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Zusammenfassung Die Neubearbeitung derstratiformen Sulfidlagerstätte Walchen bei Öblarn, Steiermark, offen-bart eine eisenbetonte submarin-exhalative Metallkonzentration in einem vulkano-sedimentären Rahmen. Dieser liegt heute in Form metamorpher Gesteine der untersten Grünschieferfazies vor. Mineralchemische Untersuchungen zeigen, daß die ehemalige intensivste metamorphe Überprägung der Lagerstätte im Bereich von 450°–500°C oberhalb 4 kb stattgefunden hat. Metavulkanite, vertreten durch Grünschiefer, lassen alkalibasaltische Affinität erkennen. Die vulkano-tektonische Position der Lagerstätte ist in einem intrakontinentalen Riftsystem zu sehen.
Mit 6 Abbildungen 相似文献
The stratiform sulphide deposit at walchen, styria, austria: Geochemistry and genesis
Summary The Walchen deposit consists of a 1–2 m thick layer of massive to disseminated pyrite-pyrrhotite-chalcopyrite ore with an average grade of 1% Cu. It has been mined intermittently in the past. The ore horizon occurs within sericitic and quartzitic phyllites which carry intercalations with significant carbonate, garnet and graphite contents. The succession is of lower Paleozoic age and forms part of the Grauwackenzone, a volcano-sedimentary unit which separates the Central Alps from the Northern Calcareous Alps.The precursor rocks of the ore environment have been pelites and sandstones; greenschists occur in the hanging wall of the mineralization. Major and trace element analyses of greenschists reveal them as low-grade metamorphic equivalents of continental alkali basalts. Hydrothermal systems generated by volcanic activity were responsible for deposition of stratiform sulphides. The predominance of clastic sediments and the absence of stringer zones point towards a shallow depositional basin.Microprobe analyses of garnets from the ore environment reveal an increase in spessartine contents from 7 mol% in phyllites to 20 mol% in the vicinity of the ore horizon. Similar data have been reported from other stratabound base metal deposits (Broken Hill, N.S.W.; Kreuzeck Mountains, Austria; Gamsberg, South Africa); the manganese concentrations represent fossil manganese haloes.Pyrite carries minor Ni and Co (up to 0.03, respectively 0.3%), pyrrhotite averages 0.8% Ni and 0.1% Co, Fe-contents of sphalerite vary from 6.41–9.33%; Cd, In and Mn have not been recorded.Garnet-biotite pairs suggest maximum metamorphic temperatures of 450°–500°C: pressures of 4 to 5 kb have been estimated. The Walchen deposit is interpreted as the product of submarine exhalative processes in an incipient rift. It was affected by prograde metamorphism during the Variscan orogeny, and by retrograde affects during a later event. Isochemical metamorphism resulted in the preservation of a primary manganese halo.
Mit 6 Abbildungen 相似文献
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Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluid inclusions 总被引：5，自引：1，他引：5
Christian G. Ballhaus Eugen F. Stumpfl 《Contributions to Mineralogy and Petrology》1986,94(2):193-204
The base metal sulfides of the Merensky Reef are associated with hydrous silicates and intense deuteric hydrous alteration of cumulus and postcumulus silicates. Biotite and phlogopite crystallized in the vicinity of sulfides from a volatile-enriched highly fractionated intercumulus melt. Amphibole, chlorite, and talc are later alteration phases of cumulus pyroxene and intercumulus plagioclase. Biotite is often accompanied by zircon, rutile, and quartz. Accessory quartz hosts a complex suite of H2O-NaCl-(CaCl2)-CO2-CH4 fluid inclusions which have thus far not been described from the Merensky Reef. The earliest fluid inclusion compositions are NaCl-(H2O) with less than 10 vol.% water; CO2 coexisting with a halite daughter crystal and brine; and polyphase inclusions with up to six daughter and accidental phases and high contents of divalent cations. The maximum trapping temperature is around 730° C at 4 to 5 kb pressure. Later inclusion generations are H2O-NaCl, CO2-H2O, and pure CO2 and CH4. The presence of Cl-rich fluids during the intercumulus stage of the crystallizing Merensky Reef is directly related to the mode of sulfide precipitation. Prior to sulfide unmixing in a hydrous magma sulfur is likely to be present as H2S. Sulfur saturation causes reaction of H2S with oxides of the silicate melt to form a sulfide melt plus water. During reaction the magma is enriched in water until a separate fluid unmixes. It carries all compounds with high fluid/melt partition coefficients, as well as metals capable of forming OH- and Cl-complexes. Precious metals are assumed to have fractionated into the Cl-rich fluid as Cl-complexes rather than being dissolved in the sulfide melt. During the cooling evolution of the fluid the precious elements precipitate around the periphery of sulfide melt droplets. The model proposed explains the distribution pattern of platinum-group minerals in the Merensky Reef better than any orthomagmatic mineralization concept offered so far. 相似文献
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Mineralium Deposita - 相似文献
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G. Simon Dr. D. H. M. Alderton Prof. E. F. Stumpfl Dr. T. Bleser 《Mineralogy and Petrology》1995,53(1-3):115-124
Summary Tellurantimony, Sb2Te3 has been recorded for the first Lime in Europe. It occurs in the epithermal precious metal deposits of western Romania: Nagyag (now Sacaramb), Stanija, and Magura-Hondal. The optical properties, chemical composition, and mineral associations of the tellurantimony are described. Significant contents of Pb, Au, Ag, and As have been noted, and these seem to be related to the specific occurrence and association. The tellurantimony-bearing assemblages probably formed under conditions of highf
Te2 and mean to lowf
S2.
Tellurantimon in Rumänien: Das erste Vorkommen in Europa
Zusammenfassung Zum ersten Mal wurde in Europa Tellurantimon (Sb2Te3) gefunden. Es tritt in epithermalen Lagerstätten von Edelmetallen in W-Rumänien auf. Nagyag (jetzt Sacaramb), Stanija und Magura-Hondol. Hier werden die optischen Eigenschaften, die chemische Zusammensetzung und die Mineralvergesellschaftungen von Tellurantimon beschrieben. Deutliche Gehalte an Pb, Au, Ag und As scheinen in Zusammenhang mit der Besonderheit dieser Vorkommen und dieser Vergesellschaftung zu stehen. Die Tellurantimonführenden Zusammensetzungen wurden wahrscheinlich unter hoherf Te2 und niedriger is mittlererf s2 gebildet.相似文献
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G. C. Amstutz E. F. Stumpfl W. -D. Grimm K. Weber-Diefenbach 《Mineralium Deposita》1981,16(3):459-465
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Dr. M. Cornelius Prof. E. F. Stumpfl Dr. D. Gee Dr. W. Prochaska 《Mineralogy and Petrology》1987,36(3-4):247-265
Summary The New Norcia and the Yornup bodies are situated within the high-grade Western Gneiss Terrain of the Yilgarn Block. The New Norcia body consists of mafic and ultramafic rocks of gabbronoritic, olivine-gabbronoritic and harzburgitic composition respectively, metamorphosed to amphibolite, amphibolitic serpentinite and serpentinite.The upper part of the body is conformably intercalated with quartzites and minor psammites.The Yornup body consists of an ultramafic zone, mainly of lherzolitec and harzburgitic and minor dunitic composition and a mafic zone of olivine-gabbronorite, which has partly been differentiated.Chondrite-normalized PGE patterns of lherzolites and harzburgites from both localities show gentle, positive trends and abundances of approximately 0.01 times C 1. Patterns of sulphide-bearing rocks are about 0.1 times C 1, with Pd strongly enriched.The flat patterns suggest that the magma was derived from high degrees of partial melting and underwent only minor differentiation.Mobilization of sulphides fractionated the PGE and particularly enriched palladium.The patterns resemble those of komatiites and komatiite-related nickel sulphides. They are distinct from steep positively trending patterns characteristic of Archean tholeiites.It is assumed that prior to the main metamorphic event, magma compositionally similar to that of komatiites intruded at the contact of a protocontinental basement and overlying sediments forming sill-shaped bodies.
With 8 Figures
Contribution to the Ore Mineralogy Symposium (IMA/COM) at the 14th General Meeting of the International Mineralogical Association, at Stanford, California, in July, 1986. 相似文献
Platingruppen-Elemente in mafisch-ultramafischen Gesteinen des Western Gneiss Terrain, West-Australien
Zusammenfassung Die Lokalitäten New Norcia and Yornup befinden sich im hochmetamorphen Teil des Yilgarn-Blockes, dem Western Gneiss Terrain.Die New Norcia Abfolge besteht aus Amphiboliten und amphibolitischen Sepentiniten mit gabbronoritischer und olivin-gabbronoritischer sowie aus Serpentiniten mit harzburgitischer Zusammensetzung. Im Hangenden sind die Amphibolite mit Quarziten und Psammiten verzahnt.Lherzolite, Harzburgite und untergeordnet auch Dunite bilden den ultramafischen Teil der Yornup-Abfolge, deren mafische Einheit aus Amphiboliten gabbronoritischer bis olivin-gabbronoritischer Zusammensetzung besteht und in einem Teil Differentiation zeigt.Chondrit-normalisierte PGE Verteilungsmuster von Lherzoliten und Harzburgiten beider Lokalitäten zeigen einen schwach positiven Trend von Iridium zu Gold; die PGE-Gehalte sind ca. 0.01 fach chondritisch. Die PGE-Gehalte sulfidhaltiger Gesteine sind ca. 0.1 fach chondritisch und zeigen starke Palladium-Anreicherungen.Aus dem flachen Verlauf der PGE-Kurven wird auf einen hohen Aufschmelzungsgrad und nur unbedeutende Differentiation geschlossen. In den mobilisierten Sulfiden fand eine Fraktionierung der PGE statt und führte insbesondere zu einer starken Anreicherung des Palladiums.Die PGE-Kurven sind denen von Komatiiten und den mit diesen assoziierten Nickelsulfiden ähnlich und unterscheiden sich deutlich von steilen Kurven archaischer Tholeiite.Es wird angenommen, daß vor der metamorphen Überprägung des WGT ein in der Zusammensetzung Komatiiten ähnelndes Magma zwischen einem protokontinentalen Basement und daraufliegenden Sedimenten intrudierte und sillförmige Körper bildete.
With 8 Figures
Contribution to the Ore Mineralogy Symposium (IMA/COM) at the 14th General Meeting of the International Mineralogical Association, at Stanford, California, in July, 1986. 相似文献