全文获取类型
收费全文 | 111篇 |
免费 | 1篇 |
专业分类
大气科学 | 2篇 |
地球物理 | 6篇 |
地质学 | 77篇 |
海洋学 | 15篇 |
天文学 | 8篇 |
自然地理 | 4篇 |
出版年
2020年 | 3篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 8篇 |
2010年 | 4篇 |
2009年 | 17篇 |
2008年 | 5篇 |
2007年 | 7篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2004年 | 8篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有112条查询结果,搜索用时 36 毫秒
1.
Jaap Tinbergen 《Astrophysics and Space Science》2003,288(1-2):3-14
Measurement of circular polarization is mostly looked upon as a specialist craft, applied by polarization freaks to answer uninteresting questions. This paper attempts to correct that view: some important questions can only be tackled by circular polarimetry, there is nothing very special about Stokes V and its measurement is entirely analogous to that of Q and U.Radio and optical polarimetry are covered, using both single telescopes and interferometers. 相似文献
2.
Jaap S. Sinninghe Damst Marcel M.M. Kuypers Richard D. Pancost Stefan Schouten 《Organic Geochemistry》2008,39(12):1703
The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ13C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C31 and C32 hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ13CTOC with the δ13C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ13C values of S-bound phytane and C35 hopane were also used to estimate pCO2 levels. Before the OAE burial event, pCO2 levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO2 levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO2 levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO2 levels. 相似文献
3.
Andrea Jaeschke Michael D. Lewan Ellen C. Hopmans Stefan Schouten Jaap S. Sinninghe Damst 《Organic Geochemistry》2008,39(12):1735
Anaerobic ammonium oxidation (anammox) has been recognized as a major process resulting in loss of fixed inorganic nitrogen in the marine environment. Ladderane lipids, membrane lipids unique to anammox bacteria, have been used as markers for the detection of anammox in marine settings. However, the fate of ladderane lipids after sediment burial and maturation is unknown. In this study, anammox bacterial cell material was artificially matured by hydrous pyrolysis at constant temperatures ranging from 120 to 365 °C for 72 h to study the stability of ladderane lipids during progressive dia- and catagenesis. HPLC-MS/MS analysis revealed that structural alterations of ladderane lipids already occurred at 120 °C. At temperatures >140 °C, ladderane lipids were absent and only more thermally stable products could be detected, i.e., ladderane derivatives in which some of the cyclobutane rings were opened. These diagenetic products of ladderane lipids were still detectable up to temperatures of 260 °C using GC-MS. Thus, ladderane lipids are unlikely to occur in ancient sediments and sedimentary rocks, but specific diagenetic products of ladderane lipids will likely be present in sediments and sedimentary rocks of relatively low maturity (i.e., C31 hopane 22S/(22S + 22R) ratio <0.2 or ββ/(αβ + βα + ββ) ratio of >0.5). 相似文献
4.
5.
6.
7.
Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids. 相似文献
8.
Sulphur-containing compounds in sulphur-rich crude oils from hypersaline lake sediments and their geochemical implications 总被引:1,自引:0,他引:1
Guoying Sheng Jiamo Fu S. C. Brassell A. P. Gowar G. Eglinton Jaap S. Sinninghe Damste Jan W. de Leeuw P. A. Schenck 《中国地球化学学报》1987,6(2):115-126
Three sulphur-rich commercial crude oils have been studied, which contain sulphur as high as up to 4–12%. These samples were
collected from Tertiary hypersaline lake sediments of the Jianghan Basin, Hubei Province at different depths, but above the
oil generation threshold (2200m). FPD-GC and GC-MS data show that aromatic fractions of the crude oils are composed of different
homologues of sulphur-containing compounds, including long-chain normal alkyl-thiophenes and-thiolanes, long-chain isoprenoid-thiophenes
and -thiolanes, and benzothiophenes. It is worth noting that the distribution patterns of long-chain alkyl-thiophenes and
-thiolanes from two shallow-seated crude oils are quite similar to those of normal alkanes showing marked even-odd predominance.
It seems that the even-odd predominance of sulphur-containing compounds decreases with increasing burial depth of the crude
oils. The major component of aliphatic fraction is phytane, and similarly the major peaks of aromatic fractions also represent
C20 isoprenoid thiophenes.
Some preliminary conclusions have been drawn from the above discussion: (1) Abundant sulphur-containing compounds may be used
as an indicator of low mature or immature crude oils produced from hypersaline lake sediments; (2) Sulphur-containing compounds
are considered to be early diagenetic products of reactions between elemental sulphur or sulfides and alkanes or their precursors
(phytols, fatty acids, alcohols, etc.), or of bacterial activities, but not direct inputs of organisms. 相似文献
9.
Aoibheann A. Kilfeather Jeffrey J. Blackford Jaap J. M. van der Meer 《Pure and Applied Geophysics》2007,164(2-3):509-525
Tsunami deposits are provisionally distinguished in the field on the basis of anomalous sand horizons, fining-up and fining-landward,
coupled with organic-rich, fragmented `backwash' sediments. In this paper, micromorphological features of a sediment sequence
previously interpreted as being of tsunami origin are described. These characteristics are shown to be consistent with the
macro-scale features used elsewhere, but show additional details not seen in standard stratigraphies, including possible evidence
for individual waves, possibly wave-magnitude progression, organic fragment alignment and intraclast microstructures. Although
replication and more complete studies are needed, this analysis confirms the identification of a tsunami in Willapa Bay in
ca.1700 AD, while demonstrating a widely applicable technique for confirming or refuting possible tsunami deposits. 相似文献
10.
Microbial ecology of the stratified water column of the Black Sea as revealed by a comprehensive biomarker study 总被引:2,自引:0,他引:2
Stuart G. Wakeham Rudi Amann Katherine H. Freeman Ellen C. Hopmans Bo Barker Jrgensen Isabell F. Putnam Stefan Schouten Jaap S. Sinninghe Damst Helen M. Talbot Dagmar Woebken 《Organic Geochemistry》2007,38(12):2070-2097
The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results. 相似文献