The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg     

Carlton D. Hunt  William F. Fitzgerald 《Marine Chemistry》1983,12(4)

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.  相似文献   

How U.S. ocean policy and market power can reform the coral reef wildlife trade     

Brian N. Tissot  Barbara A. Best  Eric H. Borneman  Andrew W. Bruckner  Cara H. Cooper  Heather D’Agnes  Timothy P. Fitzgerald  Amanda Leland  Susan Lieberman  Amy Mathews Amos  Rashid Sumaila  Teresa M. Telecky  Frazer McGilvray  Brian J. Plankis  Andrew L. Rhyne  Glynnis G. Roberts  Benjamin Starkhouse  Todd C. Stevenson 《Marine Policy》2010

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.  相似文献   

The sources and composition of mercury in Pacific Ocean rain   总被引：1，自引：0，他引：1  

R. P. Mason  W. F. Fitzgerald  G. M. Vandal 《Journal of Atmospheric Chemistry》1992,14(1-4):489-500

Here we report measurements of total Hg (Hg_T), reactive Hg (Hg_R), and methylmercury (MMHg) in precipitation from the equatorial Pacific Ocean, collected during a cruise in January and February 1990, and from a mid-continental location in the rural temperate lacustrine northcentral Wisconsin environs. The concentrations of Hg_T (14.4±6.5 pM), Hg_R (8.9±4.5 pM) and MMHg (<50 fM) found in equatorial Pacific rain were less than the average concentrations found in Wisconsin. In general, the results indicate that although particulate Hg is a small fraction of the total atmospheric Hg burden, it is the major contributor to Hg in precipitation. Furthermore, deposition could be an important source of Hg_R to the equatorial Pacific Ocean. In contrast, deposition is not a significant source of MMHg to either the equatorial Pacific Ocean or the remote seepage lakes of Wisconsin. This implies that methylated mercury is formedin situ in these systems.  相似文献   

西天山喇嘛苏铜矿成矿斑岩的岩石学、地球化学特征及成因探讨   总被引：7，自引：3，他引：4  

张东阳  张招崇  薛春纪  艾羽 《岩石学报》2010,26(3):680-694

位于西天山别珍套-科古琴晚古生代岛弧西段的喇嘛苏铜矿床是区内最大的铜矿床,与成矿作用有着密切关系的斑岩体为英云闪长斑岩、花岗闪长斑岩,是同源岩浆分异演化的产物,且花岗闪长斑岩可能属于岩浆演化晚期的产物。本区成矿斑岩的主量、微量元素和Sr-Nd同位素地球化学特征表明,其富集大离子亲石元素,而相对亏损高场强元素,出现了较为明显的Ta、Nb负异常,初始锶同位素ISr和εNd(t=390Ma)值分别为0.7072～0.7076和-0.32～0.17,显示壳幔混合源的特征,利用Sr和Nd同位素估算其源区物质约有50%来源于地壳。岩石地球化学特征指示了其为典型钙碱性火山弧花岗岩,暗示其形成于大陆弧环境。结合区域地质背景,推测本区成矿斑岩是在洋壳俯冲作用下发生部分熔融,交代原先的地幔楔,并混合了部分下地壳的物质,经历分离结晶作用的产物,其形成可能与晚古生代准噶尔洋板块向南的俯冲作用有关。结合东西天山的成矿斑岩的地球化学特征对比研究,岩浆源区的差别可能导致不同类型斑岩型矿床的形成,斑岩型铜矿床的形成较斑岩型钼矿床可能有更少的地壳物质贡献。  相似文献   

Do people “personally experience” global warming,and if so how,and does it matter?   总被引：1，自引：0，他引：1  

Karen Akerlof  Edward W. Maibach  Dennis Fitzgerald  Andrew Y. Cedeno  Amanda Neuman 《Global Environmental Change》2013,23(1):81-91

For most people, the direct and personally observable signals of climate change should be difficult to detect amid the variability of everyday weather. Yet, previous research has shown that some people believe they have personally experienced global warming. Through four related studies, our paper sheds light on what signals of global warming some people believe they are detecting, why, and whether or not it matters. These studies were conducted using population survey and climatic data from a single county in Michigan. Study 1 found that 27% of the county's adult residents felt that they had personally experienced global warming. Study 2 – based on content analysis of people's open-ended responses – found that the most frequently described personal experiences of global warming were changes in seasons (36%), weather (25%), lake levels (24%), animals and plants (20%), and snowfall (19%). Study 3 – based on NOAA climatic data – found that most, but not all, of these detected signals are borne out in the climatic record. Study 4 – using the survey data – found that personal experience of global warming matters in that it predicts perceptions of local risk of global warming, controlling for demographics, political affiliation, and cultural beliefs about national policy outcomes. We conclude that perceived personal experience of global warming appears to heighten people's perception of the risks, likely through some combination of direct experience, vicarious experience (e.g., news media stories), and social construction.  相似文献   

TIBOOBURRA,A NEW AUSTRALIAN METEORITE FIND,AND OTHER CARBONACEOUS CHONDRITES OF HIGH PETROLOGIC GRADE     

M.J. Fitzgerald  A.L. Jaques 《Meteoritics & planetary science》1982,17(1):9-26

Tibooburra, a new meteorite find from western New South Wales, belongs to the Vigarano subgroup of the carbonaceous chondrites and, on the basis of its opaque mineralogy, appears to be oxidised. Petrological evidence suggests that, like the Allende meteorite, Tibooburra is a CV3 chondrite which has experienced greater metamorphic effects than other CV3 meteorites. Tibooburra has a bulk composition intermediate between the CO and less altered CV chondrites. This transitional nature is exhibited by several elements and is convincingly displayed by the multivariate techniques of cluster analysis and principal component analysis. Tibooburra thus resembles several other CV chondrites, such as Coolidge and Karoonda, which have been strongly metamorphosed. This group of meteorites is believed to have accreted early in the history of the Vigarano parent body and, as a result, contain greater quantities of high temperature Ca-Al-rich inclusions but less low temperature matrix and volatile phases than other CV chondrites. Furthermore, in these meteorites both the matrix and magnesium silicate phases appear to be more iron rich than those in later accreted meteorites. Subsequently, these deeper seated meteorites have undergone more pronounced thermal metamorphism than those located in shallower portions of the parent body.  相似文献   

ADELAIDE AND BENCH CRATER — MEMBERS OF A NEW SUBGROUP OF THE CARBONACEOUS CHONDRITES     

M.J. Fitzgerald  J.B. Jones 《Meteoritics & planetary science》1977,12(4):443-458

The composition and mineralogy of Bench Crater and a new carbonaceous chondrite (Adelaide) are compared. They, Kakangari and possibly certain carbonaceous xenoliths from other meteorites constitute a distinct chemical subgroup of the carbonaceous chondrites characterized primarily by a calcium-to-aluminium ratio (atomic) of about 0.5. It is proposed to call this group the Kakangari (CK) group  相似文献   

Relationships between molecular bacterial diversity and chemistry of groundwater in the Wairarapa Valley,New Zealand     

KA Sirisena  CJ Daughney  M Moreau  KG Ryan  GK Chambers 《新西兰海洋与淡水研究杂志》2013,47(4):524-539

Groundwater plays an important role in New Zealand water supplies and hence monitoring activities are conducted regularly. Most monitoring programmes aim to evaluate groundwater chemistry and almost completely overlook the microbial component in this ecosystem. In our present study, the bacterial community structure of groundwater in the Wairarapa Valley was examined using the terminal restriction fragment length polymorphism (T-RFLP), and relationships between bacterial community structure and groundwater chemistry, aquifer confinement and groundwater usage were explored. In addition, the results from this study were compared with a previous T-RFLP survey of the same area in an attempt to detect changes in bacterial community structure over time. The data obtained suggested that bacterial community structure was related to groundwater chemistry, especially to redox conditions. Species composition showed minimal variation over time if groundwater chemistry remained unchanged. These findings reflect the potential of using bacterial communities as biological indicators to evaluate the health of groundwater ecosystems. We suggest that it is important to include this type of broad bacterial diversity assessment criteria into regular groundwater monitoring activities.  相似文献   

Competitive Sorption of Antimony with Zinc,Nickel, and Aluminum in a Seaweed Based Fixed‐bed Sorption Column     

Adil Bakir  Peter McLoughlin  Syed A. M. Tofail  Eddy Fitzgerald 《洁净——土壤、空气、水》2009,37(9):712-719

The removal of heavy metals such as Ni(II), Zn(II), Al(III), and Sb(III) from aqueous metal solutions was investigated using novel, cost effective, seaweed derived sorbents. Studies with a laboratory scale fixed‐bed sorption column, using a seaweed waste material (referred to as waste Ascophyllum product (WAP)) from the processing of Ascophyllum nodosum as biosorbent, demonstrated high removal efficiencies (RE) for a variety of heavy metals including Ni(II), Zn(II) and Al(III), with 90, 90 and 74% RE achieved from initial 10 mg/L metal solutions, respectively. The presence of Sb(III) in multi component metal solutions suppressed the removal of Ni(II), Zn(II) and Al(III), reducing the RE to 28, 17 and 24%, respectively. The use of Polysiphonia lanosa as a biosorbent showed a 67% RE for Sb(III), both alone and in combination with other metals. Potentiometric and conductometric titrations, X‐ray photoelectron and mid‐infrared spectroscopic analysis demonstrated that carboxyl, alcohol, sulfonate and ether groups were heavily involved in Sb(III) binding by P. lanosa. Only carboxyl and sulfonate groups were involved in Sb(III) binding by WAP. Furthermore, a greater amount of weak acidic groups (mainly carboxylic functions) were involved in Sb(III) binding by P. lanosa, compared to WAP which involved a greater concentration of strong acidic groups (mainly sulfonates).  相似文献   

Photochemical fractionation of16O in the space medium modeled by resonance excitation of CO by H-Lyman α     

G. Arrhenius  M. J. Corrigan  R. W. Fitzgerald 《Astrophysics and Space Science》1988,145(2):303-318

Inferences about the formation of primordial matter in our solar system rest on analysis of the earliest preserved materials in meteorites, of the structure of the solar system today, and of matter in evolving stellar systems elsewhere.The isotope distribution in meteorites suggests that molecular excitation processes similar to those observed today in circumstellar regions and dark interstellar clouds were operating in the early solar nebula. Laboratory model experiments together with these observations give evidence on the thermal state of the source medium from which refractory meteoritic dust formed. They indicate that resonance excitation of the broad isotopic bands of molecules such as¹²C¹⁶O, MgO, O₂, AlO, and OH by strong UV line sources such as H-L, MgII, H, and CaII may induce selective reactions resulting in the anomalous isotopic composition of oxygen and possibly other elements in refractory oxide condensates in meteorites.  相似文献