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TIMS and SHRIMP U–Pb analyses of zircons from Milford Orthogneiss metadiorite (P = 1–1.4 GPa; T ≥ 750°C) of the Arthur River Complex of northern Fiordland reveal a bimodal age pattern. Zircons are predominantly either Paleozoic (357.0 ± 4.2 Ma) and prismatic with oscillatory zoning, or Cretaceous (133.9 ± 1.8 Ma) and ovoid with sector or patchy zoning. The younger age component is not observed overgrowing older grains. Most grains of both ages are overgrown by younger Cretaceous (~120 Ma) metamorphic zircon with very low U and Th/U (0.01). We interpret the bimodal ages as indicating initial igneous emplacement and crystallisation of a dioritic protolith pluton at ~357 Ma, followed by Early Cretaceous granulite-facies metamorphism at ~134 Ma, during which a significant fraction (~60%) of the zircon grains dissolved, and subsequently reprecipitated, effectively in situ, in partial melt pockets. The remaining ~40% of original Paleozoic grains were apparently not in contact with the partial melt, remained intact, and show only slight degrees of Pb loss. Sector zoning of the Cretaceous grains discounts their origin by solid state recrystallisation of Paleozoic grains. The alternative explanation—that the Paleozoic component represents a 40% inherited component in an Early Cretaceous transgressive dioritic magma—is considered less likely given the relatively high solubility of zircon in magma of this composition, the absence of 134 Ma overgrowths, the single discrete age of the older component, equivalent time-integrated 177Hf/176Hf compositions of both age groups, and the absence of the Cambrian-Proterozoic detrital zircon that dominates regional Cambro-Ordovician metasedimentary populations. Similar bimodal Carboniferous-Early Cretaceous age distributions are characteristic of the wider Arthur River Complex; 8 of 12 previously dated dioritic samples have a Paleozoic component averaging 51%. Furthermore, the age and chemical suite affinity of these and several more felsic rocks can be matched with those of the relatively unmetamorphosed Carboniferous plutonic terrane along the strike of the Mesozoic margin in southern Fiordland, also supporting the in situ derivation of the Carboniferous “inherited” component.  相似文献   
2.
Precise U–Pb zircon dates from three volcanic ash beds that bracket the Hangenberg Shale in the Holy Cross Mountains, Poland, constrain the age and duration of one of the most significant palaeobiological events of the Palaeozoic Era, the Hangenberg Event. It is linked to a terminal Devonian global shift from greenhouse to icehouse climate conditions, a global transgression, and widespread black shale deposition. Our results constrain the Hangenberg Event to between 358.97 ± 0.11 Ma and 358.89 ± 0.20 Ma, with a calculated duration of 0.05 +0.14/?0.05 Ma. A third, underlying ash bed yielded a distinctly older age of 359.97 ± 0.46 Ma. The duration of ~50–100 ka. for the event is comparable to those of Quaternary glaciations, and is consistent with both a glacio‐eustatic origin for the eustatic fluctuations and changes in ocean chemistry that led to this major reorganization of the biosphere.  相似文献   
3.
Using high-precision zircon U-Pb ID-TIMS geochronology, tuffs from the Chang 9 shale and the Chang 7 shale were dated. The tuff in the Chang 9 shale is 241.47 ± 0.17 Ma, which falls between the top tuff age of 241.06 ± 0.12 Ma and the bottom tuff age of 241.558 ± 0.093 Ma in the Chang 7 shale. These reveal that the Chang 9 and Chang 7 shales are contemporaneous, belonging to the Ladinian stage of the Middle Triassic. This insight expands the region of the main source rock of Chang 7 to the north...  相似文献   
4.
A new natural zircon reference material SA01 is introduced for U‐Pb geochronology as well as O and Hf isotope geochemistry by microbeam techniques. The zircon megacryst is homogeneous with respect to U‐Pb, O and Hf isotopes based on a large number of measurements by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) and secondary ion mass spectrometry (SIMS). Chemical abrasion isotope dilution thermal ionisation mass spectrometry (CA‐ID‐TIMS) U‐Pb isotopic analyses produced a mean 206Pb/238U age of 535.08 ± 0.32 Ma (2s, n = 10). Results of SIMS and LA‐ICP‐MS analyses on individual shards are consistent with the TIMS ages within uncertainty. The δ18O value determined by laser fluorination is 6.16 ± 0.26‰ (2s, n = 14), and the mean 176Hf/177Hf ratio determined by solution MC‐ICP‐MS is 0.282293 ± 0.000007 (2s, n = 30), which are in good agreement with the statistical mean of microbeam analyses. The megacryst is characterised by significant localised variations in Th/U ratio (0.328–4.269) and Li isotopic ratio (?5.5 to +7.9‰); the latter makes it unsuitable as a lithium isotope reference material.  相似文献   
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