The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana     

Frank D. Eckardt  Robert G. Bryant  Graham McCulloch  Baruch Spiro  Warren W. Wood 《Applied Geochemistry》2008

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.  相似文献   

Pb−Sr−Nd−O isotopic constraints on the origin of rhyolites from the Taupo Volcanic Zone of New Zealand: evidence for assimilation followed by fractionation from basalt   总被引：1，自引：0，他引：1  

M. T. McCulloch  T. K. Kyser  J. D. Woodhead  L. Kinsley 《Contributions to Mineralogy and Petrology》1994,115(3):303-312

A comprehensive Sr–Nd–Pb–O isotopic study is reported for rhyolites from the Maroa Volcanic Centre in the Taupo Volcanic Zone (TVZ) of New Zealand. The Sr–Nd isotopic compositions of the rhyolites (⁸⁷Sr/⁸⁶Sr=0.705236 to 0.705660 and _Nd = 2.0 to 0.2) are intermediate between those of primitive basalts (⁸⁷Sr/⁸⁶Sr=0.70387 and _Nd = 5.3) and the Torlesse basement (⁸⁷Sr/⁸⁶Sr=0.709 and _Nd = -4.5). The relatively low mantle-like oxygen isotopic compositions of ¹⁸ O = 7 ± 0.5 are consistent with the Nd-Sr isotopic constraints in that they can be accounted for by 15% to 25% crustal contamination of a basaltic parent by relatively ¹⁸ O-rich Torlesse metasediment. High precision Pb isotopic analyses of plagioclase separates from the Maroa rhyolites show that they have essentially the same compositions as the Torlesse metasedimentary terrane which is itself distinctive from the Western or Waipapa metasediments. Due to the high concentration of Pb in the Torlesse metasediments (>20 ppm) compared to the basalts (<2 ppm), the Pb isotopic composition of the volcanics may be controlled by relatively small amounts (>10%) of crustal contamination. All these results are shown to be consistent with derivation of the rhyolites by 15% to 25% contamination of relatively primitive basaltic magmas with Torlesse metasedimentary crust, followed by extensive, essentially closed system fractionation of the basalt to a magma of rhyolite composition. It is argued that the processes of assimilation and fractionation are separated in both space and time. The voluminous high silica rhyolites, which make up >97% of the exposed volcanism in the continental margin back-are basin environment of the TVZ, therefore appear to be a product of predominantly new additions to the crust with assimilation-recycling of pre-existing crust being of secondary importance.  相似文献   

Transparency: aid or obstacle to effective defence of vulnerable environments from reservoir construction? Dam decisions and democracy in North East England     

Christine S McCulloch 《Area》2006,38(1):24-33

Public participation in transparent decisionmaking has been proposed as a panacea for environmental protection. Bargaining theory suggests drawbacks to transparency such as hardening of attitudes and intransigence. Yet achievement of consensus on environmental values for integrated water resource management demands public involvement. Historical study of attempts to prevent reservoir construction in upland valleys designated for protection of nature suggests that 'closed-door' bargaining proved more effective for environmentalists than open, public debate. Records now open for analysis of disputes over Teesdale and Farndale, 1950–1970, allow comparisons to be made between behind-the-scenes deliberations and 'open-door' public discussion. The ambition of progressing from public participation to devolution of environmental decisionmaking and responsibility to the local scale demands more conceptualization of the process of decisionmaking on water resource development.  相似文献   

Porites corals as recorders of mining and environmental impacts: Misima Island, Papua New Guinea   总被引：1，自引：0，他引：1  

Stewart J. Fallon  Jamie C. White†Malcolm T. McCulloch 《Geochimica et cosmochimica acta》2002,66(1):45-62

In 1989 open-cut gold mining commenced on Misima Island in Papua New Guinea (PNG). Open-cut mining by its nature causes a significant increase in sedimentation via the exposure of soils to the erosive forces of rain and runoff. This increased sedimentation affected the nearby fringing coral reef to varying degrees, ranging from coral mortality (smothering) to relatively minor short-term impacts. The sediment associated with the mining operation consists of weathered quartz feldspar, greenstone, and schist. These rocks have distinct chemical characteristics (rare earth element patterns and high abundances of manganese, zinc, and lead) and are entering the near-shore environment in considerably higher than normal concentrations. Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we analyzed eight colonies (two from high sedimentation, two transitional, two minor, and two unaffected control sites) for Y, La, Ce, Mn, Zn, and Pb. All sites show low steady background levels prior to the commencement of mining in 1988. Subsequently, all sites apart from the control show dramatic increases of Y, La, and Ce associated with the increased sedimentation as well as rapid decreases following the cessation of mining. The elements Zn and Pb exhibit a different behavior, increasing in concentration after 1989 when ore processing began and one year after initial mining operations. Elevated levels of Zn and Pb in corals has continued well after the cessation of mining, indicating ongoing transport into the reef of these metals via sulfate-rich waters. Rare earth element (REE) abundance patterns measured in two corals show significant differences compared to Coral Sea seawater. The corals display enrichments in the light and middle REEs while the heavy REEs are depleted relative to the seawater pattern. This suggests that the nearshore seawater REE pattern is dominated by island sedimentation. Trace element abundances of Misima Island corals clearly record the dramatic changes in the environmental conditions at this site and provide a basis for identifying anthropogenic influences on corals reefs.  相似文献   

Source of trace element variability in Great Barrier Reef corals affected by the Burdekin flood plumes     

Chantal Alibert  Les Kinsley  Malcolm T. McCulloch  Felicity McAllister 《Geochimica et cosmochimica acta》2003,67(2):231-246

Massive corals in the Great Barrier Reef, analyzed at high-resolution for Sr/Ca (thermal ionization mass spectrometry) and trace elements such as Ba and Mn (laser ablation inductively coupled plasma mass spectrometry), can provide continuous proxy records of dissolved seawater concentrations, as well as sea surface temperature (SST). A 10-yr record (1989 to 1998) from Pandora Reef, an inshore reef regularly impacted by the freshwater plumes of the Burdekin River, is compared with an overlapping record from a midshelf reef, away from runoff influences. Surface seawater samples, taken away from river plumes, show little variability for Sr/Ca (8484 ± 10 μmol/mol) and Ba (33.7 ± 0.7 nmol/kg). Discrete Ba/Ca peaks in the inshore coral coincide with flood events. The magnitude of this Ba/Ca enrichment is most likely controlled by the amount of suspended sediments delivered to the estuary, which remains difficult to monitor. The maximum flow rate at peak river discharge is used here as a proxy for the sediment load and is shown to be strongly correlated with coral Ba/Ca (r = 0.97). After the wet summer of 1991, the coral Ba/Ca flood peak is followed by a plateau that lingers for several months after dissipation of plume waters, signifying an additional flux of Ba that may originate from submarine groundwater seeps and/or mangrove reservoirs. Both Mn and Y are enriched by a factor of ∼5 in inshore relative to midshelf corals. Mn/Ca ratios show a seasonal cycle that follows SST (r = 0.7), not river discharge, with an additional high variability in summer suggesting a link with biological activity. P and Cd show no significant seasonal variation and are at a low level at both inshore and midreef locations. However, leaching experiments suggest that part of the coral P is not lattice bound.  相似文献   

Evolution of the early Earth: Constraints from Nd---Nd isotopic systematics     

Malcolm T. McCulloch  Victoria C. Bennett 《Lithos》1993,30(3-4):237-255

Combined ¹⁴⁷Sm---¹⁴³Nd and the now extinct [τ(1/2)₁₄₆=103×10⁶ yr] ¹⁴⁶Sm---¹⁴²Nd isotopic systematics are reported for early Archean gneisses from Greenland (Amîtsoq and Akilia associations), and Canada (Acasta gneiss). Using both field relationships and high resolution U---Pb SHRIMP ion-probe ages, it has been possible to identify the most ancient rocks in these terrains for isotopic analyses. Preliminary ¹⁴²Nd analyses of a still limited number of samples have failed to identify terrestrial ¹⁴²Nd anomalies. Effects, if present, are limited to < 10 ppm and we have thus been unable to confirm the +33±4 ppm ε₁₄₂ value claimed by Harper and Jacobsen (1992a, b) for a single sample. From the lack of ¹⁴⁶Sm---¹⁴²Nd effects we infer that large-scale fractionation events that may have occurred in the first 200 Ma of Earth history did not leave a significant nor widespread imprint on the early Archean mantle or crust. If a terrestrial magma ocean, with associated LREE fractionation, formed as a result of planetary accretion, then it had a lifetime of at most 250 m.y. before being remixed into the Earth's mantle.

The samples analysed in this study have a range of ε₁₄₃ values including highly positive values of up to +4.2. This requires that the earliest known Archean crust was differentiated from a reservoir that was strongly depleted in the LREE as compared with chondritic compositions. In the early Archean it is proposed that the depletions in LREE are a consequence of extraction of a limited fraction of the Earth's continental crust ( < 10%) from the upper 200 km of the mantle. A three reservoir model, consisting of the continental crust, depleted mantle and a more primitive mantle reservoir can be extended to account for both the present-day, as well as the evolving Nd isotopic composition of the Earth's crust and mantle. In contrast to previous models, the rate of growth of the continental crust is used as an input parameter to constrain the concomitant growth and evolution of the depleted mantle reservoir. Recycling of large volumes of bulk continental crust into the mantle is not considered to be an important process, nor is the existence of an additional major enriched component in the early Archean mantle.  相似文献   

Genesis of granitoid batholiths of Peninsular Malaysia and implications for models of crustal evolution: Evidence from a NdSr isotopic and UPb zircon study     

T.C Liew  M.T McCulloch 《Geochimica et cosmochimica acta》1985,49(2):587-600

Nd, Sr and U-Pb isotopic data for the late Triassic West Coast Province batholiths and Permian to Triassic East Coast Province batholiths of Peninsular Malaysia allow estimates of the ages of the crustal fragments comprising the peninsula to be made. Initial ?_Nd and ?_Sr values for granitoids from the West Coast Province range from ?6 to ?10 and +160(0.716) to +660(0.751) respectively. Nd model ages calculated based on a depleted mantle evolution model (T_DM^Nd) range from 1300 Ma to 1800 Ma and are in general agreement with the mid-Proterozoic upper intersection ages of U-Pb zircon reverse discordia (1500–1700 Ma). Initial ?_Nd and ?_Sr values for granitoids from the East Coast Province range from ?0.8 to ?6 and +10(0.705) to +130(0.714) respectively. Calculated T_DM^Nd ages of 900–1400 Ma for these granitoids are comparable to two U-Pb zircon reverse discordia intercepts that yield 800 Ma and 1350 Ma. The general agreement of U-Pb zircon inheritance ages and T_DM^Nd ages are interpreted to correspond to the Proterozoic ‘crust formation’ ages of the continental fragments represented by the West Coast and East Coast batholithic provinces. Mid-Proterozoic (~ 1300–1900 Ma) ‘crust formation’ ages are commonly shown by other Phanerozoic continental margin plutonic and volcanic belts. The ubiquitous mid-Proterozoic ‘crust formation’ ages and the absence of Archaean signatures suggest voluminous juvenile additions to the continental crust in the mid-Proterozoic. Such ages at continental margins would imply that many continental blocks had achieved very much their present-day extent by the mid-Proterozoic.  相似文献   

Nd-Sr isotopic and geochemical systematics in Cambrian boninites and tholeiites from Victoria,Australia     

D. R. Nelson  A. J. Crawford  M. T. McCulloch 《Contributions to Mineralogy and Petrology》1984,88(1-2):164-172

Rocks with boninitic affinities have been recognised in a number of ophiolites, including the Cambrian Heathcote and Mt Wellington Greenstone Belts of Victoria. Boninites and high-Mg andesites from the Heathcote Greenstone Belt show a restricted range of initial _Nd values of between +3.3 to +5.8. Extremely refractory boninites from the Mt Wellington Greenstone Belt have _Nd ranging from +1.3 to –9. Ti/Zr is positively correlated with Sm/Nd with the Heathcote lavas generally possessing greater depletion of Ti and enrichment of Zr relative to the middle and heavy REE with increasing LREE/HREE. These data are consistent with the generation of boninites by partial melting of refractory peridotite following invasion by LREE- and Zr-enriched, low _Nd fluids. Tholeiites overlying the boninites in both greenstone belts have flat REE patterns and _Nd+5, lower than that anticipated for lavas derived from depleted MORB source reservoirs in the Cambrian, suggesting that their source was also contaminated by a LREE-enriched, low _Nd component similar to that involved in the generation of the Howqua boninites. The added components have characteristics compatible with their derivation from subducted altered oceanic crust and/or from wet subducted sediments. The identification of boninites and other low-Ti lavas in the Victorian greenstone belts is strong evidence for island arc development in southeastern Australia during the Lower Cambrian and provides further support for a subduction-related origin for many ophiolites.  相似文献   

SmNd isotopic systematics of Enderby Land granulites and evidence for the redistribution of Sm and Nd during metamorphism     

M.T. McCulloch  L.P. Black 《Earth and Planetary Science Letters》1984,71(1):46-58

Measurements of¹⁴³Nd/¹⁴⁴Nd and¹⁴⁷Sm/¹⁴⁴Nd are reported for whole rocks and mineral separates from granulites of the Napier Complex at Fyfe Hills. Charnockites, leuconorites and gabbros yield a whole rock SmNd isochron age of3060 ± 160m.y. and an initial¹⁴³Nd/¹⁴⁴Nd ratio of0.50776 ± 10 (?_Nd(3060m.y.) = ?2.0 ± 1.8). The negative ?_Nd value and the presence of geologically induced dispersion in the data suggest that the isochron age does not represent the time of primary crystallization of the complex but instead indicates a time of later redistribution of Sm and Nd and partial re-equilibration of¹⁴³Nd/¹⁴⁴Nd ratios. This probably occurred during the upper granulite facies metamorphism which has also been dated at～ 3100m.y. by RbSr and UPb zircon studies [1]. Coexisting clinopyroxene, apatite and total rock fractions in two adjacent samples define an approximately linear array corresponding to an age of 2300 ± 300 m.y. This array indicates that redistribution of Sm and Nd and re-equilibration of¹⁴³Nd/¹⁴⁴Nd ratios occurred on an intermineral scale during the upper amphibolite to lower granulite facies metamorphism at～ 2450m.y.Due to the resetting of the SmNd system on both whole rock and mineral scales, the primary crystallization age of the igneous protolith is not well constrained by the present data, although it is clearly3100m.y. If it is assumed that the complex was derived initially from a depleted mantle reservoir(?_Nd(T) ? 2), evolution of the negative ?_Nd value of ?2.0 with the observed Sm/Nd ratios requires a prehistory of～ 380m.y. This implies a primary age of～ 3480m.y. However, substantially older primary ages can be inferred if the source reservoirs had?_Nd(T) > 2 and/or substantial reductions in the Sm/Nd ratio occurred in whole rocks during the granulite facies metamorphism at 3100 m.y. Such an inferred reduction in the Sm/Nd ratio may have been the result of preferential loss of Sm relative to Nd, or introduction of a low Sm/Nd fluid with?_Nd ≥ 0 during granulite facies metamorphism.  相似文献   

皖南和赣东北蛇绿岩成因及其构造意义：元素和Sm－Nd同位素制约   总被引：32，自引：0，他引：32  

赵建新  李献华  周国庆  邢凤鸣 《地球化学》1995,(4)

本文对扬子块体南缘构造侵位于板溪群（及相应地层）的皖南和赣东北晚元古代蛇绿岩进行了系统的元素和Ｓｍ－Ｎｄ同位素地球化学研究，结果表明两套蛇绿岩具有类似的元素地球化学特征，即二者的火山岩元素地球化学特征均类似于形成于弧后盆地构造环境的拉斑玄武岩。但是，两套蛇绿岩的Ｎｄ同位素组成明显不同。赣东北蛇绿岩具有相当均一的高εＮｄ（Ｔ）值（＋５．５±１．２），表明来源于一较亏损的上地幔源区，并且没有受到明显的较成熟地壳物质的混染。相反，皖南蛇绿岩的εＮｄ（Ｔ）值低，并有较大的变化范围（＋４．５──１．０），并和Ｓｍ／Ｎｄ、Ｎｄ、ＭｇＯ、ＳｉＯ２呈明显的二元混合相关关系，表明蛇绿岩是由亏损幔源岩浆（初始εＮｄ（Ｔ）≈＋５．５）在结晶分异过程中与地壳组分（初始εＮｄ（Ｔ）≈－１）混合形成的。皖南和赣东北蛇绿岩的Ｎｄ同位素和元素地球化学特征以及该地区的同时代花岗岩和火山岩的时空分布特征，可以用华南和扬子元古宙陆－弧－陆碰撞模式来解释。大约在１．０Ｇａ前，扬子和华南块体之间存在一多岛弧洋盆。大陆边缘岛弧和大洋岛弧在扬子块体南缘发育演化。皖南和赣东北蛇绿岩就是在大陆边缘盆地和弧间盆地演化过程中形成的洋壳构造侵位的碎片。该地区Ｉ型  相似文献