A simple model for the evolution of disc galaxies: the Milky Way     

Thorsten Naab  Jeremiah P. Ostriker 《Monthly notices of the Royal Astronomical Society》2006,366(3):899-917

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Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates     

Philippe E. Raison  Regis Jardin  Daniel Bouëxière  Rudy J. M. Konings  Thorsten Geisler  Claudiu C. Pavel  Jean Rebizant  Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.  相似文献   

On the effect of temperature and strain-rate dependent viscosity on global mantle flow, net rotation, and plate-driving forces     

Thorsten W. Becker 《Geophysical Journal International》2006,167(2):943-957

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GGM02 – An improved Earth gravity field model from GRACE     

B. Tapley  J. Ries  S. Bettadpur  D. Chambers  M. Cheng  F. Condi  B. Gunter  Z. Kang  P. Nagel  R. Pastor  T. Pekker  S. Poole  F. Wang 《Journal of Geodesy》2005,79(8):467-478

A new generation of Earth gravity field models called GGM02 are derived using approximately 14 months of data spanning from April 2002 to December 2003 from the Gravity Recovery And Climate Experiment (GRACE). Relative to the preceding generation, GGM01, there have been improvements to the data products, the gravity estimation methods and the background models. Based on the calibrated covariances, GGM02 (both the GRACE-only model GGM02S and the combination model GGM02C) represents an improvement greater than a factor of two over the previous GGM01 models. Error estimates indicate a cumulative error less than 1 cm geoid height to spherical harmonic degree 70, which can be said to have met the GRACE minimum mission goals. Electronic Supplementary Material Supplementary material is available in the online version of this article at  相似文献   

Model identification for hydrological forecasting under uncertainty   总被引：2，自引：2，他引：2  

Thorsten Wagener  Hoshin V. Gupta 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(6):378-387

Methods for the identification of models for hydrological forecasting have to consider the specific nature of these models and the uncertainties present in the modeling process. Current approaches fail to fully incorporate these two aspects. In this paper we review the nature of hydrological models and the consequences of this nature for the task of model identification. We then continue to discuss the history (“The need for more POWER‘’), the current state (“Learning from other fields”) and the future (“Towards a general framework”) of model identification. The discussion closes with a list of desirable features for an identification framework under uncertainty and open research questions in need of answers before such a framework can be implemented.  相似文献   

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry     

Boris P. Koch  Matthias Witt  Thorsten Dittmar 《Geochimica et cosmochimica acta》2005,69(13):3299-3308

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.  相似文献   

Late Miocene to Early Pliocene blueschist from Taiwan and its exhumation via forearc extraction          下载免费PDF全文

Sascha Sandmann  Thorsten J. Nagel  Nikolaus Froitzheim  Kamil Ustaszewski  Carsten Münker 《地学学报》2015,27(4):285-291

Blueschist facies rocks in the Yuli Belt of Taiwan's Central Range record ongoing subduction of the Eurasian plate. We present a prograde Lu–Hf garnet–whole‐rock age of 5.1 ± 1.7 Ma from a retrogressed blueschist in the Yuli Belt. This age is considerably younger than the previously assumed age of 14–8 Ma for high‐pressure metamorphism in the Yuli Belt and represents the youngest Lu–Hf garnet age ever recorded for blueschist facies metamorphism. The age sheds new light on the palaeogeographic origin and exhumation scenario of the Yuli Belt. We propose that the Yuli Belt originated from the ocean–continent boundary of the Chinese passive margin. It was subducted eastward during collision with the Luzon island arc and rapidly exhumed when the forearc lithosphere was removed from above the continental slab by discrete subduction (extraction). This process reduces the pressure above the continental slab and may prompt the ascent of subducted crust into the opening gap. Thus, it can control the exhumation of high‐pressure rocks.  相似文献   

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity          下载免费PDF全文

Enrique Muñoz  José Luis Arumí  Thorsten Wagener  Ricardo Oyarzún  Victor Parra 《水文研究》2016,30(26):4934-4943

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.  相似文献   

Glacier outburst floods reconstructed from lake sediments and their implications for Holocene variations of the plateau glacier Folgefonna in western Norway     

Torgeir O. Rthe  Jostein Bakke  Eivind Wilhelm Nagel Stren 《Boreas: An International Journal of Quaternary Research》2019,48(3):616-634

A sudden release of large volumes of water during a glacier outburst flood (GLOF) is a major hazard worldwide. Here, we identify the sedimentary signature of glacial and non‐glacial processes, including GLOFs, based on lacustrine sediments from the distal glacier‐fed Lake Buarvatnet in western Norway. Historically documented GLOFs in 2002 CE and during the 1980s CE are identified in the ²¹⁰Pb‐ and ¹⁴C‐dated sediments. These events have the same sedimentary signature as 12 earlier events throughout the Holocene interpreted to represent previous GLOFs in the catchment. The GLOFs are interpreted to have occurred during periods when the glacier extent was similar to the modern positions, and the events are thus used to pinpoint past positions of the glacier terminus and, hence, the equilibrium line altitudes (ELAs). The results indicate that the glacier Svartenutbreen, located at the eastern part of Folgefonna, had a similar size in 2002 CE as c. 8200–8300 cal. a BP, corresponding to the 8.2 ka event in the North Atlantic region. The regrowth of Sørfonna after the Holocene Thermal Optimum occurred at c. 6900 cal. a BP and Svartenutbreen was at modern size and extent in the periods c. 6400, c. 5450, c. 4850, c. 3850, c. 3550 and c. 1650 cal. a BP. Since 1650 cal. a BP, we infer that the glacier was larger than the 2002 CE glacier extent until 1910 CE when a GLOF occurred. Svartenutbreen has been retreating since 1910 CE, which led to the ice damming of the two historical GLOFs in the 1980s and 2002 CE separated by a glacier advance in the 1990s CE. The findings are discussed and compared to other regional glacier reconstructions in Norway, and emphasize the value of identifying and utilizing GLOFs as an indicator of past ELA variability.  相似文献   

Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand     

Michael Gonsior  Barrie M. Peake  William T. Cooper  David C. Podgorski  Juliana D'Andrilli  Thorsten Dittmar  William J. Cooper 《Marine Chemistry》2011,123(1-4):99-110

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.  相似文献