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基于热模拟实验的富有机质泥页岩成岩作用及演化特征   总被引:1,自引:0,他引:1  
富有机质泥页岩蕴含丰富的油气资源,但成岩研究基础薄弱,已成为制约页岩油气勘探开发进程的重要因素。通过开展成岩热模拟实验,结合扫描电镜观察、流体成分测试及有机酸测试等实验测试手段,全面描述实验过程中所发生的水-岩化学反应,试图揭示泥页岩成岩过程及成岩演化规律。研究结果显示,有机质热演化过程中存在一个较宽的有机酸生成窗口,对孔隙流体性质具有重要影响;长石和方解石存在接力溶蚀现象,长石溶蚀高峰过后紧接着出现方解石溶蚀高峰,但方解石溶蚀窗较窄,此后出现方解石重新沉淀结晶;黏土矿物转化及长石的溶蚀过程中会产生大量自生微晶石英,成链状或簇状胶结泥页岩骨架。泥页岩地层作为一个相对封闭体系,各类成岩作用之间相互关联,相互影响,构成错综复杂的成岩体系,进一步增加其成岩作用研究难度。  相似文献   
3.
Extreme events have gained considerable scientific attention recently due to their potentially catastrophic impacts. Heat waves are thought to be more pronounced now in most parts of the world, and especially in South Asia, but doubts remain. The aim of this study is to calculate the frequency and intensity of heat waves in South Asia, focusing on Pakistan and identifying the regions within Pakistan that are most vulnerable to heat waves. Analyses have been performed both at provincial and country levels from 1961 to 2009. The provincial level analysis shows positive trends for heat waves of magnitudes ≥40°C and ≥45°C for 5 and 7 consecutive days. Events of magnitude ≥40°C and ≥45°C for 10 consecutive days also increased in frequency in Punjab, Sindh, and Balochistan. These regions are therefore considered to be the regions most vulnerable to heat wave events in Pakistan. The Balochistan region shows a consistently increasing trend throughout the study period, which may lead to more frequent drought in the future. The country level analysis indicates an increase in the frequency of 5 and 7 consecutive days heat waves at all defined temperature thresholds. The 10-days heat waves spells show a slight increase at ≥40°C and no significant change at ≥45°C. The Gilgit Baltistan and Azad Jammu & Kashmir areas reported no events at ≥45°C for 5, 7 and 10 continuous days. It is anticipated that with a long term rise in temperatures around the globe, heat waves will become more frequent and intense in all parts of the world, including Pakistan.  相似文献   
4.
Arsenotrophic bacteria contribute to the nutrient cycling in arsenic (As) affected groundwater. This study employed a culture‐independent and ‐dependent investigation of arsenotrophic microbiomes in As affected groundwater samples collected from Madhabpur, Sonatengra, and Union Porishod in Singair Upazila, Manikganj, Bangladesh. Total As contents, detected by Atomic Absorption Spectrophotometry (AAS) of the samples, were 47 µg/L (Madhabpur, SNGW‐1), 53 µg/L (Sonatengra, SNGW‐2), and 12 µg/L (Union porishod, SNGW‐3), whereas the control well (SNGW‐4; depths >150 m) showed As content of 6 µg/L. Denaturing Gradient Gel Electrophoresis (DGGE) analysis of the amplified 16S rRNA gene from As‐affected groundwater samples revealed the dominance of aerobic bacteria Pseudomonas within heterogeneous bacterial populations. DGGE of heterotrophic enrichments supplemented with arsenite [As (III)] for 4 weeks showed the dominance of Chryseobacterium, Flavobacterium, and Aquabacterium, whereas the dominant genera in that of autotrophic enrichments were Aeromonas, Acinetobacter, and Pseudomonas. Cultured bacteria retrieved from both autotrophic and heterotrophic enrichments were distinguished into nine genotypes belonging to Chryseobacterium, Acinetobacter, Escherichia, Pseudomonas, Stenotrophomonas, Janibacter, Staphylococcus, and Bacillus. They exhibited varying range of As(III) tolerance from 4 to 27 mM. As(III) transformation potential was confirmed within the isolates with oxidation rate as high as 0.143 mM/h for Pseudomonas sp. Sn 28. The arsenotrophic microbiome specifies their potential role in groundwater As‐cycling and their genetic information provide the scientific basis for As‐bioremediation.  相似文献   
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The Indo-Gangetic aquifer is one of the world’s most important transboundary water resources, and the most heavily exploited aquifer in the world. To better understand the aquifer system, typologies have been characterized for the aquifer, which integrate existing datasets across the Indo-Gangetic catchment basin at a transboundary scale for the first time, and provide an alternative conceptualization of this aquifer system. Traditionally considered and mapped as a single homogenous aquifer of comparable aquifer properties and groundwater resource at a transboundary scale, the typologies illuminate significant spatial differences in recharge, permeability, storage, and groundwater chemistry across the aquifer system at this transboundary scale. These changes are shown to be systematic, concurrent with large-scale changes in sedimentology of the Pleistocene and Holocene alluvial aquifer, climate, and recent irrigation practices. Seven typologies of the aquifer are presented, each having a distinct set of challenges and opportunities for groundwater development and a different resilience to abstraction and climate change. The seven typologies are: (1) the piedmont margin, (2) the Upper Indus and Upper-Mid Ganges, (3) the Lower Ganges and Mid Brahmaputra, (4) the fluvially influenced deltaic area of the Bengal Basin, (5) the Middle Indus and Upper Ganges, (6) the Lower Indus, and (7) the marine-influenced deltaic areas.  相似文献   
6.
The 1991 Gulf oil spill heavily impacted the coastal areas of the Saudi waters of the Arabian Gulf and recent studies have indicated that even 15 years after the incident, macrobenthos had not completely recovered in the sheltered bays in the affected region such as, Manifa Bay. This study investigates the community conditions of macrobenthos in the open waters in one of the impacted areas, Al-Khafji waters, about 14 years after the spill. Diversity measures and community structure analyses indicate a healthy status of polychaete communities. The BOPA index reveals that oil sensitive amphipods were recolonized in the study area. This confirms that the benthic communities of the oil spill impacted area had taken only <14 years to recover in the open waters of the impacted areas. The study also reveals the existence of three distinct polychaete communities along the depth and sediment gradients.  相似文献   
7.
The Ganges River water and riverbank shallow groundwater were studied during a single wet season using the hydrochemical and isotopic composition of its dissolved load. The dissolved concentrations of major ions (Cl?, SO4 2?, NO3 ?, HCO3 ?, Ca2+, Na+, Mg2+, and K+), trace elements (barium (Ba) and strontium (Sr)) and stable isotopes (O and D) were determined on samples collected from the Ganges River and its riverbank shallow aquifers. In the present study, the shallow groundwater differs significantly from the Ganges River water; it shows distinct high concentrations of Ca2+, Mg2+, HCO3 ?, Ba, and Sr due to water–rock interaction and this in particular suggests that the Ganges River may not contribute significantly to the riverbank shallow aquifers during wet season. Besides, the sum of the total cationic charge (∑+, in milliequivalents per liter) in the groundwater shows high values (2.48 to 13.91 meq/L, average 9.12 meq/L), which is much higher than the sum of the cations observed in the Ganges water (1.36 to 3.10 meq/L, average 1.94 meq/L). Finally, the more depleted stable isotopic (δ 18O and δ 2H) compositions of the Ganges River water are in contrast to those of the riverbank aquifer having enriched stable isotopic values during the wet season and the riverbank groundwater thus has a purely local origin from precipitation.  相似文献   
8.
This study investigates the values of pH, total dissolved solids (TDS), elevation, oxidative reduction potential (ORP), temperature, and depth, while the concentrations of Br, and potentially harmful metals (PHMs) such as Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe in the groundwater samples. Moreover, geographic information system (GIS), XLSTAT, and IBM SPSS Statistics 20 software were used for spatial distribution modeling, principal component analysis (PCA), cluster analysis (CA), and Quantile-Quantile (Q-Q) plotting to determine groundwater pollution sources, similarity index, and normal distribution reference line for the selected parameters. The mean values of pH, TDS, elevation, ORP, temperature, depth, and Br were 7.2, 322 mg/L, 364 m, 188 mV, 29.6 °C, 70 m, 0.20 mg/L, and PHMs like Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe were 0.38, 0.26, 0.08, 0.27, 0.36, 0.22, 0.04, 0.43 and 0.86 mg/L, respectively. PHMs including Cr (89%), Cd (43%), Mn (23%), Pb (79%), Co (20%), and Fe (91%) exceeded the guideline values set by the world health organization (WHO). The significant R2 values of PCA for selected parameters were also determined (0.62, 0.67, 0.78, 0.73, 0.60, 0.87, ?0.50, 0.69, 0.70, 0.74, ?0.50, 0.70, 0.67, 0.79, 0.59, and ?0.55, respectively). PCA revealed three geochemical processes such as geogenic, anthropogenic, and reducing conditions. The mineral phases of Cd(OH)2, Fe(OH)3, FeOOH, Mn3O4, Fe2O3, MnOOH, Pb(OH)2, Mn(OH)2, MnO2, and Zn(OH)2 (?3.7, 3.75, 9.7, ?5.8, 8.9, ?3.6, 2.2, ?4.6, ?7.7, ?0.9, and 0.003, respectively) showed super-saturation and under-saturation conditions. Health risk assessment (HRA) values for PHMs were also calculated and the values of hazard quotient (HQ), and hazard indices (HI) for the entire study area were increased in the following order: Cd>Ni>Cu>Pb>Mn>Zn>Cr. Relatively higher HQ and HI values of Ni, Cd, Pb, and Cu were greater than one showing unsuitability of groundwater for domestic, agriculture, and drinking purposes. The long-term ingestion of groundwater could also cause severe health concerns such as kidney, brain dysfunction, liver, stomach problems, and even cancer.  相似文献   
9.
Parkachik Glacier is located in the Suru sub-basin of the Upper Indus River, Zanskar Himalaya. The Glacier has been analysed using Corona KH-4B (1971), Landsat-TM (1999), field survey (2015), Google EarthTM (2015) and ASTER GDEM (2015) for frontal recession and area changes. Overall, from 1971 to 2015, the Glacier has retreated by 127 ± 0.09 m i.e. (0.75 ± 0.07%) at a rate of 2.9 ± 0.004 ma?1 with a simultaneous decrease in area from 49.5 to 48.8 km2 i.e. 740 ± 0.7 m2 (1.5 ± 0.09%) at a rate of 74 ± 0.7 m2a?1. However, during recent decade (1999–2015), the rate of glacier recession of 3.9 ± 0.004 ma?1 with a corresponding area loss of 500 ± 0.74m2 (1 ± 0.1%) was higher than the retreat rate of 2.3 ± 0.001 ma?1 and an area loss of 240 ± 0.02m2 (0.48 ± 0.08%) during 1971–1999. In the field, the evidences of glacier recession are present in the form of separated dead ice blocks from the main Glacier, recessional dumps/moraines, active ice calving activity and a small proglacial pond/lake at the terminus/snout of the Glacier. However, the recession over the studied period has been very slow and is controlled by its topographic configuration, particularly the large altitudinal range (6030–3620 m), almost northerly aspect and steep slope (average ~ 30°).  相似文献   
10.
Soil nutrient maps based on intensive soil sampling are useful to adopt site-specific management practices. Geostatistical methods have been widely used to determine the spatial correlation and the range of spatial dependence at different sampling scales. If spatial dependence is detected, the modeled semivariograms can then be used to map the interested variable by kriging, an interpolation method that produces unbiased estimates with minimal estimation variance. The objectives of this paper were to examine and map the spatial distribution of the soil micronutrients Cu, Zn, Fe and Mn on an agricultural area in Kupwara, J&K, under temperate climatic conditions. The ordinary kriging was first used to determine the values for the non-sampled locations, and then the indicator approach was used to transform the micronutrient content values into binary values having the mean values of each nutrient as the threshold content. All four elements analyzed showed spatial dependence using the indicator semivariograms. The strength of spatial dependence was assessed using the values of nugget effect and range from the semivariogram, the fitted range values decreased in the order Zn > Cu > Mn > Fe. The spatial dependence of the combination of two or more of the studied micronutrients was also examined using indicator semivariograms. In opposition to spatial analysis of individual microelements, indicator semivariograms obtained for the binary coding of the variables showed a great nugget effect value or a low proportion of sill. The maps for each nutrient obtained using indicator kriging showed some similarity in the spatial distribution, suggesting the delimitation of uniform management areas.  相似文献   
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