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Aromatic ketones were concentrated from filtered Baltic Sea water by liquid—solid adsorption. After wet-chemical separation from acidic and basic components, the neutral fraction was column chromatographed to yield sub-fractions of increasing polarity. A subfraction eluted from silica gel with cyclopentane/diethyl ether contained a number of compounds which were identified by GC and GC—MS techniques as fluorenone, anthraquinone, benzanthrone, and benzene derivatives carrying an oxo group in the α-position relative to the aromatic ring. Formation and abiotic chemical reactions of these compounds in seawater are discussed.  相似文献   
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Aerial photographs taken in the 1963 and 2001 and bathymetric charts, in conjunction with coastal processes are analyzed to assess changes in rate of shoreline position, seabed level, and seabed grain sizes along the Tabarka–Berkoukech beach at the north-western Tunisian coastline. The littoral cell of this beach, 12-km-long, is bounded by pronounced embayments and rocky headlands separated by sandy stretches. Although not yet very much undeveloped, this littoral is still experienced degradation and modification, especially along its shoreline, with significant coastal erosion at some places. Results obtained from analysis of shoreline position indicate that El Morjene Beach is experienced a landward retreat of more than −62 m, at a maximum rate of −1.64 m/year, whereas the El corniche beach is advanced about 16–144 m, at an average rate of 0.42 m–3.78 m/year. This beach accretion has been formed on the updrift side of the Tabarka port constructed between 1966 and 1970. Comparison of bottom contours deduced from bathymetric charts surveyed in 1881 and 1996 off the coastline between Tabarka Port and El Morjene Beach identifies erosional areas (sediment source) and accretionary zones (sediment sink). Erosion (0.87–4.35 cm/year) occurs between El kebir River Mouth and El Morjene beach, whereas accretion exists in the zone down wind of the port ranges between 0.87 and 5.21 cm/year. Morphological analyses of the shoreline and the seabed of the study nearshore area indicate that shoreline retreat corresponds to areas of seabed scour (sediment source) while shoreline accretion is associated with areas of seabed deposition (sediment sink). Furthermore, simulation of wave propagation using STWAVE model combined with grain size distributions of the seabed shows that fine sands are much dominated in depositional areas with low wave energy, whereas coarser sands in erosive zones with high wave energy. The results obtained suggest that the change of seabed morphology, wave height pattern and grain size sediment have a great influence on the modification of shoreline morphology and dynamics.  相似文献   
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We analyzed the feedback of AGN jets on cooling flow clusters using three-dimensional AMR hydrodynamic simulations. We studied the interaction of the jet with the intracluster medium and creation of low X-ray emission cavities (Bubbles) in cluster plasma. The distribution of energy input by the jet into the system was quantified in its different forms, i.e. internal, kinetic and potential. We find that the energy associated with the bubbles, (pV+γ pV/(γ−1)), accounts for less than 10 percent of the jet energy.  相似文献   
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