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1.
The picritic (MgO >13·5%) lavas of Grenada providea unique opportunity to evaluate the platinum group elements(PGE) and Os isotope compositions of primitive subduction-generatedmelts. Compared with other arc lavas they have undergone verylimited crustal contamination ( 相似文献
2.
The results of a laser ablation microprobe–inductivelycoupled plasma mass spectrometry Lu–Hf isotope study ofzircons in 0·93–1·67 Ga rocks from southNorway indicate that early Proterozoic protoliths of the BalticShield have present-day 176Hf/177Hf 相似文献
3.
A suite of pyroxenites from the Beni Bousera peridotite massif,northern Morocco, have been analysed for Re–Os and Lu–Hfisotopic compositions. Measured sections of the massif indicatethat pyroxenite layers make up between 1 and 9% by volume ofthe total outcrop. Clinopyroxenes from two Cr-diopside pyroxeniteshave unradiogenic Hf isotope compositions ( 相似文献
4.
Aaron GRONSTAL Victoria PEARSON Andreas KAPPLER Craig DOORIS Mahesh ANAND Franck POITRASSON Terence P. KEE Charles S. COCKELL 《Meteoritics & planetary science》2009,44(2):233-247
Abstract— Batch culture experiments were performed to investigate the weathering of meteoritic material by iron‐oxidizing bacteria. The aerobic, acidophilic iron oxidizer (A. ferrooxidans) was capable of oxidizing iron from both carbonaceous chondrites (Murchison and Cold Bokkeveld) and iron meteorites (York and Casas Grandes). Preliminary iron isotope results clearly show contrasted iron pathways during oxidation with and without bacteria suggesting that a biological role in meteorite weathering could be distinguished isotopically. Anaerobic iron‐oxidizers growing under pH‐neutral conditions oxidized iron from iron meteorites. These results show that rapid biologically‐mediated alteration of extraterrestrial materials can occur in both aerobic and anaerobic environments. These results also demonstrate that iron can act as a source of energy for microorganisms from both iron and carbonaceous chondrites in aerobic and anaerobic conditions with implications for life on the early Earth and the possible use of microorganisms to extract minerals from asteroidal material. 相似文献
5.
NEUMANN ELSE-RAGNHILD; GRIFFIN WILLIAM LINDSEY; PEARSON NORMAN J.; O'REILLY SUZANNE YVONNE 《Journal of Petrology》2004,45(12):2573-2612
Laser ablation microprobe data are presented for olivine, orthopyroxeneand clinopyroxene in spinel harzburgite and lherzolite xenolithsfrom La Palma, Hierro, and Lanzarote, and new whole-rock trace-elementdata for xenoliths from Hierro and Lanzarote. The xenolithsshow evidence of strong major, trace element and Sr isotopedepletion (87Sr/86Sr 0·7027 in clinopyroxene in themost refractory harzburgites) overprinted by metasomatism. Thelow Sr isotope ratios are not compatible with the former suggestionof a mantle plume in the area during opening of the AtlanticOcean. Estimates suggest that the composition of the originaloceanic lithospheric mantle beneath the Canary Islands correspondsto the residues after 25–30% fractional melting of primordialmantle material; it is thus significantly more refractory than‘normal’ mid-ocean ridge basalt (MORB) mantle. Thetrace element compositions and Sr isotopic ratios of the mineralsleast affected by metasomatization indicate that the upper mantlebeneath the Canary Islands originally formed as highly refractoryoceanic lithosphere during the opening of the Atlantic Oceanin the area. During the Canarian intraplate event the uppermantle was metasomatized; the metasomatic processes includecryptic metasomatism, resetting of the Sr–Nd isotopicratios to values within the range of Canary Islands basalts,formation of minor amounts of phlogopite, and melt–wall-rockreactions. The upper mantle beneath Tenerife and La Palma isstrongly metasomatized by carbonatitic or carbonaceous meltshighly enriched in light rare earth elements (REE) relativeto heavy REE, and depleted in Zr–Hf and Ti relative toREE. In the lithospheric mantle beneath Hierro and Lanzarote,metasomatism has been relatively weak, and appears to be causedby high-Si melts producing concave-upwards trace element patternsin clinopyroxene with weak negative Zr and Ti anomalies. Ti–Al–Fe-richharzburgites/lherzolites, dunites, wehrlites and clinopyroxenitesformed from mildly alkaline basaltic melts (similar to thosethat dominate the exposed parts of the islands), and appearto be mainly restricted to magma conduits; the alkali basaltmelts have caused only local metasomatism in the mantle wall-rocksof such conduits. The various metasomatic fluids formed as theresults of immiscible separations, melt–wall-rock reactionsand chromatographic fractionation either from a CO2-rich basalticprimary melt, or, alternatively, from a basaltic and a siliceouscarbonatite or carbonaceous silicate melt. KEY WORDS: mantle xenoliths; mantle minerals; trace elements; depletion; carbonatite metasomatism 相似文献
6.
High-Temperature Fluid-Rock Interaction and Scapolitization in an Extension-Related Hydrothermal System, Mary Kathleen, Australia 总被引：1，自引：0，他引：1
OLIVER NICHOLAS H. S.; RAWLING TIMOTHY J.; CARTWRIGHT IAN; PEARSON PAUL J. 《Journal of Petrology》1994,35(6):1455-1491
In the polymetamorphic Mary Kathleen Fold Belt, at the centreof the Proterozoic Mount Isa Inlier, Queensland, an early phaseof extension (1760–1730 Ma) resulted in intrusion of voluminousgranitic and doleritic magmas into the carbonate-evaporite-dominatedCorella Formation at 5–10 km depths. Widespread high-temperaturemetasomatism ensued, involving scapolitization in dolerite,formation of albite-scapolite shear zones in granite, exo- andendoskarn formation, and a zone of K–Na–Ca alterationin the lowermost Corella Formation. Granites and dolerites werealtered to an unusual Na–Ca-rich bulk composition, reflectinghigh-temperature infiltration of highly saline, chemically reactiveexternally derived fluid. The alteration products and theirdistribution suggest not only reaction of magmatic/aqueous fluidswith the country rocks but also extensive halite dissolutionand recirculation of saline fluids back into the intrusive bodies.The bulk of fluid flow occurred at high temperatures (500–700C), and major element and isotopic fronts were generally notsmoothed out by the effects of temperature gradients, with theexception of one part of the system which shows evidence forup-temperature fluid flow. Analysis of oxygen isotopic dataand the position of isotopic and geochemical fronts revealstime-integrated fluid fluxes of up to 2 104 m3/m2 for themetasomatism. Although very high salinities (up to 50 mol% NaCl)were attained by evaporite dissolution, 18O values of most alterationproducts are in the range 7–12%, reflecting a predominanceof oxygen derived from an igneous fluid. The position and interrelationshipsof metasomatic and isotopic fronts indicate an earlier stageof infiltration dominated by fluid released from crystallizinggranite (with 18O 10–12%), and a later stage (18O 7–9%)in which fluid had already interacted with halite and a mixedmafic-felsic igneous source or was repeatedly circulated betweenthese rock types during alteration. The data reflect only aminimal contribution from fluids produced by devolatilizationof the abundant carbonate-bearing rocks in the Corella Formation,and there are substantial areas of Corella Formation rocks thathave escaped metasomatism during this phase of intrusion-relatedhydrothermal activity and during the subsequent regional metamorphicoverprint. Along with the requirement that the fluids dissolvedlarge amounts of halite from the same sequence, and the structuralobservations, we favour a model where fluid was preferentiallychannelled along specific permeable conduits, including formerevaporite layers, before interaction with the now exposed alteredrocks. Fluid was probably driven by both convective circulationand dilatancy-related deformation accompanying emplacement ofmagmas into a major crustal extensional dcollement. 相似文献
7.
BRUECKNER HANNES K.; VAN ROERMUND HERMAN L. M.; PEARSON NORMAN J. 《Journal of Petrology》2004,45(2):415-437
Mineralogical, isotopic, geochemical and geochronological evidencedemonstrates that the Friningen body, a garnet peridotite bodycontaining garnet pyroxenite layers in the Seve Nappe Complex(SNC) of Northern Jämtland, Sweden, represents old, certainlyProterozoic and possibly Archean, lithosphere that became incorporatedinto the Caledonian tectonic edifice during crustal subductioninto the mantle at c. 450 Ma. Both garnet peridotite and pyroxenitecontain two (M1 and M2) generations of garnet-bearing assemblagesseparated by the formation of two-pyroxene, spinel symplectitearound the M1 garnet and the crystallization of low-Cr spinel1Cin the matrix. These textures suggest initial high-pressure(HP) crystallization of garnet peridotite and pyroxenite succeededby decompression into the spinel stability field, followed byrecompression into the garnet peridotite facies. Some pyroxenitelayers appear to be characterized solely by M2 assemblages withstretched garnet as large as several centimeters. Laser ablationmicroprobe–inductively coupled plasma mass spectrometryRe–Os analyses of single sulfide grains generally definemeaningless model ages suggesting more than one episode of Reand/or Os addition and/or loss to the body. Pentlandite grainsfrom a single polished slab of one garnet peridotite, however,define a linear array on an Re–Os isochron diagram that,if interpreted as an errorchron, suggests an Archean melt extractionevent that left behind the depleted dunite and harzburgite bodiesthat characterize the SNC. Refertilization of this mantle bymelts associated with the development of the pyroxenite layersis indicated by enriched clinopyroxene Sr–Nd isotope ratios,and by parallel large ion lithophile-enriched trace elementpatterns in clinopyroxene from pyroxenite and the immediatelyadjacent peridotite. Clinopyroxene and whole-rock model Sm–Ndages (TDM = 1·1–2·2 Ga) indicate that fertilizationtook place in Proterozoic times. Sm–Nd garnet2–clinopyroxene2–wholerock ± orthopyroxene2 mineral isochrons from three pyroxenitelayers define overlapping ages of 452·1 ± 7·5and 448 ± 13 Ma and 451 ± 43 Ma (2 相似文献
8.
NEUMANN E.-R.; WULFF-PEDERSEN E.; PEARSON N. J.; SPENCER E. A. 《Journal of Petrology》2002,43(5):825-857
Mantle xenoliths from Tenerife show evidence of metasomatismand recrystallization overprinting the effects of extensivepartial melting. The evidence includes: recrystallization ofexsolved orthopyroxene porphyroclasts highly depleted in incompatibletrace elements into incompatible-trace-element-enriched, poikiliticorthopyroxene with no visible exsolution lamellae; formationof olivine and REE–Cr-rich, strongly Zr–Hf–Ti-depletedclinopyroxene at the expense of orthopyroxene; the presenceof phlogopite; whole-rock CaO/Al2O3 >> 1 (Ca metasomatism) inrecrystallized rocks; and enrichment in incompatible elementsin recrystallized rocks, relative to rocks showing little evidenceof recrystallization. The ‘higher-than-normal’ degreeof partial melting that preceded the metasomatism probably resultsfrom plume activity during the opening of the Central AtlanticOcean. Sr–Nd isotopic compositions are closely similarto those of Tenerife basalts, indicating resetting from theexpected original mid-ocean ridge basalt composition by themetasomatizing fluids. Metasomatism was caused by silicic carbonatitemelts, and involved open-system processes, such as trappingof elements compatible with newly formed acceptor minerals,leaving residual fluids moving to shallower levels. The compositionsof the metasomatizing fluids changed with time, probably asa result of changing compositions of the melts produced in theCanary Islands plume. Spinel dunites and wehrlites representrocks where all, or most, orthopyroxene has been consumed throughthe metasomatic reactions. KEY WORDS: Canary Islands; Tenerife; mantle xenoliths; geochemistry; Ca metasomatism; open-system processes; lithosphere; ocean islands 相似文献
9.
‘Lower crustal’ suite xenoliths in basaltic and kimberlitic magmas are dominated by mafic granulites and may also include eclogites and garnet pyroxenites. Pressures of up to 25 kbar obtained from such xenoliths are well in excess of an upper value of c. 12 kbar for exposed granulite terranes. Palaeogeotherms constructed from xenoliths for the lower crust beneath the Phanerozoic fold belts of eastern Australia (SEA) and beneath the eastern margin of the Australian craton (EMAC) indicate two distinct thermal regimes. The two geotherms have similar form, with the EMAC curve displaced c. 150°C to lower temperatures. Reaction microstructures show the partial re-equilibration of primary igneous assemblages to granulite and eclogite assemblages and are interpreted to reflect the cooling from magmatic temperatures. Variations in mineral compositions and zoning are used to constrain further the history of several EMAC xenoliths to near-isobaric trajectories. Detailed graphical models are constructed to predict compositional changes for isobaric P–T paths (at 7, 14 & 21 kbar) to transform an SEA-type geotherm to a cratonic geotherm. The models show that for the assemblage grt + cpx ± ky + plag + qtz, the changes associated with falling temperature in Xgr, Xjd (increase) and Xan (decrease) will be greater at higher pressures. These results indicate that discernible zoning is more likely to be preserved in the higher pressure xenoliths. The zoning recorded in clinopyroxene from mafic granulite xenoliths over the pressure range c. 12–22 kbar suggests isobaric cooling of a large crustal thickness (30–35 km). An isobaric cooling path is consistent with magma accretion models for the transition of a crust–mantle boundary from an SEA-type geotherm to a cratonic geotherm. The coexistence of granulite and eclogite over the depth range 35–75 km beneath the EMAC indicates that the granulite to eclogite transition in the lower crust is controlled by P–T conditions, bulk chemistry and kinetic factors. At shallower crustal levels, typified by exposed granulite terranes, isobaric cooling may not result in the transition to eclogite. 相似文献
10.
Abstract This is an updated and extended presentation of the results of the IAHS Workshop on Quality Assurance in Hydrologic Measurement, held during the XXI General Assembly of the International Union of Geodesy and Geophysics (IUGG), Boulder, Colorado, USA, in July 1995. The main focus at Boulder was on experience with hydrological applications of the international standard ISO 9002 and developments in rating curve theory. A case study of a quality assurance system is presented. Progress in hydrometric quality assurance since the workshop and areas for future development are discussed. 相似文献