Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

青藏高原隆升的非线性动态有限元仿真研究   总被引：7，自引：4，他引：3  

杨红心  王乘  张秋文  郑文衡 《大地测量与地球动力学》2002,22(2):75-81

根据青藏高原的地质特征建立分析模型，采用3维动态有限元方法，在计算仿真板块速度场的基础上，计算在青藏高原的隆升过程中该地区地壳岩石的等效应力和位移随时间的变化，计算仿真得到的速度场与1998年GPS观测的速度场吻合良好；与过去一贯的假设相反，计算结果反映出地壳应力场不是静态的，而是此起彼伏，不断变化的，应力值最大且变化最剧烈的地区在克什米尔地区、鄂尔多斯地区和鲜水河－小江断裂带，与地震多发区域吻合。  相似文献   

“BASS 300 PARACOM”: a “model” underwaterparametric communication system     

Coates  R.F.W. Ming Zheng Liansheng Wang 《Oceanic Engineering, IEEE Journal of》1996,21(2):225-232

Parametric transduction offers valuable advantages for underwater acoustic communications. Perhaps the most significant benefit is the fact that high directivity is achieved by means of a physically small transmit transducer. This feature may, ultimately, be employed to permit long-range, low-frequency communication using a compact source. The high directivity is desirable to combat multipath propagation and to achieve data communications in water which is shallow by comparison with range. A real-time, high data-rate “model” differential phase shift keying (DPSK) communication system has been constructed and demonstrated. This system uses parametric transduction, with a 300-kHz primary frequency and a 50-kHz secondary frequency. Experimental results show that the system can be employed to combat multipath propagation in shallow water and can achieve high data-rate text and color image transmission at 10 and 20 kb s^-1 for 2-DPSK and 4-DPSK, respectively, through a transmission bandwidth of 10 kHz. The “model” system was developed to confirm performance predictions for a future, operational long-range link employing a 50-kHz primary frequency and a 5-kHz secondary frequency  相似文献   

Dust supply from river floodplains: the case of the lower Huang He (Yellow River) recorded in a loess–palaeosol sequence from the Mangshan Plateau     

Maarten A. Prins  Hongbo Zheng  Kay Beets  Simon Troelstra  Patrick Bacon  Ilse Kamerling  Wouter Wester  Martin Konert  Xiangtong Huang  Wang Ke  Jef Vandenberghe 《第四纪科学杂志》2009,24(1):75-84

The Mangshan Plateau is located on the south bank of the Huang He (Yellow River) just west of the city of Zhengzhou, well outside the Loess Plateau in central China. Mixing models of the grain‐size data indicate that the loess deposits are mixtures of three loess components. Comparison of the mixing model with existing models established for a series of loess–palaeosol sequences from the Loess Plateau indicates that the Mangshan loess has been supplied from a proximal dust source, the Huang He floodplain, during major dust outbreaks. The high accumulation rates, the composition of the loess components, and especially the high proportions of a sandy loess component support this. Owing to the exceptionally high accumulation rates, the Mangshan grain size, magnetic susceptibility and carbonate records provide a high‐resolution archive of environmental and climate change. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

地壳对海洋潮汐的响应   总被引：2，自引：2，他引：0  

郑文衡  王乘  何振  牛安福 《大地测量与地球动力学》2002,22(2):41-46

应用三维动态有限元方法研究了中国北部地区的地壳对邻近的渤海与黄海海平面变化的响应。虽然此应力场过于微弱不足以引发地震，但发现应力集中的位置及应力场变化较大的位置恰好与某些现代地震的震中一致。这一结果表明研究地壳对广泛分布的载荷的响应对研究区域地震构造是有帮助的。  相似文献   

人造导引星自适应光学的倾斜决定问题     

范承玉  宋正方 《中国天文和天体物理学报》1997,(1)

本文从Zernike多项式出发 ,推导了激光导引星自适应光学倾斜校正的非等晕性方差 ,以其方差 1rad2 为判据 ,导出了倾斜等晕角的表达式 ,得出了与Parenti和Sasiela推导的相同的结果  相似文献   

LAST GLACIATION AND MAXIMUM GLACIATION IN THE QINGHAI-XIZANG (TIBET) PLATEAU: A CONTROVERSY TO M. KUHLE,S ICE SHEET HYPOTHESIS   总被引：1，自引：0，他引：1  

施雅风  郑本兴  李士杰 《中国地理科学(英文版)》1992,(4)

Since the late 1950's, many Chinese scientists have explored the remains of the Quaternary glaciation in the Qinghai-Xizang (Tibet) Plateau and its surrounding mountains. In the main, 3-4 glaciations have been recognized. The largest one occurred in the Late Middle Pleistocene with piedmont glaciers, ice caps and trellis valley glaciers in many high peak regions. But here is no evidence of a unified ice sheet covering the whole plateau as described by M. Kuhle. Due to the further uplifting of the Himalayas and Qinghai-Xizang Plateau the climate became progressively drier, diminishing the extension of glaciers during the Late Pleistocene. The elevation of the snow line during the Last Glaciation was about 4,000 m on the south, east and northeast edges of the plateau and ascended to 5500 m on the hinder northwest of the plateau. The thermal effect of the big plateau massif, the sharp increase of aridity from the southeast rim to the northwest inland area and the abrupt decrease of precipitation during the  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

ANALYSIS OF DRIVING FORCES ON THE CHANGE OF HISTORICAL FARMLAND USE IN SHANDONG PROVINCE DURING THE QING DYNASTY （1644-1911）     

ZHANGXue-qin GEQuan-sheng ZHENGJing-yun 《中国地理科学(英文版)》2003,13(3):207-215

How land-cover has been changed by human use over the last 300 years is one of the five overarching questions guiding the Land-use/Cover Change (LUCC) Science/Research Plan. China has variety of historical docu-ments providing unique data superiority. So the characteristics of farmland area in Shandong Province during the Qing Dynasty (1644-1911) are summarized firstly: 1) the rising trend of farmland area was striking; 2) farmland area had re-markable fluctuation; 3) farmland area per capita decreased dramatically; 4) wasteland reclamation index increased rapidly. Then, the driving forces of farmland area change are analyzed. It is concluded that natural and human factors are jointly influential. Among the driving forces, human dimensions are the main factors of farmland area change,which direct the general tendency of the changes mentioned above. And the natural factors influence the stability of farmland area as well. Variation of the natural factors would act as the major contributory factor to farmland area change during years or periods of abrupt climatic changes, or during the intensive occurring periods of natural hazards.Besides, the passive aspects of human factors, such as war chaos also influenced the fluctuation of the farmland area.This research indicates that it is feasible to study the land-use/cover change by Chinese historical literatures, which has huge potential to provide a comprehensive picture of the growing dominance of human land-use and land-cover pat-terns that can be used in many global change research oroiects.  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献