Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters     

J.A. Saunders  M.-K. Lee  M. Shamsudduha  P. Dhakal  A. Uddin  M.T. Chowdury  K.M. Ahmed 《Applied Geochemistry》2008

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.  相似文献   

Third order contribution to the wave-making resistance of a ship at finite depth of water     

Shahjada Tarafder  Md 《Ocean Engineering》2007,34(1):32-44

This paper presents a potential based boundary element method for solving a nonlinear free surface flow problem for a ship moving with a uniform speed in finite depth of water. The free surface boundary condition is linearized by the systematic method of perturbation in terms of a small parameter up to third order. The surfaces are discretized into flat quadrilateral elements and the influence coefficients are calculated by Morino's analytical formula. Dawson's upstream finite difference operator is used in order to satisfy the radiation condition. The second order solution gives better result than the first or third order solution. So the present method with the second order solution can be adopted as a powerful tool for the hydrodynamic analysis of the thin ship in finite depth of water.  相似文献   

Destroying hills in the northeastern part of Bangladesh: A qualitative assessment of extent of the problem and its probable impact     

Md. Sirajul Islam  G. M. Jahid Hasan  Md. Aktarul Islam Chowdhury 《International Journal of Environmental Science and Technology》2006,2(4):301-308

Indiscriminate cutting of hills in the Sylhet region has become a major environmental issue. The nature and life style of Sylhet intimately related with the hills are thus under the threat of a drastic imbalance in its ecosystem. Due to such hill cutting the mostly affected sectors of this region will be its weather and climate, geomorphology and hydrology, and the indigenous flora and fauna. As a result the frequency of natural calamities like earthquake, flash flooding etc may increase considerably. Deforestation and resulting increased soil erosion, decreased ground water recharge and deteriorated water quality might also be as consequences of such hill cutting. This paper investigates the cause and extent of the problem along with its probable impact and finally suggests actions for conservation of hills for ecological balance of the region.  相似文献   

Slow arsenic poisoning of the contaminated groundwater users     

M. M. Uddin  A. K. M. Harun-Ar-Rashid  S. M. Hossain  M. A. Hafiz  K. Nahar  S. H. Mubin 《International Journal of Environmental Science and Technology》2006,3(4):447-453

This paper gives impact of Arsenic contaminated water on human health as well as overview of the extent and severity of groundwater arsenic contamination in Bangladesh. Scalp hair is the most important part of the human body to monitor the accumulation of this type of poison. Therefore, an experiment has been carried out by Neutron Activation Analysis (NAA) at Atomic Energy Research Establishment (AERE), Savar, Dhaka, Bangladesh on human hair of corresponding tube well water users of these areas to determine the total accumulation of arsenic to their body. Hair samples collected from the region where the groundwater was found highly contaminated with arsenic. The obtained results of arsenic concentration in the lower age (Hb) categories of users (below 12 years of age users) is in the range of 0.33 to 3.29 /gmg/g (ppm) and that in the Hu categories (upper 12 years of age users) is 0.47 to 6.64 μg/g (ppm). Where as maximum permissible range is 1 ppm certified from WHO. Results show that the peoples are highly affected where the groundwater is highly contaminated with arsenic and acts as the primary source of arsenic poisoning among the peoples of those areas. The results indicate that human population is affected with arsenic locally using the contaminated water for a long time.  相似文献   

Impact of Southern Oscillation on the Frequency of Monsoon Depressions in the Bay of Bengal     

Singh  O. P.  Ali Khan  Tariq Masood  Rahman  Md. Sazedur 《Natural Hazards》2002,25(2):101-115

The impact of Southern Oscillation on thecyclogenesis over the Bay of Bengal duringthe summer monsoon has been investigated.The analysis of correlation coefficients(CCs) between the frequency of monsoondepressions and the Southern OscillationIndex (SOI) reveals that more depressionsform during July and August of El Niñoyears. Due to this, the seasonal frequencyof monsoon depressions remains little higherduring El Niño epochs even though thecorrelations for June and September are notsignificant. The CCs for July and August aresignificant at the 99% level.The El Niño-Southern Oscillation (ENSO)is known to affect Indian MonsoonRainfall (IMR) adversely. The enhancedcyclogenesis over the Bay of Bengal duringJuly and August is an impact of ENSO whichneeds to be examined closely. Increasedcyclogenesis over the Bay of Bengal may bereducing the deficiency in IMR duringEl Niño years by producing more rainfallover the eastern parts of India duringJuly and August. Thus there is a considerablespatial variation in the impact of ENSOon the monsoon rainfall over India and El Niñoneed not necessarily imply a monsoonfailure everywhere in India.The area of formation of monsoon depressionsshifts eastward during El Niño years.Warmer sea surface temperature (SST) anomaliesprevail over northwest and adjoiningwestcentral Bay of Bengal during premonsoon andmonsoon seasons of El Niño years.May minus March SOI can provide useful predictionsof monsoon depression frequencyduring July and August.  相似文献   

Characterization of Kota Sandstone Under Different Strain Rates in Uniaxial Loading     

Md. Shams Alam  Tanusree Chakraborty  Vasant Matsagar  K. Seshagiri Rao  Prince Sharma  Manjit Singh 《Geotechnical and Geological Engineering》2015,33(1):143-152

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A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting          下载免费PDF全文

J. Uddin  J. P. Foley  R. J. Smith  N. H. Hancock 《水文研究》2016,30(11):1757-1767

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Development of Tide–Surge Interaction Model for the Coastal Region of Bangladesh     

Gour Chandra Paul  Ahmad Izani Md. Ismail  Azizur Rahman  Md. Fazlul Karim  Ashabul Hoque 《Estuaries and Coasts》2016,39(6):1582-1599

In this paper, a two-dimensional, vertically integrated hydrodynamic model is developed taking into account entrained air bubbles during storm surges as well as incorporating inverted barometer, and river and land dynamics. The model is specifically designed for the coastal region of Bangladesh. A nested scheme method with a fine mesh scheme (FMS), capable of incorporating the complex coastline and all major offshore islands accurately, nested into a coarse mesh scheme (CMS) covering up to 15° N latitude in the Bay of Bengal is used. To incorporate the small and big offshore islands in the Meghna estuarine region with its complex coastline accurately, a very fine mesh scheme (VFMS) is again nested into the FMS. Along the northeast corner of the VFMS, the Meghna river discharge is taken into account. The coastal and island boundaries are approximated through proper stair steps. The model equations are solved by a semi-implicit finite difference technique using a staggered C-grid. A stable appropriate tidal condition over the model domain is generated by applying tidal forcing with the four major tidal constituents M ₂, S ₂, K ₁, and O ₁ along the southern open boundary of the CMS. This tidal regime is introduced as the initial state of the sea for nonlinear interaction of tide and surge. The model is applied to simulate water levels due to the interaction of tide and surge associated with the cyclones April 1991 and Aila at different coastal and island locations along the coast of Bangladesh. The results are found to be quite satisfactory with root mean square error of ～0.50 m as calculated for both the storm events. Tests of sensitivities on water levels are carried out for air bubbles, offshore islands, river discharge, inverse barometer, and grid resolution. The presence of air bubbles increases simulated water levels a little bit in our model, and the contribution of air bubbles in increasing water level is found around 2 %. Further, water levels are found to be influenced by offshore islands, river discharge, inverse barometer as well as grid resolution.  相似文献   

Estimating groundwater recharge based on mass balance evaluation of unsaturated zone in a coastal catchment characterized by tropical rainforest weather conditions     

Seyed Reza Saghravani  Ismail Yusoff  Wan Zakaria Wan Md Tahir  Zainudin Othman 《Environmental Earth Sciences》2016,75(8):668

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Sources and controls for elevated arsenic concentrations in groundwater of Datong Basin,Northern China     

Chunli Su  Yapeng Zhu  Zainab Abbas  Md. Enamul Huq 《Environmental Earth Sciences》2016,75(7):570

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