Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait)   总被引：3，自引：2，他引：1  

Sonja Aulbach  Roberta L. Rudnick  William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92

Lithium concentrations and isotopic compositions of olivine and ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both δ⁷Li and Li concentrations. Olivines in iron-rich peridotites (Fo_85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ⁷Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively light δ⁷Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas. A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has a ⁸⁷Sr/⁸⁶Sr of 0.7029 and ¹⁴³Nd/¹⁴⁴Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared to previous estimates of the plume that were based on rift basalts. Although elevated δ⁷Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics in Sr, Nd and Li isotope composition. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments     

Abbondanzi F  Campisi T  Focanti M  Guerra R  Iacondini A 《Marine environmental research》2005,59(5):419-434

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.  相似文献   

High-resolution numerical modelling of convective precipitation over Northern Italy     

T. Paccagnella  S. Tibaldi  R. Buizza  S. Scoccianti 《Meteorology and Atmospheric Physics》1992,50(1-3):143-163

Summary A number of forecast experiments were performed in order to assess the capability of reproducing, by means of a limited-area numerical model, the highly structured mesoscale circulations occurring in the Po Valley of Northern Italy during a north-westerly cold front passage across the Alpine chain, with particular attention to the modelling of the effects of organized convection. The case-study occurred during summer 1987 and the model used throughout was the 1989 version of the UB/NMC Limited Area Model (University of Belgrade, National Meteorological Centre of Washington). The model was integrated both with eta, , and sigma, , as vertical coordinates and ECMWF initialized analyses were always used as initial conditions. ECMWF initialized analysis or operational forecast fields were also used for updating in time the lateral boundary conditions. Experiments show qualitative and quantitative agreement with observations, both in upper-air geopotential height fields, in MSLP and in cumulated precipitation. Several modelling issues were also investigated, e.g. sensitivity of the results to horizontal and vertical model resolution and to the influence of the lateral boundaries poitioning, finding large effects of the latter on quantitative precipitation fields. Difficulties in modelling very localized mesoscale phenomena, e.g. organized convective thunderstorms in the Po Valley and Alpine North Foehn in the Milan area, were generally encounted.  相似文献   

Quantitative Evaluation of Water Deposited By Dew on Monuments   总被引：1，自引：0，他引：1  

Dario Camuffo  Roberta Giorio 《Boundary-Layer Meteorology》2003,107(3):655-672

Samples of White and Green Carrara marble, and three types oflimestone and brick exposed in the field vertically and horizontally were used to evaluate condensationon monuments during clear sky nights. Experiments in a simulation chamber under controlledconditions led to a general equation for the actual amount of water deposited on a surface by dew.This is determined by: How much and for how long the surface temperature falls below the dew point,the moisture content in the air and the ventilation. On clear nights, the condensation on buildingstructures facing the sky may reach some 0.2 kg m^-2 (or 0.2 mm), whereas condensation on verticalsurfaces is very small. Computation of the seasonal trend of night-time condensationshowed that the maximum amount of water condensed per night occurs in the autumn, with the moreabundant concentration of moisture in the air. The total amount of water condensed per month isfound to be a maximum in the summer-autumn period. Morning condensationfor the thermal inertia of monuments is also relevant, and has been calculated to reach the same order of magnitude as thenocturnal dew. A detailed analysis of the temperature and mixing ratio profiles near a condensingsurface has shown two different situations. In still air, the two profiles follow an exponentiallaw and the thermal and the concentration layers lie within a few tens of millimetres. Inthe presence of turbulence, the thickness of these two layers is dramatically reduced. In still air, infront of a vertical, chilly surface, the deposition rate of air pollutants by thermophoresis and/orStefan flow is increased by 3 or 4 times in comparison with a horizontal surface. In the presence ofturbulence, the thickness of the thermal and concentration layers was dramatically reduced, makingthese two kinds of deposition much faster.  相似文献   

Tectono-sedimentary evolution of the Miocene Oued Dayr Formation (Ghomaride Complex,Internal Domain of the Maghrebian Rif Belt,Morocco)     

Bilal?El OuaragliEmail author  Mohamed?Najib?Zaghloul  Hajar?El Talibi  Roberta?Somma 《Arabian Journal of Geosciences》2016,9(15):660

This work deals with sedimentological, petrographic, and structural analyses of a middle Miocene late-orogenic sedimentary cycle, denoted Oued Dayr Formation, recognized in the Rifian sector of the Maghrebian Chain (Morocco). The analyzed Formation (75 m thick) starts with 15–20 m of light colored polymict conglomerates, with minor sandstone beds, lying on the Paleozoic basement and Mesozoic cover of the Ghomaride Nappe. Facies analysis indicates a fining-upward deposition in a marine environment characterized by increasing deepening, reflecting a subsidence rate that exceeds sedimentary supply. Petrographic analysis points out that sandstones are represented by litharenites originated by erosion of recycled orogen. The conglomerates pebbles and cobbles consist of Alpine low- to high-grade metamorphic rocks as metarenites, phyllites, mylonitic quartzites, micaschists, augen gneisses deriving from the exhumed deep metamorphic basement, the overlying metasedimentary of the Sebtide Nappes and of sedimentary rocks as sandstones, jaspes, limestones, and shales deriving from the Ghomaride Nappes and their sedimentary cover. Data reveal mixed provenance indicating that the Oued Dayr Formation was fed by the Internal Nappes stack of the Maghrebian Chain. Structural analysis shows that the Oued Dayr Formation accumulated in a Thrust-Top basin, during an early extension (D₀ phase), recorded by synsedimentary normal faults within middle Langhian deposits on the rear of the Internal Nappes stack. Subsequent ductile and brittle compressional (D₁, D₂, D₃) and extensional (D₄) deformation phases occurred during and/or after the stacking, exhumation, and early unroofing of Sebtide Complex coeval with the opening of the western Mediterranean back-arc basins since middle Miocene time.  相似文献   

Effects of two offshore gas platforms on soft-bottom benthic communities (northwestern Adriatic Sea, Italy)     

Sarine Manoukian  Alessandra Spagnolo  Giuseppe Scarcella  Elisa Punzo  Roberta Angelini  Gianna Fabi   《Marine environmental research》2010,70(5):402-410

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Initialization and data assimilation experiments with a primitive equation model     

Paola Malanotte-Rizzoli  Roberta E. Young  Dale B. Haidvogel 《Dynamics of Atmospheres and Oceans》1989,13(3-4)

The process of combining models of the ocean circulation with large data sets is known in meteorology as model initialization and data assimilation. This process is new to oceanographers, who only now are on the verge of having available world-wide synoptic maps of dynamic variables. In this paper we carry out a series of idealized initialization/assimilation experiments with a primitive equation (PE) model, which constitute a first step in developing a realistic process model and data assimilation techniques for the Gulf Stream system. The PE model is used in a spin-down mode and initialized with an analytic jet profile with geostrophically balanced fields.Two major questions are addressed in the present study. The first concerns the initialization process of a PE model during which internal/inertial gravity wave noise is produced. We ask: are the initialization shocks equally crucial for ocean models as they have been for their atmospheric counterparts? The results of an extensive series of balanced versus unbalanced initializations indicate that, for a PE model with a rigid lid, a brutally unbalanced initialization is required to produce strong internal gravity wave shocks. A geostrophically balanced initialization is sufficient to ensure smooth jet evolutions, with no apparent gravity waves, over long time durations in the spin-down mode. No sophisticated initialization procedures seem, therefore, to be required.The second question addressed is: which component of the flow is the most important in data assimilation to drive the model response towards a baseline reference ocean? We specifically compare the knowledge of the depth-integrated flow only, corresponding to measurements of the total transport, with the knowledge of the density field only, or equivalently the velocity shear. The knowledge of the interior density field is much more effective in decreasing the root-mean-square (r.m.s.) errors relative to the reference ocean. If the baroclinic structure is known, coarse horizontal resolutions of data insertion can be reached before significantly worsening the model estimates. If only the depth-averaged flow is known, a decrease in the horizontal resolution of data assimilation has an immediate effect: the r.m.s. errors sharply increase and the assimilation run diverges from the reference ocean. In the assimilation of the barotropic flow alone, even with dense resolution, the errors in the deep layers always show an increasing trend. The relative effectiveness of baroclinic versus barotropic data insertion can be rationalized in the context of geostrophic adjustment theory.  相似文献   

Dissolution mechanisms of silicate minerals yielded by intercomparison with glasses and radiation damage studies     

J. -C. Petit  J. -C. Dran  G. Della Mea  A. Paccagnella 《Chemical Geology》1989,78(3-4):219-227

The behaviour of two silicates (albite and olivine) toward aqueous dissolution has been investigated with emphasis to two aspects: (1) similarities and differences with silicate glasses; and (2) influence of ion bombardment which transforms the initially crystalline structure to a glass-like one. The occurrence on leached materials of hydrated layers enriched with metallic elements is checked by using high-energy ion beam analytical techniques.

It is shown that for both amorphous and crystalline silicates, dissolution involves competing processes responsible for either hydrated-layer generation (hydration by ion exchange and/or water permeation), or its destruction (hydrolysis of siloxane bonds and detachment of silica units). At moderate temperature ( 100°C), the latter processes dominate for crystalline silicates and the resulting dissolution is congruent. However, these silicates tend to behave like glasses upon ion bombardment above a critical dose. At higher temperature (> 200°C), hydration is markedly enhanced and thick altered layers are generated even on undamaged minerals such as albite and orthoclase, where alkali cations are easily exchangeable.  相似文献   

Vertical distribution features of atmospheric water vapour in the Po valley area     

Claudio Tomasi  Tiziana Paccagnella 《Pure and Applied Geophysics》1988,127(1):93-115

Two sets of radiosounding measurements, taken at different hours from some stations in the Po Valley area, were examined in order to obtain the values of precipitable waterw and determine the shapes of the vertical distribution curves of absolute humidity. From these curves, we calculated the bestfit values of scale heightsH ₁ andH ₂ in the 0÷5 km and 5÷10 km altitude intervals, respectively. The analysis of the radiosounding data clearly shows that parametersw andH ₁ are closely related to the evolutionary features of the meteorological conditions on synoptic scale and are influenced, to a lesser extent, by the diurnal variations in the atmospheric ground layer. Seasonal average curves of temperature and absolute humidity, as functions of altitude, were also defined from the radiosounding measurements taken at various hours of the day. Moreover, interpolation methods in time (applied to a 12-hour range) and in space (range of about 300 km) were proposed for determining parametersw andH ₁ from the radiosounding measurements taken at different hours from the same station or from different stations at the same hour. Reliability tests, made by comparing the same station or from different stations at the same hour. Reliability tests, made by comparing the values given by the interpolation methods with those directly obtained from the radiosounding measurements, show that these evaluations ofw andH ₁ are affected by standard errors of estimate, which are comparable to the errors usually made in analyzing the radiosounding data.  相似文献   

Impacts of maintenance channel dredging in a northern Adriatic coastal lagoon. I: Effects on sediment properties,contamination and toxicity     

Roberta Guerra  Andrea PasterisMassimo Ponti 《Estuarine, Coastal and Shelf Science》2009

Conservation and management of coastal lagoons envisage direct human intervention. To prevent siltation and to preserve the hydrodynamics features of the lagoon system, the inner channels undergo regular maintenance dredging.  相似文献