Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Bacterial productivity in the Prydz Bay and its adjacent waters,Antarctic     

邱雨生  黄奕普  陈敏  刘广山 《极地研究(英文版)》2004,15(1):14-27

1　IntroductionBacteriaandtheiractivitiesplayanimportantroleintheelementalbiogeochemicalcyclesandenergytransformingintheocean (Zhenetal.1 997) .DortchandPackard(1 989) proposedthatfoodwebsintheeutrophicwatersaredominatedbythebiomassofprimaryproducerswhilefoodwebsintheoligotrophicwatersaredominatedbythebiomassofmicrobes.Heterotrophicbacteriahadbeenshowntoplayanimportantroleinthedecompositionoflarge ,rapidlysinkingorganicparticleswithinandbelowtheeuphot iczone ,andfurthertoaffecttheelementaldyn…  相似文献   

A Time Evolution Study of the Superhumps of the Dwarf Nova 1RXS J232953.9+062814 by Wavelet Transform     

Ai-Ying Zhou  Yu-Lei Qiu 《Astrophysics and Space Science》2003,288(3):327-339

The time evolution behaviour of the superhumps of the dwarf nova1RXS J232953.9+ 062814 is investigated with the wavelet analysis method. On the basis of two nights CCD photometry performed during its first superoutburst as well as other published brightness data, we reveal the superhump's time-dependence as a function of periods and time. Our light curves, which phased in the rapid decay ending portion of the superoutburst and in the dawn of a following normal outburst, are important to help trace the superhump evolution for the star. Both the superhump period and the orbital period of the binary system are detected in the present data. We obtain P _sh=0.0458±0.0002d and P _orb=0.0450±0.0002d. They agree with those existing values. The two periods exchanged their roles during the superhump evolution. The general profile of brightness fading over the outbursts roughly followed an exponential decay law or a form of a five-order polynomial. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

斑节对虾白斑综合症杆状病毒感染的实验模式     

邱德全  林继辉  刘丽  张凌飞 《广东海洋大学学报》2001,21(1):10-13

在建立斑节对虾实验室养殖模式的基础上，对野外采集的有白斑综合症病毒（WSSV）病典型症状的斑节对虾初步纯化其病毒，并进行WSSV的PCR检测，得到WSSV的感染用样品。对健康斑节对虾分别进行浸浴感染，投喂感染和注射感染。对感染死亡个体进行WSSA的PCR检测和细菌检测，证实WSSV感染性和致死性。浸浴感染、投喂感染和注射感染的感染量分别为4mL/L、0.2g/10g虾体、1/2稀释液0.05mL/10g虾体，死亡开始时间分别为16d、42h、28h，三种感染模式最终死亡率100%，从开始死亡到全部死亡延续时间分别为15d、82h、44h。  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献   

现代天文选址中的视宁度（Ⅱ）     

仇朴章  刘忠 《天文学进展》1996,14(3):175-180

在文献」１「４ 基础上，根据近年文选址实践中提出的问题，先进一步讨论了大气相干直径和时间的的物理和意义，然后强调了自由大气湍流的天文成像效应及选址中进行研究和测量的重要性。最后对差分像运动方法测量视宁度的定标和系统误差等问题作了分析。  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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伪随机码调制的CW半导体激光雷达试制报告     

肖弟权  何建新  邱万智 《成都信息工程学院学报》1993,(4)

本文报告一种用半导体激光器作光源,用子脉冲宽度100ns,长度为511的周期伪随机码对半导体激光器的输出作幅度调制;APD作光电检测器,高速数字信号处理器TMS320C25作信号处理的激光雷达组成方案和试作样机的实验结果。  相似文献   

西部大开发中的科技伦理调控     

吴秋凤 《广东海洋大学学报》2003,23(5):94-98

在阐述西部大开发中科技主导地位的基础上 ,从科技应用成效二重性的视角 ,探讨了关注西部科技伦理的必要性 ,并初步提出了西部大开发战略的科技伦理调控机制  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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