Distribution of Ferric Iron in some Upper-Mantle Assemblages   总被引：16，自引：5，他引：11  

CANIL  DANTE; O'NEILL  HUGH ST. C. 《Journal of Petrology》1996,37(3):609-635

The distribution of ferric iron among the phases of upper-mantlerocks, as a function of pressure (P), temperature (T) and bulkcomposition, has been studied using ⁵⁷Fe Mssbauer spectroscopyto determine the Fe³⁺/Fe ratios of mineral separates from 35peridotite and pyroxenite samples. The whole-rock Fe³⁺ complementof a peridotite is typically shared approximately evenly amongthe major anhydrous phases (spinel and/or garnet, orthopyroxeneand clinopyroxene), with the important exception of olivine,which contains negligible Fe³⁺. Whole-rock Fe³⁺ contents areindependent of the T and P of equilibration of the rock, butshow a well-defined simple inverse correlation with the degreeof depletion in a basaltic component. Fe³⁺ in spinel and inboth pyroxenes from the spinel Iherzolite facies shows a positivecorrelation with temperature, presumably owing to the decreasein the modal abundance of spinel. In garnet peridotites, theFe³⁺ in garnet increases markedly with increasing T and P, whereasthat in clinopyroxene remains approximately constant. The complexnature of the partitioning of Fe³⁺ between mantle phases resultsin complicated patterns of the activities of the Fe³⁺ -bearingcomponents, and thus in calculated equilibrium f_O2, which showlittle correlation with whole-rock Fe³⁺ or degree of depletion.Whether Fe³⁺ is taken into account or ignored in calculatingmineral formulae for geothermobarometry can have major effectson the resulting calculated T and P. For Fe-Mg exchange geothermometers,large errors must occur when applied to samples more oxidizedor reduced than the experimental calibrations, whose f_O2 conditionsare largely unknown. Two-pyroxene thermometry is more immuneto this problem, and probably provides the most reliable P—Testimates. Accordingly, the convergence of P—T valuesderived for a given garnet peridotite assemblage may not necessarilybe indicative of mineral equilibrium. The prospects for thecalculation of accurate Fe³⁺ contents from electron microprobeanalyses by assuming stoichiometry are good for spinel, uncertainfor garnet, and distinctly poor for pyroxenes. KEY WORDS: mantle; oxidation; partitioning; peridotite; thermobarometry ^*Corresponding author. Present address: School of Earth and Ocean Sciences, University of Victoria, P.O. Box 1700, Victoria, B.C., V8W 2Y2, Canada  相似文献   

The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar   总被引：2，自引：0，他引：2  

O'NEILL  HUGH ST. C.; MAVROGENES  JOHN A. 《Journal of Petrology》2002,43(6):1049-1087

The solubility of sulfur as S^2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al₂O₃–SiO₂(CMAS)± TiO₂ ± FeO, at 1400°C and 1 bar, using CO–CO₂–SO₂gas mixtures to vary oxygen fugacity (fO₂) and sulfur fugacity(fS₂). For all compositions, the S solubility is confirmed tobe proportional to (fS₂/fO₂)^1/2, allowing the definition ofthe sulfide capacity (C_S) of a silicate melt as C_S = [S](fO₂/fS₂)^1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine C_Sas a function of melt composition at 1400°C. The resultswere fitted to the equation  相似文献   

North‐eastern Laurentide,western Greenland and southern Innuitian ice stream dynamics during the last glacial cycle          下载免费PDF全文

QUENTIN SIMON  CLAUDE HILLAIRE‐MARCEL  GUILLAUME ST‐ONGE  JOHN T. ANDREWS 《第四纪科学杂志》2014,29(1):14-26

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Volcanological study of the middle Miocene Okiduse Volcanic Group,Woodlark Island (Muyuw), eastern Papua     

I. D. Lindley 《Australian Journal of Earth Sciences》2016,63(6):731-754

Woodlark Island (Muyuw) is located in a tectonically complex region, one of the few places on Earth where continental breakup is occurring ahead of seafloor spreading. Rifting commenced in the late Miocene (8.8–6 Ma) and is associated with the westward-propagating Woodlark Basin Spreading Centre. The island comprises approximately 850 km² of raised Pleistocene coral reef and associated sediments with a central, moderately elevated range underlain by the middle Miocene calc-alkaline to shoshonitic Okiduse Volcanic Group (new name). It provides an exposure of upper Cenozoic geology in close proximity to the spreading centre. The Okiduse Volcanic Group is host to most of the island's historical gold and silver production and recently defined mineral resources totalling 1.75 Moz gold. This study uses facies analysis of pyroclastic deposits to develop a detailed geological map of the Okiduse Volcanic Group, with a revision and reinterpretation of the unit. Facies associations suggest that two major volcanic centres erupted synchronously during the middle Miocene (14–12 Ma), referred to as the Watou Mountain Eruptive Centre (new name) and the Uvarakoi Caldera (new name). The mafic–intermediate Watou Mountain Eruptive Centre formed during frequent small eruptions of widely varying style. Strombolian, subplinian, vulcanian and dome-related explosive eruptions occurred, alternating with extrusion of block and ash flow deposits and lava domes. Pyroclastic deposits were rapidly reworked from the steep cone, and were redeposited in a series of coalescing aprons surrounding the volcano. The felsic Uvarakoi Caldera formed during a series of violent explosive eruptions by rapid removal of magma from the underlying chamber, followed by collapse. Plinian and possibly phreatoplinian eruptions, as a result of magma–water mixing in the surface environment, resulted in widely dispersed, highly fragmented tuff deposits. The caldera was modified by widespread erosion following eruptions, resulting in fluvial, laharic and slope-wash deposits. This study highlights lithological controls (porosity and permeability) by various units within the Okiduse Volcanic Group on ore deposition.  相似文献   

A multi-dimensional assessment of urban vulnerability to climate change in Sub-Saharan Africa     

Lise Byskov Herslund  Fatemeh Jalayer  Nathalie Jean-Baptiste  Gertrud Jørgensen  Sigrun Kabisch  Wilbard Kombe  Sarah Lindley  Patrik Karlsson Nyed  Stephan Pauleit  Andreas Printz  Trond Vedeld 《Natural Hazards》2016,82(2):149-172

In this paper, we develop and apply a multi-dimensional vulnerability assessment framework for understanding the impacts of climate change-induced hazards in Sub-Saharan African cities. The research was carried out within the European/African FP7 project CLimate change and Urban Vulnerability in Africa, which investigated climate change-induced risks, assessed vulnerability and proposed policy initiatives in five African cities. Dar es Salaam (Tanzania) was used as a main case with a particular focus on urban flooding. The multi-dimensional assessment covered the physical, institutional, attitudinal and asset factors influencing urban vulnerability. Multiple methods were applied to cover the full range of vulnerabilities and to identify potential response strategies, including: model-based forecasts, spatial analyses, document studies, interviews and stakeholder workshops. We demonstrate the potential of the approach to assessing several dimensions of vulnerability and illustrate the complexity of urban vulnerability at different scales: households (e.g., lacking assets); communities (e.g., situated in low-lying areas, lacking urban services and green areas); and entire cities (e.g., facing encroachment on green and flood-prone land). Scenario modeling suggests that vulnerability will continue to increase strongly due to the expected loss of agricultural land at the urban fringes and loss of green space within the city. However, weak institutional commitment and capacity limit the potential for strategic coordination and action. To better adapt to urban flooding and thereby reduce vulnerability and build resilience, we suggest working across dimensions and scales, integrating climate change issues in city-level plans and strategies and enabling local actions to initiate a ‘learning-by-doing’ process of adaptation.  相似文献   

Element Mobility During Incipient Granulite Formation at Kabbaldurga, Southern India   总被引：7，自引：2，他引：7  

ST?HLE  H.J.; RAITH  M.; HOERNES  S.; DELFS  A. 《Journal of Petrology》1987,28(5):803-834

At Kabbaldurga, infiltration of carbonic fluids along a systemof ductile shears and foliation planes has led to partial transformationof Archaean grey biotite–hornblende gneiss to coarse-grainedmassive charnockite at about 2.5 b.y. ago. The dehydration ofthe gneiss assemblage was induced by a marked metasomatic changeof the reacting system from granodioritic to granitic, and obviouslytook place under conditions of an open system at 700–750?C and 5–7 kb. Extensive replacement of plagioclase (An_16–30)by K-feldspar through Na, Ca–K exchange reactions withthe ascending carbonic fluids led to strong enrichment in K,Rb, Ba, and SiO₂, and to a depletion in Ca. Progressive dissolutionof hornblende, biotite, magnetite, and the accessory mineralsapatite and zircon resulted in a marked depletion in Fe, Mg,Ti, Zn, V, P, and Zr. Most important is the recognition of REEmobility: with advancing charnockitization, the moderately fractionatedREE distribution patterns of the grey gneisses (La_N270; La_N/Yb_N= 5–20; Eu_N27; Eu/Eu^* = 0.6–0.3) give way to stronglyfractionated REE patterns with a positive Eu-anomaly (La_N200;La_N/Yb_N = 20–80; Eu_N22; Eu/Eu^* = 0.6–1.8). The systematicdepletion especially in the HREE is due to the progressive dissolutionof zircon, apatite (and monazite), which strongly concentratethe REE. Stable isotope data (¹⁸O of 6.9–8.0 per mille for gneissesand charnockites; ¹³C of –8.5 and –6.5 per millefor late carbonate) indicate a magmatogenic source for the carbonicfluids. In contrast to the currently favoured derivation ofcarbonic fluids by decarbonation of the upper mantle or degassingof underplated basaltic intrusions, it is discussed here thatabundant fluid inclusions in lower crustal charnockites providedan extensive reservoir of ‘fossil’ carbonic fluids.Shear deformation has tapped this reservoir and generated thechannel-ways for fluid ascent. Charnockitization of the Kabbaldurgatypethus appears to be a metasomatic process which is tectonicallycontrolled and restricted to the crustal level of the amphiboliteto granulite transition.  相似文献   

Effect of Silica Activity on OH- IR Spectra of Olivine: Implications for Low-aSiO2 Mantle Metasomatism     

MATVEEV  S.; O'NEILL  H. ST. C.; BALLHAUS  C.; TAYLOR  W. R.; GREEN  D. H. 《Journal of Petrology》2001,42(4):721-729

Hydrogen solubility and hydroxyl substitution mechanism in olivineat upper-mantle conditions are not only a function of pressure,temperature, water fugacity and hydrogen fugacity, but are alsoinfluenced by silica activity. Olivine synthesized in equilibriumwith magnesiowüstite displays hydroxyl stretching bandsin the wavenumber range from 3640 to 3430 cm^–1. In contrast,olivine in equilibrium with orthopyroxene shows absorption bandsin a narrower wavenumber range from 3380 to 3285 cm^–1.The two fundamentally different spectra are assigned to hydroxylin tetrahedral and octahedral sublattices, respectively. Olivinein equilibrium with orthopyroxene is also less capable of incorporatinghydroxyl, relative to olivines in equilibrium with magnesiowüstite,by about a factor of ten. A comparison of spectra obtained aspart of this study with hydroxyl spectra of natural mantle olivinesshows that the latter display hydroxyl stretching patterns reminiscentof equilibrium with magnesiowüstite, although undoubtedlyolivine in the Earth’s mantle coexists with orthopyroxene.This may be attributed to a metasomatic overprint by a low-silicafluid and/or melt that was in reaction relationship with orthopyroxene.A likely metasomatic agent is a carbonatitic melt. When carbonatiticmelts decompose to oxides and CO₂, they may temporarily imposea low-aSiO₂ environment inherited by the olivine structure.If this suggestion proves true, Fourier transform IR spectroscopymay be used to fingerprint metasomatic episodes in the lithosphericmantle. KEY WORDS: FTIR spectrometry; olivine; mantle; metasomatism; water  相似文献   

The late Miocene to Pleistocene ice-rafting history of southeast Greenland     

KRISTEN E. K. ST. JOHN  LAWRENCE A. KRISSEK 《Boreas: An International Journal of Quaternary Research》2002,31(1):28-35

Analysis of a Miocene-Pleistocene ice-rafted debris (IRD) record from the western Irminger Basin provides evidence for the initiation and long-term behavior of the SE portion of the Greenland Ice Sheet. In the late Miocene (~7.3 Ma), IRD supply to Ocean Drilling Program site 918 increased significantly indicating that glaciers large enough to reach sea level were present in SE Greenland long before the onset of widespread Northern Hemisphere glaciation. IRD accumulated at this site throughout the Pliocene and Pleistocene, supporting the hypothesis that SE Greenland was a key nucleation area for the formation of the Greenland Ice Sheet. Since glacial onset, the western Irminger Basin IRD record is characterized by a succession of episodes with high IRD mass accumulation rates (MARs). The site 918 IRD record indicates that greatest iceberg production in SE Greenland occurred during major climatic transitions (e.g. widespread Northern Hemisphere glacial expansion at 2.7 Ma and the mid-Pleistocene climate shift at 0.9 Ma), and that SE Greenland sometimes also led the northern North Atlantic region in glacial response to climatic forcing (e.g. glacial intensification at ~4.8 and, along with NE Greenland, at ~3.5 Ma).  相似文献   

Editorial comment: Simplicity     

Dennis Lindley 《Mathematical Geology》1997,29(2):183-184

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The interplanetary electric field, cleft currents and plasma convection in the polar caps     

P. M. Banks  T. Araki  C. R. Clauer  J. P. ST. Maurice  J. C. Foster 《Planetary and Space Science》1984,32(12):1551-1557

This report investigates the suggestion that the pattern of plasma convection in the polar cleft region is directly determined by the interplanetary electric field (IEF). Owing to the geometrical properties of the magnetosphere, the East-West component of the IEF will drive field-aligned currents which connect to the ionosphere at points lying on either side of noon, while currents associated with the North-South component of the IEF will connect the two polar caps as sheet currents centered at noon. The effects of the hypothesized IEF driven cleft current systems on polar cap ionospheric plasma convection are investigated through a series of numerical simulations. The simulations demonstrate that this simple electrodynamic model can account for the narrow “throats” of strong dayside antisunward convection observed during periods of southward interplanetary magnetic field (IMF) as well as the sunward convection observed during periods of strongly northward IMF. Thedawn-dusk shift of polar cap convection which is related to the B_y component of the IMF is also accounted for by the model.  相似文献