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1.
The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian–Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO2 >53 wt%, Al2O3 >15 wt%, MgO >2.5 wt%, Mg# >49, Sr >650 ppm, Y <17 ppm, Yb <2 ppm, Ni >25 ppm, Cr >50 ppm and Sr/Y >42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation. 相似文献
2.
Bassam A. ABUAMARAH Mokhles K. AZER Paul D. ASIMOW Habes GHREFAT Heba S. MUBARAK 《《地质学报》英文版》2021,95(2):459-480
The Abu Dabbab albite granite(ADAG), in the central Eastern Desert of Egypt, hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield. Here, we report detailed field,petrographic, mineralogical and geochemical investigation of the ADAG, an isolated stock-like granitic body with sharp intrusive contacts against metamorphic country rocks, probably emplaced at about 600 Ma. The fine-grained porphyritic upper unit is a preserved remnant of the shallowly-emplaced apex of the magma chamber, whereas the medium-grained lower unit crystallized at deeper levels under subvolcanic conditions. The peraluminous leucocratic ADAG shares common geochemical characteristics with post-collisional intraplate A-type magmas. In addition to the conspicuous enrichment in Na2 O, the ADAG is remarkable for its anomalous concentrations of Ta, Nb, Li, Hf, Ga, Sn, Zn and heavy rare-earth elements. Nb-Ta minerals in the ADAG are mixed with Fe-Mn oxides, forming black patches that increase in abundance toward of the base of the intrusion. Columbite-tantalite, cassiterite and wolframite are the most important ore minerals.Pronounced negative Eu anomalies(Eu/Eu* = 0.10–0.24) reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interaction. The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness. Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes, late-stage metasomatism caused limited redistribution of rare metals. Fluid-driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen, amazonite, and quartz veins along fracture systems. 相似文献
3.
Mokhles Kamal Azer Robert J. Stern Jun-Ichi Kimura 《International Journal of Earth Sciences》2010,99(2):245-267
New geochemical, isotopic, and geochronological data and interpretations are presented for late Neoproterozoic intrusive carbonates
and related rocks of southern Sinai, Egypt (northernmost Arabian–Nubian Shield). The Tarr carbonates are coarsely crystalline
and related to explosive emplacement of hypabyssal and volcanic albitite at 605 ± 13 Ma. The carbonates associated with the
albitites are divisible into two types: primary dolomitite and secondary breunneritite (Fe-rich magnesite). The dolomitite
was clearly intrusive but differs from classic igneous carbonatites, containing much lower abundances of incompatible elements,
such as REE, U, Th, Rb, Nb, Y, P, Sr, Zr, Ba, and total alkalies. The breunneritite is a secondary replacement of dolomitite,
probably marking the roots of a vigorous hydrothermal system. Albitites show pristine abundances of major and trace elements
and were not subjected to a major metamorphic overprint. They are relatively more fractionated, alkaline and related to within-plate
A-type magmas, were emplaced in an extensional or non-compressive tectonic regime in the cupola of high-level A-type granite.
Tarr albitites may represent residual magma remaining after near-total crystallization of an A-type granite pluton at depth,
forcibly emplaced into the roof above the cooling pluton. The intrusive dolomitite exsolved from highly differentiated albitite
melt, in the apical regions of a still-buried alkaline “A-type” granite pluton that was rich in CO2; these volatiles migrated upwards and towards the cooler margins of the magma body. Late NNE-SSW extension allowed a shallow-level
cupola to form, into which albitite melts and carbonate fluids migrated, culminating in explosive emplacement of albitite
breccia and intrusive carbonate. Isotopic compositions of Tarr dolomitite and albitite indicate these are consanguineous and
ultimately of mantle origin. Magmatic volatiles fenitized the wall rock, while submarine hydrothermal activity transformed
some of the dolomitite into breunneritite. Recognition of Tarr-type should encourage similar hypabyssal complex intrusions
to be sought for in association with A-type granitic plutons elsewhere. 相似文献
4.
Post-collisional alkaline magmatism (∼610–580 Ma) is widely distributed in the northern part of the Neoproterozoic Arabian-Nubian Shield (ANS), i.e. the northern part of the Egyptian Eastern Desert and Sinai. Alkaline rocks of G. Tarbush constitute the western limb of the Katharina ring complex (∼593 ± 16 Ma) in southern Sinai. This suite commenced with the extrusion of peralkaline volcanics and quartz syenite subvolcanics intruded by syenogranite and alkali feldspar granite. The mineralogy and geochemistry of these rocks indicate an alkaline/peralkaline within-plate affinity. Quartz syenite is relatively enriched in TiO2, Fe2O3, MgO, CaO, Sr, Ba and depleted in SiO2, Nb, Y, and Rb. The G. Tarbush alkaline suite most likely evolved via fractionation of mainly feldspar and minor mafic phases (hornblende, aegirine) from a common quartz syenite parental magma, which formed via partial melting of middle crustal rocks of ANS juvenile crust. Mantle melts could have provided the heat required for the middle crustal melting. The upper mantle melting was likely promoted by erosional decompression subsequent to lithospheric delamination and crustal uplift during the late-collisional stage of the ANS. Such an explanation could explain the absence or scarce occurrence of mafic and intermediate lithologies in the abundant late- to post-collisional calc-alkaline and alkaline suites in the northern ANS. Moreover, erosion related to crustal uplift during the late-collision stage could account for the lack or infrequent occurrence of older lithologies, i.e. island arc metavolcanics and marginal basin ophiolites, from the northern part of the ANS. 相似文献
5.
The Neoproterozoic Allaqi-Heiani suture （800-700 Ma） in the south Eastern Desert of Egypt is the northernmost linear ophiolitic belt that defines an arc-arc suture in the Arabian- Nubian shield （ANS）. The Neoproterozoic serpentinized peridotites represent a distinct lithology of dismembered ophiolites along the Allaqi-Heiani suture zone. The alteration of peridotites varies, some contain relicts of primary minerals （Cr-spinel and olivine） and others are extremely altered, especially along thrusts and shear zones, with development of talc, talc-carbonate and quartz-carbonate. The fresh cores of the chromian spinels are rimmed by ferritchromite and Cr- magnetite. The fresh chromian spinels have high Cr# （0.62 to 0.79）, while Mg# shows wider variation （0.35-0.59）. High Cr# in the relict chromian spinels and Fo content in the primary olivines indicate that they are residual peridotites after extensive partial melting. The studied ophiolitic upper mantle peridotites are highly depleted and most probably underwent high degrees of partial melting at a supra-subduction zone setting. They can be produced by up to -20%-22% dynamic melting of a primitive mantle source. The mineralogical and geochemical features of the studied rocks reflect that the mantle peridotites of the north part of the Wadi Allaqi district are similar to the fore-arc peridotites of a supra-subduction zone. 相似文献
6.
Hisham Gahlan Mokhles Azer Paul Asimow Khaled Al-Kahtany 《Arabian Journal of Geosciences》2016,9(12):603
The Abu Rumeil syenitic rocks represent the inner ring dyke of the Katherina Ring complex, southern Sinai, Egypt. They are divided petrologically into two types, alkali feldspar syenite and quartz syenite. The mineralogy and geochemistry of the syenites indicate an alkaline nature with a shoshonitic affinity. Although rare mafic xenocrysts overgrown by primary K-feldspars and overlapping rare earth element (REE) patterns indicate some role for crustal contamination, the trace element chemistry shows a dominant mantle contribution. The geochronology and field relations imply that the Abu Rumeil syenites were emplaced in a post-collisional, within-plate tectonic setting, yet they express the enrichments in large-ion lithophile elements relative to high field strength elements generally characteristic of subduction influence. We suggest that this signature is inherited from partial melting of a lithospheric mantle source previously affected by subduction during assembly of the Arabian-Nubian Shield. Little evidence of the early evolution of the suite is preserved; there are no associated mafic rocks. We therefore restrict our attention to a petrogenetic model that can explain the relations among the observed felsic composition. The REE patterns of all samples are enriched in light REE and fractionated, but it is notable that there are small positive Eu anomalies in the alkali-feldspar syenites contrasting with small negative Eu anomalies in the quartz syenites. Positive Eu anomalies suggest a cumulate nature for the alkali-feldspar syenites; there are also breaks in the slopes of most variation trends between the alkali-feldspar syenites and the quartz syenites. The general trends in all major oxides and trace elements within the suite can be modeled by fractional crystallization of feldspars—with smaller roles for pyroxene, biotite, apatite, and Fe-Ti oxides—from an intermediate liquid to form the quartz syenites and by assimilation of the near-liquidus phases into the same starting liquid to form the alkali feldspar syenites. The geothermobarometry of pyroxenes and amphiboles suggests shallow emplacement (<10 km depth) and crystallization temperatures ranging from 1100 °C down to 800 °C. 相似文献
7.
Ophiolitic peridotites exposed in the Eastern Desert(ED) of Egypt record multiple stages of evolution, including different degrees of partial melting and melt extraction, serpentinization, carbonatization and metamorphism. The present study deals with metaperidotites at two selected localities in the central and southern ED, namely Wadi El-Nabá and Wadi Ghadir, respectively. They represent residual mantle sections of a Neoproterozoic dismembered ophiolite that tectonically emplaced over a volcano-sedimentary succession that represents island–arc assemblages. The studied metaperidotites are serpentinized, with the development of talc-carbonate and quartz-carbonate rocks, especially along shear and fault planes. Fresh relics of primary minerals(olivine, orthopyroxene and Cr-spinel) are preserved in a few samples of partiallyserpentinized peridotite. Most of the Cr-spinel crystals have fresh cores followed by outer zones of ferritchromite and Crmagnetite, which indicates that melt extraction from the mantle protolith took place under oxidizing conditions. The protoliths of the studied metaperidotites were dominated by harzburgites, which is supported by the abundance of mesh and bastite textures in addition to some evidence from mineral and whole-rock chemical compositions. The high Cr#(0.62–0.69; Av. 0.66) and low TiO2(0.3 wt%) contents of the fresh Cr-spinels, the higher Fo(89–92; Av. 91) and NiO(0.24–0.54 wt%, Av. 0.40) contents of the primary olivine relics, together with the high Mg#(0.91–0.93; Av. 91) and low CaO, Al2 O3 and TiO2 of the orthopyroxene relics, are all comparable with depleted to highly depleted forearc harzburgite from a suprasubduction zone setting. The investigated peridotites have suffered subsequent phases of metasomatism, from oceanfloor hydrothermal alteration(serpentinization) to magmatic hydrothermal alteration. The enrichment of the studied samples in light rare earth elements(LREEs) relative to the heavy ones(HREEs) is attributed to most probably be due to the contamination of their mantle source with granitic source hydrothermal fluids after the obduction of the ophiolite assemblage onto the continental crust. The examined rocks represent mantle residue that experienced different degrees of partial melting(～10% to 25% for W. El-Nabá rocks and ～5% to 23% for W. Ghadir rocks). Variable degrees of partial melting among the two investigated areas suggest mantle heterogeneity beneath the Arabian-Nubian Shield(ANS). 相似文献
8.
9.
Bassam A. Abuamarah Mokhles K. Azer Amany M.A. Seddik Paul D. Asimow Pedro Guzman Brent T. Fultz M.J. Wilner Nathan Dalleska Mahmoud H. Darwish 《Chemie der Erde / Geochemistry》2022,82(1):125840
The Homrit Akarem granitic intrusion (HAGI) outcrops near the western edge of the south Eastern Desert basement exposure in Egypt. It is a composite of two cogenetic intrusive bodies: an early albite granite phase shallowly emplaced at the apex of a magmatic cupola, and a later subjacent pink granite phase with a marginal zone of muscovite granite and better preservation of magmatic features. Mineral chemistry of primary biotite and garnet, together with whole-rock chemistry, identify the HAGI as a highly fractionated A-type peraluminous intrusion. The chemistry of F-dominant, Li-bearing, Fe3+-rich primary magmatic mica in the pink granite resembles that typically found in highly evolved Nb-Y-F pegmatites. The HAGI is the evolved product of a primary magma generated by partial melting of juvenile crust of the Arabian-Nubian Shield (ANS), emplaced along a regional strike-slip fault system that promoted its ascent. The main emplacement mechanism and evolutionary sequence of the HAGI was magmatic, although secondary minerals and textures resulting from hydrothermal fluid interactions are observed, especially at its margins. Primary columbite-(Mn) crystallized from melt and was partly replaced by secondary fluorcalciomicrolite. The high fluorine content of magmatic fluids exsolved from the intrusion is indicated by quartz-fluorite veins, greisenization, albitization, and F-bearing secondary oxide minerals. The magmatic derivation of this fluid is demonstrated by the F-dominant primary mica, a siderophyllite-polylithionite solid solution commonly known as zinnwaldite. The chemistry of zinnwaldite constrains the F/OH activity ratio and oxygen fugacity of its parental melt and thereby resolves the ambiguity between pressure and the effects of F in controlling the normative quartz content of rare-metal granites. The HAGI is less mineralized than the post-collisional rare-metal granites found further east in the south Eastern Desert, replicating a trend observed previously in the central Eastern Desert and suggesting that east-west zoning in rare metal enrichment is a persistent feature across latitudes at the western edge of the ANS. 相似文献
10.
New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO_2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization. 相似文献