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Abstract— The Crow Creek Member is one of several marl units recognized within the Upper Cretaceous Pierre Shale Formation of eastern South Dakota and northeastern Nebraska, but it is the only unit that contains shock‐metamorphosed minerals. The shocked minerals represent impact ejecta from the 74‐Ma Manson impact structure (MIS). This study was aimed at determining the bulk chemical compositions and analysis of planar deformation features (PDFs) of shocked quartz; for the basal and marly units of the Crow Creek Member. We studied samples from the Gregory 84‐21 core, Iroquois core and Wakonda lime quarry. Contents of siderophile elements are generally high, but due to uncertainties in the determination of Ir and uncertainties in compositional sources for Cr, Co, and Ni, we could not confirm an extraterrestrial component in the Crow Creek Member. We recovered several shocked quartz grains from basal‐unit samples, mainly from the Gregory 84‐21 core, and results of PDF measurements indicate shock pressures of at least 15 GPa. All the samples are composed chiefly of SiO2 (29–58 wt%), Al2O3 (6–14 wt%), and CaO (7–30 wt%). When compared to the composition of North American Shale Composite, the samples are significantly enriched in CaO, P2O5, Mn, Sr, Y, U, Cr, and Ni. The contents of rare earth elements (REE), high field strength elements (HFSE), Cr, Co, Sc, and their ratios and chemical weathering trends, reflect both felsic and basic sources for the Crow Creek Member, an inference, which is consistent with the lithological compositions in the environs of the MIS. The high chemical indices of alteration and weathering (CIA' and CIW': 75–99), coupled with the Al2O3‐(CaO*+Na2O)‐K2O (A‐CN'‐K) ratios, indicate that the Crow Creek Member and source rocks had undergone high degrees of chemical weathering. The expected ejecta thicknesses at the sampled locations (409 to 219 km from Manson) were calculated to range from about 1.9 to 12.2 cm (for the present‐day crater radius of Manson), or 0.4 to 2.4 cm (for the estimated transient cavity radius). The trend agrees with the observed thicknesses of the basal unit of the Crow Creek Member, but the actually observed thicknesses are larger than the calculated ones, indicating that not all of the basal unit comprises impact ejecta.  相似文献   
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To constrain the tectonic and metamorphic history of the GrenvilleProvince of southern Ontario we have quantitatively evaluatedchanges in peak metamorphic pressures and temperatures in theregion. Pressures increase northwest from the Frontenac Axistowards the Grenville Front, and they increase from 4–6kb near Madoc to 10–11 kb south of North Bay. Furtherto the north pressures decrease to 8–9 kb in the GrenvilleFront Tectonic Zone north of the French and Mattawa Rivers.Temperatures form a broad high, reaching 800?C northeast ofParry Sound, and decreasing to 400–500?C in the HastingsLow near Madoc, 600–650?C east towards the Ottawa River,and 650–700?C near Sudbury. This regional P-T distributionis in good agreement with constraints available from the distributionof aluminosilicate polymorphs. Comparison of thermobarometric results with regional tectonicfeatures shows a sharp discontinuity across the Mattawa andFrench Rivers, with a 1–2-kb pressure drop to the north.This implies that the major movement along this zone since theGrenville event was ‘south-side-up’ rather than‘north-side-up’ as suggested by Lumbers (1971).Large P-T discontinuities are not apparent across the domainboundaries mapped by Davidson and co-workers east of Parry Sound,but small discontinuities may exist. Sparse data may indicatethat the Central Metasedimentary Belt equilibrated at 1–2kb lower pressures than the Central Gneiss Terrane. Zoning profiles in garnet-pyroxene pairs have been used to placeconstraints on the metamorphic pressure-temperature-time pathin the Parry Sound, Port Severn, Bancroft, and Mattawa areasof the Grenville Province, Ontario. A nonlinear fitting routinewas used to obtain best-fit core and rim analyses for garnetsand pyroxenes. These results were combined with plagioclasecore/rim analyses to obtain estimates of peak and retrogradeconditions. The resultant retrograde P-Tpath has a slope of7 ? 10 b/?C, and involves pressure changes of 0?6–2?1kb for temperature changes of 60–130?C. Present address: Department of Geosciences, University of Arizona, Tucson, Arizona 85721  相似文献   
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A Holocene tephra record from the Lofoten Islands, Arctic Norway   总被引:2,自引:0,他引:2  
Pilcher, J., Bradley, R. S., Francus, P. & Anderson, L. 2005 (May): A Holocene tephra record from the Lofoten Islands, Arctic Norway. Boreas , Vol. 34, pp. 136–156. Oslo. ISSN 0300–9483.
A tephrochronology has been established for a peat bog in the Lofoten Islands that provides a dating framework for future lake and bog studies of climate variation in this climatically sensitive area. Twenty-three tephra layers were identified, all apparently of Icelandic origin. These included the historically dated tephras of AD 1875 (Askja), AD 1362 (Öraefajökull), AD 1158 (Hekla), AD 1104 (Hekla) and the Landnam tephra identified at AD 875 in the GRIP ice core. Other layers, previously radiocarbon dated in Ireland and elsewhere, include the Hekla eruptions of c. 2310 BC and c. 5990 BC. The basal clays below the peat contain tephra of both the Askja eruption of c. 9500 BC (10 000 radiocarbon years BP) and the well-known Vedde Ash of c. 12 000 BP (10 030 80 BC in GRIP ice core).  相似文献   
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Sequences of tills, buried paleosols, wood and tephra in lateral moraines provide a record of Holocene advances and retreats of the Bugaboo Glacier in British Columbia. The oldest paleosol is tentatively classified as a Spodosol (Cryorthod). It incorporates Mazama tephra (6,800 B.P.) and charcoal and humus dated at 3,390 and 4.400B.P., respectively, and records early and middle Holocene warming and/or drying. This paleosol overliesa latest Pleistocene or early Holocene till associated with a nearby end moraine and assigned to the regionally known 'Crowfoot Advance'. Less-developed paleosols (Cryumbrepts) are formed on Neoglacial tills deposited shortly before 3,000 B. P., between c. 2,500 to 1,900 B. P., and between c. 900 B.P. and the 19th century. The paleosols and surface soils form microcatenas with morphological variations due to differences in original topography and vegetation. The chronology derived from these paleosols and tills generally agrees with, but increases the resolution of, what is known of Holocene glacier histories in the Canadian Cordillera.  相似文献   
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Rare earth elements (REE) were determined in fine, medium and coarse crystalline replacement dolomites, and for saddle dolomite cements from the Middle Devonian Presqu'ile barrier from Pine Point and the subsurface of the Northwest Territories and north-eastern British Columbia. REE patterns of the fine crystalline dolomite are similar to those of Middle Devonian limestones from the Presqu'ile barrier. Fine crystalline dolomite occurs in the back-barrier facies and may represent penecontemporaneous dolomitization at, or just below, the sea floor. Medium crystalline dolomite is widespread in the lower southern and lower central barrier. Medium crystalline dolomite is slightly depleted in heavy REE compared with Devonian marine limestones and fine crystalline dolomite, and has negative Ce and Eu anomalies. Medium crystalline dolomites replaced pre-existing limestones or were recrystallized from earlier fine crystalline dolomites. During these processes, the REE patterns of their precursors were modified. Late stage, coarse crystalline replacement dolomite and saddle dolomite cements occur together in the upper barrier and have similar geochemical signatures. Coarse crystalline dolomites have negative Eu anomalies, and those from the Pine Point area also have positive La anomalies. Saddle dolomites are enriched in light REE and have positive La anomalies. The REE patterns of coarse crystalline dolomite and saddle dolomite differ from those of marine limestones and fine and medium crystalline dolomites, suggesting that different diagenetic fluids were responsible for these later dolomites. Although massive dolomitization requires relatively large volumes of fluids in order to provide the necessary amounts of Mg2-. dolomitization and subsequent recrystallization may not necessarily modify the REE signatures of the precursor limestones because of the low concentrations of REE in most natural fluids. Thus, relative fluid-rock ratios during diagenesis may be estimated from REE patterns in the diagenetic and precursor minerals. Fine crystalline dolomites retain the REE patterns of their limestone precursors. In the medium and coarse crystalline dolomites the precursor REE patterns were apparently altered by large volumes of fluids involved during dolomitization. This study suggests that REE compositions of dolomites and their limestone precursors may provide important information about the relative amounts of fluids involved during diagenetic processes, such as dolomitization.  相似文献   
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The concentration and composition of suspended particulate matter (SPM) were measured weekly for a period of one year in the flood front waters traversing a muddy tidal flat. SPM concentrations were lowest in the winter when portions of the tidal flat were covered with ice, and biological activity was minimal. In contrast, the summer months had the highest SPM concentrations which reflected increased bottom resuspension. The two main sources of SPM were suspended matter carried in from offshore on the flooding tide and resuspended in situ bottom sediments. The offshore source was characterized by low SPM concentrations, coarse textures, and a high content of protein and chlorophyll ‘a’. Samples taken during resuspension events (storms/showers) had high SPM concentrations, finer textures, and were enriched in dead detrital organic material (phaeophytin). At any one time the SPM was primarily an admixture of these two sources. The highest SPM measurements were taken during storm events, with rainfall seeming to play a dominant physical role in aiding resuspension. SPM concentrations, textures, and compositions collected during the storms closely approximated SPM measurements made over newly dug ‘clam flats’.  相似文献   
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High resolution environmental records with a refined chronology are essential to understand, reconstruct and model the climate dynamics of the last glacial-interglacial transition. Sediments from Lake Torfadalsvatn in northern Iceland contain at least four primary volcanic tephras that belong to ash zone I in the North Atlantic deep-sea cores. We chemically define these basaltic/rhyolitic tephras and the high resolution allows us to date them to about 10,800, 10,600, 9300 and 8900 BP. This detailed tephrostratigraphy will act as a refined dating and correlation tool in the North Atlantic region and enable calibration between different absolute chronologies. The pollen stratigraphy of the sediments suggests that by 10,400 14C years BP plant colonization of coastal north Iceland had begun. The pollen stratigraphy shows a succession of pioneer plants, from open tundra vegetation towards birch-juniper woodland, which probably also reflects a transition from a cool climate at 10,400 BP to conditions similar to today's sub-polar oceanic climate around 9200 BP. Diatom data largely concur with the climatic information from pollen, indicating gradually increasing productivity in the lake.  相似文献   
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