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1.
Measurements of subsurface irradiance spectra in the ocean consistently indicate intensities of long-wavelength visible light (589 nm) greater than could be derived from the penetration of sunlight. This can be attributed to natural fluorescence and/or to spectral crosstalk due to light leakage through the blocking filters of each discrete detector. A comparison of observed profiles with modelled contributions from these two possible sources indicates that both factors are contributing. At 671 and 694 nm wavelength, the excess signal appears to be predominantly fluorescence while that at 589 nm is mostly crosstalk. Both effects appear to be important at 625 nm although the amount of excess light is small compared to the other wavelengths.The above observations and interpretations are consistent with the optical design of the instrument used and the shape of natural irradiance spectra. Fluorescence efficiencies derived from the irradiance measurements correlate well with measuredin situ fluorescence. 相似文献
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We present the results of a study of the concentration and D/H ratio of molecular hydrogen from air in the Los Angeles Basin and adjacent San Gabriel Mountains. These data define a mixing relationship in dimensions of D/H ratio vs. 1/(H2) which constrains the δDVSMOW of unpolluted winter air in this region to be ca. +100 to +125 ‰ and that of urban H2 sources to be ca. −270 ‰. This study makes use of a new method for measuring the deuterium content of molecular hydrogen in small samples (∼100 to 500 cc) of air, which we describe in detail. The method consists of an off-line separation of H2 followed by introduction to the mass spectrometer in a continuous flow of He. Off-line, all components of an atmospheric gas sample, with the exception of He, H2, and Ne are condensed by exposure to a cold-trap held at 30 Kelvin. This separation is followed by cryo-transfer of non-condensable gases to a small volume molecular sieve finger, with assist from a mercury piston pump. At the mass spectrometer, the sample is put in line with a continuous flow of He where it is focused on to an additional column of molecular sieve before subsequent introduction into the ion source. Analyses of DH/H2 ratio have accuracy and precision of ±4 to 7 per mil. Comparison of sample peak area to peak areas of standards of known size allows for determination of H2 concentration with accuracy and precision of ∼±5%, relative. The method reduces sample size and processing time by several orders of magnitude compared to previous methods, allowing for sampling at proportionately higher spatial and temporal resolution. 相似文献
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Probability density distributions of vertical velocity fluctuations from the daytime convective boundary layer and from convection within a nighttime stratocumulus-capped boundary layer are described and contrasted. Some implications for the diffusion of released, neutrally buoyant, material are identified and discussed. 相似文献
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Aircraft observations of solar radiative fluxes (including the downward diffuse component) made in cloud-free conditions in the lowest 8 km of the atmosphere, have been interpreted using simultaneous measurements of aerosol characteristics. Measured flux profiles have been compared with those derived from a two-stream model of radiative transfer which can incorporate both gaseous and aerosol effects. In one of the four cases examined, sufficient aerosol data were available to estimate the radiative properties of the aerosol which could then be included in the model calculations. The findings are shown to be broadly consistent with the observations when a realistic aerosol refractive index is used. The measurement of the downward diffuse radiation enabled the radiative properties of the aerosol to be calculated directly from the flux measurements. In particular, the average single-scattering albedo of aerosol within the boundary layer in continental air masses was estimated to be about 0.7.The implications of having a highly absorbing aerosol present within the boundary layer are also considered. In one case a heating rate of about 5 K day-1 was observed across the aerosol layer, which suggests that on occasions, aerosol heating will be a significant term in the heat budget for the boundary layer. 相似文献
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A simple index explains annual atrazine transport from surface runoff‐prone watersheds in the north‐central USA 
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下载免费PDF全文 Year‐to‐year dynamics in weather affect both the timing of application and the potential hydrologic transport of pesticides. Further, the most commonly used pesticides dissipate in the environment during the growing season. Interactions among these factors – hydrology, timing of application and dissipation kinetics – hinder the detection of temporal trends in transport. It is increasingly important to be able to discern such trends, to judge effectiveness of management practices or to determine whether observed changes were caused by management or weather. In previous work, a cumulative vulnerability index was developed to account for these three factors. It explained 63% of annual variation in atrazine load in the Goodwater Creek Experimental Watershed (GCEW). The objectives of the current work were (i) to generalize the cumulative vulnerability index to explicitly account for variation in watershed size, area treated with atrazine and average application rate; (ii) to test the overall performance on watersheds showing such variation; and (3) to test whether the generalized index properly accounted for the additional input parameters. The generalized index was tested using data from GCEW (73.7 km2) and seven additional watersheds in the northeast Missouri claypan region that varied in size from 212 to 1180 km2 and from 4% to 23% of watershed area planted to corn or sorghum. Across 32 site‐years, the generalized index explained 84% of variation in annual atrazine load. Further, tests of residuals showed no dependence on either watershed area or fraction of area planted to corn and sorghum, indicating that these parameters were properly integrated into the index. The performance of the index supports the conclusion that data obtained from GCEW is representative of the Mark Twain Lake Basin and likely the entire Central Claypan Major Land Resource Area. Published 2012. This article is a U.S. Government work and is in the public domain in the USA. 相似文献
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The final stage in processing radar data so as to arrive at an estimated rain field typically involves a comparison of the preliminary radar-derived estimates of hourly rainfall with those observed by ground-based gauges. Often a mean field bias adjustment will then be applied using an age-weighted average of the individual gauge–radar comparisons. In this paper, a mean field bias adjustment is presented that uses the path-integrated rainfall estimates provided by microwave links together with information from gauges. It is shown to be at least as efficient as the current gauge-based procedure used by the UK Met Office to improve the accuracy of radar-based estimates of rainfall at the ground. 相似文献
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John M. Eiler Nami Kitchen Lauri Leshin Melissa Strausberg 《Meteoritics & planetary science》2002,37(3):395-405
Abstract— The martian meteorite, Allan Hills (ALH) 84001, contains D‐rich hydrogen of plausible martian origin (Leshin et al., 1996). The phase identity of the host(s) of this hydrogen are not well known and could include organic matter (McKay et al., 1996), phlogopite (Brearley, 2000), glass (Mittlefehldt, 1994) and/or other unidentified components of this rock. Previous ion microprobe studies indicate that much of the hydrogen in ALH 84001 as texturally associated with concretions of nominally anhydrous carbonates, glass and oxides (Boctor et al., 1998; Sugiura and Hoshino, 2000). We examined the physical and chemical properties of the host(s) of this hydrogen by stepped pyrolysis of variously pre‐treated subsamples. A continuous‐flow method of water reduction and mass spectrometry (Eiler and Kitchen, 2001) was used to permit detailed study of the small amounts of this hydrogen‐poor sample available for study. We find that the host(s) of D‐rich hydrogen released from ALH 84001 at relatively low temperatures (?500 °C) is soluble in orthophosphoric and dilute hydrochloric acids and undergoes near‐complete isotopic exchange with water within hours at temperatures of 200 to 300 °C. These characteristics are most consistent with the carrier phase(s) being a hydrous salt (e.g., carbonate, sulfate or halide); the thermal stability of this material is inconsistent with many examples of such minerals (e.g., gypsum) and instead suggests one or more relatively refractory hydrous carbonates (e.g., hydromagnesite). Hydrous salts (particularly hydrous carbonates) are common on the Earth only in evaporite, sabkha, and hydrocryogenic‐weathering environments; we suggest that much (if not all) of the “martian” hydrogen in ALH 84001 was introduced in analogous environments on or near the martian surface rather than through biological activity or hydrothermal alteration of silicates in the crust. 相似文献
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Mahsa Haghi Ahmad Savari Preeta Kochanian Mohammad Bagher Nabavi Mohammad Hasan Nami Mohammad Zakeri Mohammad Bodaghi 《Marine Ecology》2012,33(4):460-469
Mapping surveys of coastal benthic habitat in Qeshm Island Geopark, Persian Gulf, were conducted using a combination of biological, sedimentological and echo‐sounding data. The survey area covered approximately 233 km2 in a depth range of 5–25 m, and the data were acquired from a single beam echo sounder, grab, video and still photography. Sediment and macrofauna samples were collected by grab at 76 stations and subjected to classification and ordination analyses. Two acoustic classes were identified differentiating along the near/offshore axis. Sediment texture was dominated by fine grain sizes, with five distinct sub‐sediment types. In total, 214 macrobenthic taxa were identified, of which polychaetes accounted for 60%. Other dominant groups included young sponges, nematodes, malacostracan crustacean, bivalves, ostracods and ophiuroids. Underwater videos and still photos integrated the macrofaunal and sedimentary data and revealed a range of biogenic sedimentary features such as burrows and tubes. The biological data identified six main biological assemblages showing an inshore/offshore pattern. The macrobenthic abundance did not demonstrate a significant difference with depth, although polychaetes were positively correlated with depth. The highest abundance and species richness were observed at median depths. Species distribution and diversity did not show any correlation with sediment type. A preliminary habitat mapping of the south coast of the Qeshm Island Geopark has been carried out, integrating acoustic, sediment and biological data. 相似文献
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M. H. Nami A. Jaafari M. Fallah S. Nabiuni 《International Journal of Environmental Science and Technology》2018,15(2):373-384
Accurate estimates of wildfire probability and production of distribution maps are the first important steps in wildfire management and risk assessment. In this study, geographical information system (GIS)-automated techniques were integrated with the quantitative data-driven evidential belief function (EBF) model to predict spatial pattern of wildfire probability in a part of the Hyrcanian ecoregion, northern Iran. The historical fire events were identified using earlier reports and MODIS hot spot product as well as by carrying out multiple field surveys. Using the GIS-based EBF model, the relationships among existing fire events and various predictor variables predisposing fire ignition were analyzed. Model results were used to produce a distribution map of wildfire probability. The derived probability map revealed that zones of moderate, high, and very high probability covered nearly 60% of the landscape. Further, the probability map clearly demonstrated that the probability of a fire was strongly dependent upon human infrastructure and associated activities. By comparing the probability map and the historical fire events, a satisfactory spatial agreement between the five probability levels and fire density was observed. The probability map was further validated by receiver operating characteristic using both success rate and prediction rate curves. The validation results confirmed the effectiveness of the GIS-based EBF model that achieved AUC values of 84.14 and 81.03% for success and prediction rates, respectively. 相似文献