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We have obtained high quality Raman spectra for two H/D isotopically substituted hydrous aluminosilicate glasses with compositions along the NaAlSi3O8-SiO2 join. Consistent with the results of previous studies, the isotope shift for the band near 900 cm–1, whose intensity grows with increasing water content, is extremely small: v h /v d = 1.004 ± 0.004. The lack of a definite H/D isotope shift for this band does not, however, preclude its association with a vibration of a hydrous species in the glass, because of likely strong coupling between different vibrational modes of hydrated framework species. The 900 cm–1 band could well be due to a T — OH (T = Si, Al) stretching or bending vibration in the hydrous glass, as required by the presence of a combination band near 4500 cm–1 in near-infrared spectra.  相似文献   
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Samples from the upper two-thirds of the approximately 1900 m thick Neogene section exposed south of Centerville Beach on the northern California coast have predominantly reversed detrital remanent magnetism. Fossil evidence suggests a lower Pliocene through lower Pleistocene age for the section. The combined paleomagnetic and fossil data indicate that a large part of the section was deposited during the Matayama reversed epoch (2.4-0.7 million years ago). Samples from correlative sections exposed a few kilometers inland from the Centerville Beach section have a predominantly normal polarity and appear to have been remagnetized. The Centerville Beach section is important because it may serve as a standard with which to compare both other on-land Pliocene sections from western North America and nearby Deep Sea Drilling Project cores.  相似文献   
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Hydrological observations, mainly sea surface temperature measurements, are presented for the triangular region bounded by New Zealand, New Caledonia, and Western Samoa. The existence of the Tropical Convergence and the general seasonal variation of the surface parameters are discussed. A secondary convergence lying between the Subtropical Convergence and the Tropical Convergence is proposed and its relationship to the general surface circulation of the Tasman, Sea is examined.  相似文献   
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For inversion problems in which the theoretical relationship between observed data and model parameters is well characterized, a promising approach to the classification problem is the application of techniques that capitalize on the predictive power of class-specific models. Theoretical models have been developed for three zooplankton scattering classes (hard elastic-shelled, e.g., pteropods; fluid-like, e.g., euphausiids; and gas-bearing, e.g., siphonophores), providing a sound basis for model-based classification approaches. The covariance mean variance classification (CMVC) techniques classify broad-band echoes from individual zooplankton based on comparisons of observed echo spectra to model space realizations. Three different CMVC algorithms were developed: the integrated score classifier, the pairwise score classifier, and the Bayesian probability classifier; these classifiers assign observations to a class based on similarities in covariance, mean, and variance while accounting for model spare ambiguity and validity. The CMVC techniques were applied to broad-band (~350-750 kHz) echoes acquired from 24 different zooplankton to invert for scatterer class and properties. All three classification algorithms had a high rate of success with high-quality high SNR data. Accurate acoustic classification of zooplankton species has the potential to significantly improve estimates of zooplankton biomass made from ocean acoustic backscatter measurements  相似文献   
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Abstract

Semidiurnal variations in the depth of the thermocline observed near the shelf edge north‐west of Cape Egmont are probably caused bv an internal tide generated at around 200 m depth over the continental slope. The observations suggest that in this region an internal tide, with amplitude of about 20 m, propagates onto the shelf with a speed of approximately 0.5 m·s?1 and a wavelength of about 22 km.  相似文献   
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