamination observed in the upper estuary. Although the TBT contents found in the sediments studied are low relative to concentrations reported from other parts of the world, they appear to represent a potential risk for some resident marine populations. 相似文献
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Disturbance events can regularly impact stream ecosystems; however, large-scale catastrophic disturbances are rare. From September 2010 to September 2011 Christchurch City experienced over 8500 earthquakes including a magnitude 7.1. One consequence was catastrophic additions of silt and sand into waterways throughout the city. Of 161 km of permanent waterways, 102 km (63%) were affected by earthquake siltation. Benthic invertebrates and fish communities were compared across 16 streams with differing siltation. Invertebrate taxonomic richness decreased significantly (mean 17 taxa reduced to 10 taxa) and EPT taxa (Ephemeroptera, Plecoptera and Trichoptera) were removed entirely from streams receiving heavy siltation. Fish richness and density decreased significantly, with fish absent from some heavily silted streams. Many of these urban streams are sourced from springs and their stable flows and low gradient limit their ability to flush sediment. We predict that without human intervention there will be a long-term sediment legacy and it may take many years for these streams to recover from this catastrophic disturbance. 相似文献
4.
Girardi V.A. V. Teixeira W. Bettencourt J.S. Andrade S. Navarro M.S. Sato K. 《《幕》》2008,31(4):392-400
The Amazonian Craton comprises an Archean domain surrounded by four successively younger Proterozoic tectonic provinces. Within the Rio-Negro-Juruena province the Serra da Providencia Intrusive Suite （1.60 and 1.53 Ga） consists of A-type rapakivi gran- ites, charnockites and mangerites genetically associated with diabase dikes, gabbros and amphibolites. The original mafic melts were derived from a depleted mantle source （εN（T） ＋2.5 to ＋2.8;εSr（T） -12.1）. Underplated mafic magma induced melting of a short-lived felsic crust, thus originating coeval felsic-mafic magmatism in a conti- nental intraplate setting. The Colorado Complex, assigned to the Rondonian-San Ignacio province, comprises 1.35-1.36 Ga intrusive bimodal magmatism represented by monzonite gneisses associated with amphibolite, gabbro and metadiabase dikes intercalated with metasediments with detrital zircon that yield U- Pb ages of 1.35 to 1.42 Ga. Mafic samples dis- play juvenile signatures （εNd（T） 0.0 to ＋5.2; εSr（T） --5.0 to --30.7） and are less contaminated than the Serra da Previdencia and Nova Brasilandia ones. The generation of the basaltic magma is related to the subduction of an oceanic slab below the peridotite wedge （intraoceanic arc setting）. Fluids and/or small melts from the slab impregnated the mantle. The Nova Brasilandia Sequence （Sunsas-Aguapef province） comprises a metasedimentary sequence intruded by 1.10-1.02 Ga metadia- bases, gabbros, meta-gabbros, and amphibolites associated with granitic plutons （bimodal mag- matism）. The original tholeiitic magmas, derived from a depleted source （εNd（T） = ＋3.1 to ＋5.0）, in a proto-oceanic setting, underwent subsequent contamination by the host rocks, as indicated by the isotopic and trace element data. 相似文献
5.
Nearshore marine environments are influenced by an array of variables that can either be land-derived or of marine origin, and nearshore phytoplankton communities may differ in their taxonomic composition and biomass in response to such variables. The KwaZulu-Natal Bight (hereafter referred to as ‘the bight’) is an oligo-mesotrophic, nearshore oceanic environment, that is influenced by both terrestrial run-off and upwelling. A microphytoplankton survey of the bight conducted over several stations and depths and two seasons was conducted in order to ascertain species composition, abundance and biomass. Microphytoplankton abundance was generally low (a maximum of 180 000 cells l–1 was recorded) but differed considerably between sites and seasons. A total of 99 taxa of mainly Bacillariophyceae and some Dinophyceae, Prymnesiophyceae and Cyanophyceae were identified in the present study. In the central bight, higher abundance and biomass were measured in February (wet season), which may be a possible consequence of terrestrial nutrient inputs. In the northern and southern bight we measured higher abundance and biomass in August (dry season). Upwelling was not detected during the study, but an influence of terrestrial nutrient sources was detected at the coastal stations. Turbid conditions were specific to the site near the Thukela River mouth and possibly influenced abundance, biomass and species composition at this site. Historic data on microphytoplankton composition are scarce, but comparisons with surveys from the 1960s reveal that around 60% of the common diatoms recorded then also occurred in the present study. Small taxa [20–200 µm] dominated the microphytoplankton community. Community composition was fairly uniform throughout the bight in both seasons, dominated in general by Chaetoceros species, and on occasion co-dominated by Thalassionema nitzschioides and Dactyliosolen fragilissimus. 相似文献
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7.
Comparison of numerical hindcasted severe waves with Doppler radar measurements in the North Sea 总被引：1，自引：1，他引：0
Severe sea states in the North Sea present a challenge to wave forecasting systems and a threat to offshore installations such as oil and gas platforms and offshore wind farms. Here, we study the ability of a third-generation spectral wave model to reproduce winter sea states in the North Sea. Measured and modeled time series of integral wave parameters and directional wave spectra are compared for a 12-day period in the winter of 2013–2014 when successive severe storms moved across the North Atlantic and the North Sea. Records were obtained from a Doppler radar and wave buoys. The hindcast was performed with the WAVEWATCH III model (Tolman 2014) with high spectral resolution both in frequency and direction. A good general agreement was obtained for integrated parameters, but discrepancies were found to occur in spectral shapes. 相似文献
8.
Lena Virgínia Soares Monteiro Jorge Silva Bettencourt Caetano Juliani Tolentino Flvio de Oliveira 《Gondwana Research》2007,11(3):362-381
The Vazante Group hosts the Vazante nonsulfide zinc deposit, which comprises high-grade zinc silicate ore (ZnSiO4), and late-diagenetic to epigenetic carbonate-hosted sulfide-rich zinc deposits (e.g. Morro Agudo, Fagundes, and Ambrósia). In the sulfide-rich deposits, hydrothermal alteration involving silicification and dolomitization was related with ground preparation of favorable zones for fluid migration (e.g. Fagundes) or with direct interaction with the metalliferous fluid (e.g. Ambrósia). At Vazante, hydrothermal alteration resulted in silicification and dolomite, siderite, jasper, hematite, and chlorite formation. These processes were accompanied by strong relative gains of SiO2, Fe2O3(T), Rb, Sb, V, U, and La, which are typically associated with the nonsulfide zinc mineralization. All sulfide-rich zinc ores in the district display a similar geochemical signature suggesting a common metal source from the underlying sedimentary sequences.Oxygen and carbon isotope compositions of hydrothermally altered rocks reveal a remarkable alteration halo at the Vazante deposit, which is not a notable feature in the sulfide-rich deposits. This pattern could be attributed to fluid mixing processes involving the metalliferous fluid and channelized meteoric water, which may control the precipitation of the Vazante nonsulfide ore. Sulfide deposition resulted from fluid–rock interaction processes and mixing between the ascending metalliferous fluids and sulfur-rich tectonic brines derived from reduced shale units. 相似文献
9.
Rivers receiving acid mine drainage (AMD) are frequently depauperate in fish and impacts may extend long distances downstream. AMD inputs may form chemical barriers for migratory species and isolate fish in unimpacted headwaters. We investigated the response of a diadromous fish, kōaro (Galaxias brevipinnis), to remediation of an AMD tributary in a 5th order river in New Zealand. A 2005 survey indicated limited recruitment of kōaro in the river likely due to the chemical barrier of AMD. By 2010, water treatment in the contaminated tributary had raised pH from a median value of 4.3 to 6 and reduced metals in the lower river, notably aluminium from a median of 2.48 to 0.41?mg/L. In 2012, kōaro density had increased by an order of magnitude relative to 2005. Furthermore, a greater proportion of juvenile fish were present. These results indicate that large-scale remediation of discharges can reverse the impacts of AMD on fish migration. 相似文献
10.
大别造山带北缘后碰撞富钾火山岩：地球化学与岩石成因 总被引：12，自引：10，他引：12
大别造山带北缘晚中生代富钾火山岩分布在磨子潭-晓天断裂以北的上叠式火山盆地中，主要为一套以钾玄岩-粗安岩-安粗岩-粗面岩为主体的中偏碱性岩石组合，晚期出现少量碱性火山岩。化学成分上具有富碱、富钾、贫钛、氧化系数较高等特点。岩石的Rb、Ba、Th、Pb等大离子亲石元素含量高，富轻稀土，La/Nb、Ba/Nb及LREE/HREE比值高，并且有显著的Nb、Ti负异常和Pb正异常，而铕异常则不明显。富钾火山岩的Isr值较高（=0.70872-0.70895）,εNd(t)值显著偏低（=-14.62--18.51）。根据对岩石产出动力地质背景及地球化学特征的综合分析，结合同位素组成的混合模拟，表明本区富钾火山岩最可能起源于受俯冲陆壳析出流体交代作用所形成的富集地幔（EM I）的部分熔融。 相似文献