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Groundwater mixing between different aquifer types in a complex structural setting discerned by elemental and stable isotope geochemistry 
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下载免费PDF全文 Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ13C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ13C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ18O and δD ratios during the fall [δ18O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ18O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Marlon M. Jean John W. Shervais Sung-Hi Choi Samuel B. Mukasa 《Contributions to Mineralogy and Petrology》2010,159(1):113-136
The middle Jurassic Coast Range Ophiolite (CRO) is one of the most important tectonic elements in western California, cropping
out as tectonically dismembered elements that extend 700 km from south to north. The volcanic and plutonic sections are commonly
interpreted to represent a supra-subduction zone (SSZ) ophiolite, but models specifying a mid-ocean ridge origin have also
been proposed. These contrasting interpretations have distinctly different implications for the tectonic evolution of the
western Cordillera in the Jurassic. If an SSZ origin is confirmed, we can use the underlying mantle peridotites to elucidate
melt processes in the mantle wedge above the subduction zone. This study uses laser ablation–inductively coupled plasma–mass
spectrometry (LA–ICP–MS) to study pyroxenes in peridotites from four mantle sections in the CRO. Trace element signatures
of these pyroxenes record magmatic processes characteristic of both mid-ocean ridge and supra-subduction zone settings. Group
A clinopyroxene display enriched REE concentrations [e.g., Gd (0.938–1.663 ppm), Dy (1.79–3.24 ppm), Yb (1.216–2.047 ppm),
and Lu (0.168–0.290 ppm)], compared to Group B and C clinopyroxenes [e.g., Gd (0.048–0.055 ppm), Dy (0.114–0.225 ppm), Yb
(0.128–0.340 ppm), and Lu (0.022–0.05 ppm)]. These patterns are also evident in orthopyroxene. The differences between these
geochemical signatures could be a result of a heterogeneous upper mantle or different degrees of partial melting of the upper
mantle. It will be shown that CRO peridotites were generated through fractional melting. The shapes of REE patterns are consistent
with variable degrees of melting initiated within the garnet stability field. Models call for 3% dry partial melting of MORB-source
asthenosphere in the garnet lherzolite field for abyssal peridotites and 15–20% further partial melting in the spinel lherzolite
field, possibly by hydrous melting for SSZ peridotites. These geochemical variations and occurrence of both styles of melting
regimes within close spatial and temporal association suggest that certain segments of the CRO may represent oceanic lithosphere,
attached to a large-offset transform fault and that east-dipping, proto-Franciscan subduction may have been initiated along
this transform. 相似文献
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Juliano Kuchle Claiton Marlon dos Santos Scherer Christian Correa Born Renata dos Santos Alvarenga Felipe Adegas 《Journal of South American Earth Sciences》2011,31(4):358-371
The Dom João Stage comprises an interval with variable thickness between 100 and 1200 m, composed of fluvial, eolian and lacustrine deposits of Late Jurassic age, based mainly on the lacustrine ostracod fauna (although the top deposits may extend into the Early Cretaceous). These deposits comprise the so-called Afro-Brazilian Depression, initially characterized as containing the Brotas Group of the Recôncavo Basin (which includes the Aliança and the Sergi Formations) and subsequently extended into the Tucano, Jatobá, Camamu, Almada, Sergipe, Alagoas and Araripe Basins in northeastern Brazil, encompassing the study area of this paper. The large occurrence area of the Dom João Stage gives rise to discussions about the depositional connectivity between the basins, and the real extension of sedimentation. In the first studies of this stratigraphic interval, the Dom João Stage was strictly associated with the rift phase, as an initial stage (decades of 1960–70), but subsequent analyses considered the Dom João as an intracratonic basin or pre-rift phase – without any relation to the active mechanics of a tectonic syn-rift phase (decades of 1980–2000). The present work developed an evolutionary stratigraphic and tectonic model, based on the characterization of depositional sequences, internal flooding surfaces, depositional systems arrangement and paleoflow directions. Several outcrops on the onshore basins were used to build composite sections of each basin, comprising facies, architectural elements, depositional systems, stratigraphic and lithostratigraphic frameworks, and paleocurrents. In addition to that, over a hundred onshore and offshore exploration wells were used (only 21 of which are showed) to map the depositional sequences and generate correlation sections. These show the characteristics and relations of the Dom João Stage in each studied basin, and they were also extended to the Gabon Basin. The results indicate that there were two main phases during the Dom João Stage, in which distinctive sedimentary environments were developed, reflecting depositional system arrangements, paleoflow directions were diverse, and continuous or compartmented basins were developed. 相似文献
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Study of Metal Distribution in Raw and Screened Swine Manure 总被引：1，自引：0，他引：1
Ricardo Luís Radis Steinmetz Airton Kunz Valderi Luiz Dressler Érico Marlon de Moraes Flores Ayrton Figueiredo Martins 《洁净——土壤、空气、水》2009,37(3):239-244
The growth of industrial swine production over the last few years has led to a growth in concern over effluents generated by the activity. Several elements, mainly toxic metals, can be present in swine wastewater and can have a serious environmental impact. It is important, therefore, to know the metal concentration before the discharge of wastewater. In this work the temporal metal distribution in swine manure and its potential reduction using coarse (2 mm) and fine (<0.45 μm) liquid‐solid separation techniques were investigated. In order to do this, different swine manure sample preparation methods for Al, Ba, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr and Zn determination by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were tested. The acid mixtures used to digest the manure sample significantly affected the metal recovery. Good analyte recoveries were observed with nitric acid/hydrogen peroxide mixtures or nitric acid/perchloric acid mixtures. Sulfuric acid/hydrogen peroxide mixtures produced inconsistent results and poor recoveries, mainly for Ba and Pb. It was observed that metal concentrations in swine manure varied greatly with time, up to one order of magnitude, due to changes in swine production such as feed and animal numbers. Metals concentrations observed in the raw wastewater exceeded Brazilian limits for discharge into water bodies and recommendations for agricultural use. Results obtained from the liquid‐solid separation study showed that metals in the raw swine manure were not removed with coarse screening. However, the major fraction of metals were removed by filtration (0.45 μm), with the exception of Na, K and Sr. Thus, the use of liquid‐solid separation techniques that capture the fine solid fractions (and associated metals) from raw manure can have a favorable impact on the environment and contribute to swine production wastewater treatment. 相似文献
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The relationship between nitrogen (N) and phytoplankton chlorophyll a (Chl) establishes a basis for understanding eutrophication in coastal marine ecosystems. A substantial literature exists
on cross-ecosystem analysis of this relationship, but there is little information on cross-scale patterns. A collection of
observational records in Bedford Basin (Canada) was used to construct the N–Chl relationship at four time scales: intra-day,
intra-annual, interannual, and interdecadal. Additionally, a dataset of contingent observations from 16 biogeochemical ocean
provinces was used to construct the N–Chl relationship at large spatial scale. In Bedford Basin, N statistically predicts
Chl at time scales that are short (intra-day, intra-annual) and long (interdecadal) but not intermediate (interannual). There
is an apparent stoichiometric regularity in the dependence of Chl on N that crosses time scales. Further, an apparent similitude
exists between the local pattern at long time scale and the global pattern at large space scale. 相似文献
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José Tasso Felix Guimarães Marcelo Cancela Lisboa Cohen Marlon Carlos França Luiz Carlos Ruiz Pessenda Eduardo de Jesus Souza Afonso César Rodrigues Nogueira Ronnie Alves 《地球表面变化过程与地形》2013,38(13):1535-1549
The goal of this work was to understand the main hydrodynamic processes acting on tidal flats of the coast of Amapá near the mouth of the Amazon River, and how they change over the short term (~ 20 years). The analysis of morphological and geobotanical units was carried out by applying processing and interpretation methods to optical and synthetic aperture radar (SAR) images, combined with data on water salinity, maximum flood height, sedimentary facies data, rainfall and river discharge. The temporal analysis of morphological and geobotanical units suggests the relative stabilization of savannah, ‘várzea’ and mangrove areas during the drier period and increasing tidal amplitude between 1987 to 1997. The wetter period and decreasing tidal amplitude between 1997 to 2008 led to an increase in the area of ‘várzea’ and lakes over savannah, and the expansion of mangroves mainly over the inundated field and tidal mud/mixed flats. Therefore, the decrease in rainfall index during the drier period is well‐correlated with the reduction of the Calçoene River discharge and jointly with increasing tidal amplitude favored the increase of migration rate of the mud bank and erosion profile along the littoral. It was followed by the increase of the Calçoene River discharge and jointly with decreasing tidal amplitude during the wetter period, favoring the development of mangroves on muddy substrates near the coastline. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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