Exposure of the scallop Placopecten magellanicus (Gmelin) to sublethal copper and cadmium: Effects on the reproductive effort     

E. Gould  R.J. Thompson  L.J. Buckley 《Marine environmental research》1985,17(2-4)

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Distribution and Trophic Importance of Anthropogenic Nitrogen in Narragansett Bay: An Assessment Using Stable Isotopes     

Autumn Oczkowski  Scott Nixon  Kelly Henry  Peter DiMilla  Michael Pilson  Stephen Granger  Betty Buckley  Carol Thornber  Richard McKinney  Joaquin Chaves 《Estuaries and Coasts》2008,31(1):53-69

Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ¹⁵N) and carbon (δ¹³C). The δ¹⁵N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ¹⁵N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ¹⁵N values in macroalgae there reflected preferential uptake of ¹⁴N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ¹³C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ¹⁵N (13.2 ± 0.54‰ SD) and δ¹³C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ¹⁵N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.  相似文献   

TheROSAT survey of extreme UV sources: a new window on the universe     

David A. H. Buckley 《Astrophysics and Space Science》1995,228(1-2):349-365

This paper discusses the first all-sky suvey of cosmic extreme ultra-violet sources, discovered by theROSAT Wide Field Camera. Details of the instrument and the survey are presented, with comparisons made to previous selected surveys in the X-ray regime. The subsequent optical identification program is described, and the major results summarized. I then discuss the main classes of EUV emitters: active chromosphere stars and hot white dwarfs, and describe the importance of EUV obserevations in understanding the astrophysics of these objects. Many bright, and relatively nearby, sources have been identified with hitherto unrecognized active stars, representing the extremes in chromospheric and coronal activity, be it binary or age related. Many new hot DA white dwarfs have also been indentified, and the most exciting result in this area is the discovery that significant traces of heavier elements (e.g. C, N, O, Si, Fe & Al) exist in their atmospheres, substantially increasing their EUV opacities. The importance of hot white dwarfs as standard candles in probing the local interstellar medium is also discussed. Miscellaneous counterparts (AGN, PNN, O-B stars and CVs) that make up the rest of the sample of EUV sources are also briefly mentioned. I conclude the paper with a discussion of the new magnetic cataclysmic variables discovered at SAAO, which have been the subject of intensive follow-up observations.  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Integration, validation and point spacing optimisation of digital elevation models   总被引：1，自引：0，他引：1  

Simon J. Buckley  Harvey L. Mitchell 《The Photogrammetric Record》2004,19(108):277-295

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A geomatics data integration technique for coastal change monitoring     

J. P. Mills  S. J. Buckley  H. L. Mitchell  P. J. Clarke  S. J. Edwards 《地球表面变化过程与地形》2005,30(6):651-664

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Ion exchange reactions of KNiAsO4     

A. M. Buckley  S. T. Bramwell  P. Day 《Physics and Chemistry of Minerals》1988,15(5):446-451

The mica-like layer compound KNiAsO₄ easily exchanges its interlayer potassium ions for alkyl ammonium ions, RNH ₃ ⁺ (R=CH₃ - C₁₈H₃₇). Short chain ions (<>₄) will react in aqueous solution and longer chains in ethanolic solution. The reaction of KNiAsO₄ with aqueous solutions of methyl, ethyl and butyl ammonium chlorides of different concentrations has been investigated using a potassium ionselective electrode. Room temperature kinetic curves of percent exchange vs time were obtained. These indicate an apparent cooperative mechanism with some rearrangement of the alkyl ammonium ions between the layers during the reaction. KNiAsO₄ also reacts with water. This reaction may facilitate the exchange reaction with aqueous alkyl ammonium ions. The alkyl ammonium ions form ordered arrangements between the [NiAsO₄]^– layers. Small chains (<>₄) adopt a variety of configurations within the same product.Paper from the NATO Advanced Study Institute on Physical Properties and Thermodynamic Behaviour of Minerals, Cambridge 1987  相似文献   

Climatology of meteorological “bombs” in the New Zealand region     

L. M. Leslie  M. Leplastrier  B. W. Buckley  L. Qi 《Meteorology and Atmospheric Physics》2005,89(1-4):207-214

Summary The purpose of this paper is to present a recently developed climatology of explosively developing south eastern Tasman Sea extra-tropical cyclones, or meteorological “bombs”, using a latitude dependent definition for meteorological bombs based on that of Simmonds and Keay (2000a, b), and Lim and Simmonds (2002). These highly transient systems, which have a damaging impact upon New Zealand, are frequently accompanied by destructive winds, flood rains, and coastal storm surges. Two cases are selected from the climatology and briefly described here. The first case study is the major flood and storm force wind event of June 20 to 21, 2002 that affected the Coromandel Peninsula region of the North Island of New Zealand. The second case was a “supercyclone” bomb that developed well to the southwest of New Zealand region during May 29 to 31, 2004, but which could easily have formed in the New Zealand region with catastrophic consequences. It was well-captured by the new high resolution Quikscat scatterometer instrument.This study extends the work of two of the authors (Buckley and Leslie, 2004; Buckley and Leslie, 2000; Qi and Leslie, 2000), on southern hemisphere meteorological bombs, to yet another geographical location. Here, we relied heavily on surface observations, scatterometer and other satellite-derived data, and weather radar imagery in developing the climatology.  相似文献   

Zoning in garnets—Diffusion models     

David E. Anderson  Glenn R. Buckley 《Contributions to Mineralogy and Petrology》1973,40(2):87-104

When reference frames and diffusing components are properly selected, the flux equations for diffusion of the major components in natural garnets may often be approximated by: J DC. In such cases it is shown that, for reasonable diffusion coefficients and boundary conditions, observed zoning profiles in natural garnets may be explained with pure diffusion models. These models allow for original inhomogeneities in the host rock and may be used to explain why single hand specimens may show such a variety of zoning profiles within a single mineral species.  相似文献   

Variability of tropical cyclones over the southwest Pacific Ocean using a high-resolution climate model     

L. M. Leslie  D. J. Karoly  M. Leplastrier  B. W. Buckley 《Meteorology and Atmospheric Physics》2007,97(1-4):171-180

Summary Knowledge of the variability in tropical cyclone (TC) frequency and distribution is essential in determining the possible impact of natural or human-induced climate change. This variability can be investigated using the available TC data bases and by carrying out long-term climate model simulations for both past and future climates. A coupled ocean-atmosphere climate model (referred to here as the OU-CGCM) is described and applied with a higher resolution (50 km) nested domain in the southwest Pacific region. Six-member ensembles of simulations with the OU-CGCM have been run for 80 years, from 1970 to 2050. During the period 1970–2000, the OU-CGCM runs were compared with the observed TC data base. For the period 2000–2050, two ensembles of simulations were performed, one with constant greenhouse gas concentrations and the second with increasing greenhouse gases. The OU-CGCM simulated well the observed TC frequency and distribution in the southwest Pacific during the period 1970–2000. It also produced clear interannual and interdecadal TC variability in both the fixed and enhanced greenhouse gas simulations during the period 2000–2050. The variability in TC frequencies was associated with the typical atmospheric and SST anomaly patterns that occur in periods of quiet and active TC frequencies. The main findings from the enhanced greenhouse gas scenario for the period 2000–2050 are: no change in the mean decadal number of TCs relative to the control run, but a marked increase of about 15% in the mean decadal number of TCs in the most severe WMO categories 4 and 5; the likelihood of TCs during the next 50-year period that are more intense than ever previously experienced in the Australian region; a poleward extension of TC tracks; and a poleward shift of over 2 degrees of latitude in the TC genesis region.  相似文献