邻菲啰啉在测定亚铁中的保护效果          下载免费PDF全文

张会堂  刘瑄  刘渝燕  刘晶  巩宝珍 《山东国土资源》2003,19(1):54-56

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果  相似文献   

AR（P）参数估计协方差方法与其改进型方法的对比研究     

楚岩  祝轩 《地球科学与环境学报》1997,(Z1)

定性分析协方差方法及其改进型在ＡＲ（Ｐ）参数估计中的应用，提供了一种估计参数的计算机上机流程图，比较了协方差方法及其改进型谱估计结果。  相似文献   

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

基于专家系统决策的多模式控制及其应用     

宣森 《广东海洋大学学报》1993,(1)

将专家系统技术与常规控制、模糊控制、超前控制、仿人智能操作控制以及计算机控制技术相结合,设计了一种新的基于专家系统决策的多模式控制(MCDBES)。经试验和实际运行结果表明,MCDBES系统对未知数学模型的被控对象,具有良好的控制性能。本文提出的MCDBES已成功地应用于燃油陶瓷窑炉计算机控制系统。  相似文献   

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年     

guochunli 《地质学报》2008,82(1):1274-1284

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。  相似文献   

Biodiversity of meiofauna in the intertidal khe nhan mudflat,can gio mangrove forest,vietnam with special emphasis on free living nematodes     

Quang Ngo Xuan  Ann Vanreusel  Nguyen Vu Thanh  Nic Smol 《Ocean Science Journal》2007,42(3):135-152

The ecological aspect of meiofaunal communities in Can Gio mangrove forest, Ho Chi Minh city, Vietnam has not been investigated before. The composition, distribution, density and biodiversity of meiofaunal communities were studied along an intertidal transect at the Khe Nhan mudflat. Each time, three replicate samples were collected in four stations along a transect following the water line from low tide level up to the mangrove forest edge. In total, 18 meiofaunal taxa were found with the dominant taxa belonging to Nematoda, Copepoda, Sarcomastigophora and Polychaeta. The densities of meiofauna ranged from 1156 inds/10 cm² to 2082 inds/10 cm². The increase in densities from the mangrove forest edge towards the low water line was significant. Along the mudflat transect, the biodiversity (expressed by different indices) was relatively high at different taxonomic levels but did not vary significantly along the mudflat except for taxa richness. Eighty nematode genera belonging to 24 families with Comesomatidae having the highest abundance 33.8 % were found.Theristus andNeochromadora decreased in densities from the lower water line towards the mangrove forest edge, whileParacomesoma andHopperia are typical and more abundant at the middle of the mudflat.Halalaimus increased from high on the mudflat to the low water line.  相似文献   

静态精密单点定位精度分析   总被引：1，自引：0，他引：1  

王亦欣  邹璇 《测绘信息与工程》2008,33(2):14-16

阐述了精密单点定位技术的应用价值,分析了观测数据和精密钟差采样间隔对静态精密单点定位的影响,提供了工程实际使用有益的参考.  相似文献   

Early Uplift History of the Tibetan Plateau:Records from Paleocurrents and Paleodrainage in the Hoh Xil Basin     

YI Haisheng  WANG Chengshan  SHI Zhiqiang  LIN Jinhui  ZHU Lidong 《《地质学报》英文版》2008,82(1):206-213

Paleocurrent indicator data collected in field work were used to study the early Cenozoic regional paleodrainage patterns in the Hob Xil basin in northern Tibetan plateau. The paleocurrent directions of the Eocene Fenghuoshan Group obviously show that the flows were northward with a unidirectional dispersal pattern. This probably reflects the uplift of the Qiangtang terrain during the initial basin deposition period and indicates that the Tanggula Moutains occurred as topographic highlands at least in the Eocene. Paleoflows of the Oligocene Yaxicuo Group were dominantly oriented to the north and then flowed eastwards during its late deposition. This regional variability of paleodrainage patterns of the Yaxicuo Group is interpreted to record the dispersal style of sediments from transverse rivers to longitudinal river systems. It is inferred that the Oligocene uplift of the Kunlun Mountains obstructed by northward paleoflows and created longitudinal river systems parallel to the orogenic belts. The temporal and spatial changes of the paleodrainage patterns suggest that the northern boundary of the Tibetan plateau during the early Cenozoic was situated in the Hoh Xil area and its uplift has progressed northwards through time.  相似文献   

准噶尔盆地中拐地区下侏罗统层序地层特征与聚煤控制因素分析     

刘爱华  张尚锋  陈轩  刘军钊  王雅宁  贺子倩  熊冉 《安徽地质》2008,18(4):264-268

在分析前人对准噶尔盆地层序地层学研究成果的基础上,综合应用岩心、测井和地震资料,对准噶尔盆地西北缘中拐地区下侏罗统进行层序地层划分,总结了层序和体系域界面的识别标志,将下侏罗统划分为4个三级层序和7个体系域,同时叙述了各三级层序的结构特征。通过对层序内含煤岩系的发育特点分析,发现其主力煤层主要发育在JSQI和JSQ3湖侵体系域中,本文作者认为研究区内湖侵时期为有利的聚煤时期,聚煤作用主要受构造沉降、物源供给、气候和沉积环境等因素的控制。  相似文献   

中国奥陶纪地理区划纲要          下载免费PDF全文

周志毅  甄勇毅  周志强  袁文伟 《古地理学报》2008,10(2):175-182

根据区域构造、古地理和地层资料,中国奥陶纪的诸多板块、地体和活动带应分属11个地理区。文章重点研究了各地理区的边界。这些相邻的地理区块在奥陶纪曾处于远距离分离状态,除华北区南界和华南区北界明显由同期秦岭活动带限定之外,地理区的界线大多只能沿发生在奥陶纪之后的构造拼贴结合带划定,只有塔里木区北界和北疆区南界,得以通过追索代表曾在奥陶纪时段内发育于塔里木板块/哈萨克斯坦中间板块/西伯利亚板块之间的局限洋盆或深海盆地遗迹（即残留缝合带）来予以确定。中国大陆的最终形成经历了从晚石炭世至新生代的长期地质演化过程,主要包括活动带的消减以及板块和地体的漂移、增生与会聚。  相似文献