Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California     

Christopher Oze  Catherine Skinner  Andrew W. Schroth  Robert G. Coleman 《Applied Geochemistry》2008,23(12):3391-3403

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.  相似文献   

A 500 hPa synoptic wildland fire climatology for large Canadian forest fires, 1959–1996     

W. R. Skinner  M. D. Flannigan  B. J. Stocks  D. L. Martell  B. M. Wotton  J. B. Todd  J. A. Mason  K. A. Logan  E. M. Bosch 《Theoretical and Applied Climatology》2002,71(3-4):157-169

Summary In Canada, the average annual area of burned forest has increased from around 1 million ha in the 1970’s to over 2.5 million ha in the 1990’s. A previous study has identified the link between anomalous mid-tropospheric circulation at 500 hPa over northern North America and wildland fire severity activity in various large regions of Canada over the entire May to August fire season. In this study, a northern North American study region of the hemispheric gridded 5° latitude by 10° longitude 500 hPa dataset is identified and analysed from 1959 to 1996 for a sequence of six monthly periods through the fire season, beginning in April and ending in September. Synoptic types, or modes of upper air behavior, are determined objectively by the eigenvector method employing K-means cluster analysis. Monthly burned areas from the Canadian Large Fire Database (LFDB) for the same period, 1959 to 1996, are analysed in conjunction with the classified monthly 500 hPa synoptic types. Relationships between common monthly patterns of anomalous upper flow and spatial patterns of large fire occurrence are examined at the ecozone level. Average occurrence of a monthly synoptic type associated with very large area burned is approximately 18% of the years from 1959 to 1996. The largest areas burned during the main fire (May to August) season occur in the western Boreal and Taiga ecozones – the Taiga Plains, Taiga Shield, Boreal West Shield and Boreal Plains. Monthly burned areas are also analysed temporally in conjunction with a calculated monthly zonal index (Zi_m) for two separate areas defined to cover western and eastern Canada. In both western and eastern Canada, high area burned is associated with synoptic types with mid-tropospheric ridging in the proximity of the affected region and low Zi_m with weak westerlies and strong meridional flow over western Canada. Received April 3, 2001 Revised July 13, 2001  相似文献   

XPS identification of bulk hole defects and itinerant Fe 3d electrons in natural troilite (FeS)     

William M Skinner  H.Wayne Nesbitt 《Geochimica et cosmochimica acta》2004,68(10):2259-2263

XPS measurements have been made of vacuum-fractured monoclinic pyrrhotite and troilite that highlight sulfur coordination (S 2p) and iron electronic state (Fe 2p) differences between these two minerals as a result of iron lattice site occupancy. Metal-like Fe states are observed in the Fe 2p spectrum of troilite due to increased occupancy of Fe lattice sites and increased Fe-Fe 3d orbital interaction within the constraints of the mineral structure. Additional electron population near the top of the troilite valence band is confirmed by XPS measurement. These results provide comprehensive experimental evidence for itinerent 3d electrons in the natural iron sulfides.  相似文献   

Evidence from the Northeastern Atlantic basin for variability in the rate of the meridional overturning circulation through the last deglaciation   总被引：1，自引：0，他引：1  

J.-M. Gherardi  L. Labeyrie  J.F. McManus  R. Francois  L.C. Skinner  E. Cortijo 《Earth and Planetary Science Letters》2005,240(3-4):710-723

A first study from the subtropical western Atlantic, using ²³¹Pa/²³⁰Th ratios as a kinematic proxy for deep water circulation, provided compelling evidence for a strong link between climate and the rate of Meridional Overturning Circulation (MOC) over the last deglaciation. However, these results warrant confirmation from additional locations and water depths because the interpretation of the sedimentary ²³¹Pa/²³⁰Th ratio in terms of circulation vigor can be biased by variations in particle flux and composition. We have measured ²³¹Pa/²³⁰Th in a core from the Iberian margin, in the Northeastern Atlantic basin, and have compared these new results to the data from the western Atlantic basin. We find that the reduction in the circulation during H1 and YD and the subsequent increases first recognized in the sediment deposited on Bermuda Rise are also evident in the eastern basin, in a totally different sedimentary regime, confirming that sedimentary ²³¹Pa/²³⁰Th ratios record basin-wide changes in deep water circulation. However, some differences between the eastern and western records are also recognized, providing preliminary evidence to differentiate between renewal rates in the two North Atlantic basins and between shallower and deeper overturning. Our results suggest the possible existence of two sources of Glacial North Atlantic Intermediate Deep Water (GNAIW), one in the south Labrador Sea and another west of Rockall Plateau. Both sources contributed to the meridional overturning but the two had different sensitivity to meltwater from the Laurentide and the Fennoscandian ice sheets during the deglaciation. These results indicate that additional information on the geometry and strength of the ventilation of the deep Atlantic can be obtained by contrasting the evolution of sediment ²³¹Pa/²³⁰Th in different sections of the Atlantic Ocean.  相似文献   

Hyper-resolution mapping of regional storm surge and tide flooding: comparison of static and dynamic models   总被引：1，自引：0，他引：1  

Jorge A. Ramirez  Michal Lichter  Tom J. Coulthard  Chris Skinner 《Natural Hazards》2016,82(1):571-590

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Dating of marine aragonite by electron spin resonance     

Anne F. Skinner 《Quaternary Science Reviews》1988,7(3-4)

Marine aragonite, in the form of corals and/or shells, provides useful markers of geological and archaeological events. It is, therefore, important to have simple and accurate methods of dating these materials. Electron spin resonance (ESR) has previously been shown to be a reliable method for establishing the age of aragonitic coral samples in the time period approximately 100 ka B.P. The primary purpose of the present work is to discuss the problems encountered in extending this method to considerably older samples, up to 600 ka BP in age. In this time period there are questions about the stability of the ESR signal. The samples investigated are aragonitic corals from reef terraces of Barbados, West Indies, all of which have previously been dated by the methods, and by U-series disequilibrium, for samples below the limit of this method. There is generally good agreement for samples up to about 300 ka in age; older samples, even unrecrystallized, appear younger when dated by ESR than by . The source of this discrepancy is not clear. The explanation of thermal fading is not adequate. However, it appears likely that in most cases ESR will be able to be used to date materials up to this age. Further investigation is needed to determine tests that will distinguish datable samples from non-datable ones.  相似文献   

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite     

Y.-H. Sung  C. L. Ciobanu  A. Pring  J. Brügger  W. Skinner  N. J. Cook  M. Nugus 《Mineralogy and Petrology》2007,90(3-4):249-270

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.  相似文献   

The evolving role of voluntarism in ageing rural communities   总被引：1，自引：0，他引：1  

Mark W. Skinner  Alun E. Joseph 《New Zealand geographer》2007,63(2):119-129

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Accelerograph calibration and accelerogram correction     

R. I. Skinner  W. R. Stephenson 《地震工程与结构动力学》1973,2(1):71-86

When measured earthquake accelerations are used as a basis for structural design, then acceleration errors of a few per cent are usually acceptable. However a number of tasks in structural design, and in earthquake engineering research, require measured accelerations with errors limited to a few parts per thousand. Such tasks include those which call for the calculation of angular accelerations, the comparison of acceleration spectra or the calculation of relative displacement Accurate accelerations may be obtained from existing accelerographs by applying the results of an accurate static calibration to an accelerogram, and then applying corrections for the effects of accelerometer resonance. This paper concentrates attention on the correction of static errors, including sensing direction errors and cross-axis interaction errors. For completeness there is a brief discussion of dynamic errors, which depend on accelerometer periods and dampings. It is concluded that earthquake accelerations may be obtained with errors of not much more than 0·001 g, the resolution of a typical accelerograph, at least for periods greater than 0·2 sec. When the accelerations have shorter periods, larger errors may arise due to the limited accuracy of the corrections for dynamic errors The static calibration of accelerographs, and the corresponding record correction procedures, are illustrated by application to the M.O.2 accelerograph.  相似文献   

Observations of high co rotational lines in post-AGBs and PN     

K. Justtanont  A. G. G. M. Tielens  C. J. Skinner  M. R. Haas 《Astrophysics and Space Science》1995,224(1-2):305-308

We present a preliminary interpretation of high CO rotational line data obtained from KAO. The possibility of either a PDR or a shock model is considered in order to explain the observations.  相似文献