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高砷含水层沉积物矿物学特征及砷的活化   总被引:2,自引:0,他引:2  
利用X射线衍射和X射线荧光分析、沉积物序列提取试验及矿物饱和度的计算,对采自江汉平原中部沙湖地区典型高砷含水层钻孔沉积物样品矿物学进行了分析,并讨论了控制含水层中砷释放和迁移的地球化学机制.对矿物在沉积物与土壤中的分布及组成的对比分析,在一定程度上指示了矿物赋存环境和/或高砷水形成的环境背景:土壤与沉积物中高岭石以低于其他3种粘土矿物的含量普遍存在,指示了含水层沉积物形成过程江汉平原存在一定的湿热古气候环境;沉积物绿泥石含量低于土壤中绿泥石,恰恰反映了土壤比沉积物略强的碱性环境;沉积物中黄铁矿的存在,显示了含水层局部的强还原性环境,指示地下水中广泛存在的Fe2+容易与二价硫发生沉淀并结合砷.砷主要以无定形铁锰氧化物结合态(平均在31%以上)形式存在,其次以碳酸盐和有机质结合态存在.无定形铁锰氧化物的还原溶解可能是控制砷迁移到地下水中主要的地球化学机制.相对高含量的绿泥石容易在含水层中发生风化,其溶解过程可以将铁释放到地下水中,从而成为影响地下水中砷活化的潜在因素.  相似文献   
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The mixed layer of the ocean and the processes therein affect the ocean’s biological production, the exchanges with the atmosphere, and the water modification processes important in a climate change perspective. To provide a better understanding of the variability in this system, this paper presents time series of the mixed layer properties depth, temperature, salinity, and oxygen from Ocean Weather Station M (OWSM; 66° N,2° E) as well as spatial climatologies for the Norwegian Sea. The importance of underlying mechanisms such as atmospheric fluxes, advective signals, and dynamic control of isopycnal surfaces are addressed. In the region around OWSM in the Norwegian Atlantic Current (NwAC) the mixed layer depth varies between ∼20 m in summer and ∼300 m in winter. The depth of the wintertime mixing here is ultimately restrained by the interface between the Atlantic Water (AW) and the underlying water mass, and in general, the whole column of AW is found to be mixed during winter. In the Lofoten Basin the mean wintertime mixed layer reaches a depth of ∼600 m, while the AW fills the basin to a mean depth of ∼800 m. The temperature of the mixed layer at OWSM in general varies between 12 °C in summer and 6 °C in winter. Atmospheric heating controls the summer temperatures while the winter temperatures are governed by the advection of heat in the NwAC. Episodic lateral Ekman transports of coastal water facilitated by the shallow summer mixed layer is found important for the seasonal salinity cycle and freshening of the northward flowing AW. Atmospheric freshwater fluxes have no significant influence on the salinity of the AW in the area. Oxygen shows a clear annual cycle with highest values in May-June and lowest in August-September. Interannual variability of mixed layer oxygen does not appear to be linked to variations in any of the physical properties of the mixed layer.  相似文献   
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Organic matter was studied in the turbidity maximum zone (TMZ) of the Seine Estuary during 8 tidal cycles from April to October in 2001, 2002 and 2003, covering a salinity range from 0 to 27. The hydrological conditions were quite varied (extremely wet in 2001, unusually dry in 2003). A particularly striking feature is the high organic matter content in the suspended solids (SS) of the Seine estuary (4–5%).  相似文献   
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Chemical and isotopic analysis of karst water dripping over a one year period from seeps in a cave above the Cenomanian aquifer in the Judea hills of Israel lead to several conclusions: (i) The tritium ages and the chemical composition of water from different seeps in a karstic cave vary greatly, (ii) The reservoirs in the upper part of the vadose zone hold water for up to several decades, (iii) Some of the cave seeps are mixtures of the old and more recent meteoric water from paths of different length, (iv) The history of storm events can only be traced in some of the seeps, (v) For most dripping seeps there is no immediate response of seepage discharge to the rainfall intensity and quantity—i.e. the seepage discharge is fairly constant.  相似文献   
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The ecologically and socio-economically important marine ecosystems of Europe are facing severe threats from a variety of human impacts. To mitigate and potentially reverse some of these impacts, the European Union (EU) has mandated the implementation of the Marine Strategy Framework Directive (MSFD) in order to achieve Good Environmental Status (GES) in EU waters by 2020. The primary initiative for achieving GES is the implementation of coherent networks of marine protected areas (MPAs). Marine reserves are an important type of MPA in which no extraction is allowed, but their usefulness depends upon a number of ecological, management, and political factors. This paper provides a synthesis of the ecological effects of existing European marine reserves and the factors (social and ecological) underlying their effectiveness. Results show that existing European marine reserves foster significant positive increases in key biological variables (density, biomass, body size, and species richness) compared with areas receiving less protection, a pattern mirrored by marine reserves around the globe. For marine reserves to achieve their ecological and social goals, however, they must be designed, managed, and enforced properly. In addition, identifying whether protected areas are ecologically connected as a network, as well as where new MPAs should be established according to the MSFD, requires information on the connectivity of populations across large areas. The adoption of the MSFD demonstrates willingness to achieve the long-term protection of Europe's marine ecosystems, but whether the political will (local, regional, and continent wide) is strong enough to see its mandates through remains to be seen. Although the MSFD does not explicitly require marine reserves, an important step towards the protection of Europe's marine ecosystems is the establishment of marine reserves within wider-use MPAs as connected networks across large spatial scales.  相似文献   
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Recent developments in sensing and tracking technologies have enabled large geographical databases to be established that represent spatial dynamics of ‘behavioral entities’. Within this type of dynamics there are several levels and modes of organization that need to be revealed. Clusters are high‐level groupings of entities, where change in their location and form, including split and merge events, represents self‐organization and functioning patterns. Such information may contribute for better understanding spatially complex dynamic patterns. The main objective of this article is to develop an adaptable methodology that facilitates exploration of spatial order and processes in point pattern dynamics. The approach presented here utilizes data‐clustering at each snapshot of the moving pattern, and then involves pairwise linking between the clusters identified at each snapshot and those identified in the following snapshot. Such linking is based on a new methodology that defines well globally optimized solutions for numerous possible linking combinations based on Linear Programming. A preliminary assessment of the approach was conducted with an existing Ants' simulation tool, capable of creating data sets covering in detail a substantial portion of the nest's life cycle.  相似文献   
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This paper treats the problem in linearized water wave theory that arises when a wave travels across a submerged cylinder. This problem is classical and was first treated by Dean. The solution presented is novel and explicit. This is achieved through the use of certain recursive relations. The basic results are of course the same as in the older literature: (1) the coefficient of reflection is zero; (2) the only effect of the cylinder, is a phase shift relative to the undisturbed wave. However, the practical computation of the velocity potential and the phase shift is reduced almost to hand calculations. This is in contrast to the older literature which requires, in principle, the inversion of an infinite matrix. The work is motivated by the Institue's efforts to focus water waves. Cylinders are possible bodies to create the necessary phase shifts to achieve such focusing.  相似文献   
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