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1.
Several detergent-washing/air-drying decontamination protocols were tested to determine their ability to remove residual contamination from two types of ground water sampling devices. We tested a relatively simply constructed device, a bailer, and a much more complex, and theoretically more difficult to decontaminate, bladder pump. The devices were decontaminated after sampling ground water that was contaminated with organics that varied in their hydrophobic nature and propensity to be sorbed by the materials in the devices. These studies showed that a hot-detergent wash, hot-water rinse, and hot-air drying protocol was effective. 相似文献
2.
Previous research has shown that the most commonly used well casing materials-stainless steel. polyvinyl chloride (PVC). and polytetra-fluoroethylene (PTFE)-are not suited for all monitoring environments and applications. This study is part of a series of experiments that were conducted to determine the suitability of four other polymeric well casing materials-acrylonitrile butadiene styrene (ABS), fluorinalcd ethylene propylene (FHP), fiberglass-reinlorced epoxy (FRE), and fiberglass-reinforced plastic (FRP)- for use in ground water monitoring wells. In these studies, these four materials were compared with two other commonly used polymeric well casings, PVC and PTFE. Part I of these studies examines the resistance of these materials to degradation by chemicals. Future reports will consider sorption and leaching of organic and metal contaminants.
In this study, the six materials were exposed to 28 neat organic compounds (including one acid) and to extremely acidic and alkaline aqueous solutions for up to 112 days. This was done to simulate the most aggressive environments to which monitoring well casings may be exposed. The casings were observed for changes in weight and signs of physical degradation (swelling, softening, deterioration, or dissolution).
The two fluorinated polymers (FEP and PTFE) were not degraded by any of the lest chemicals. Among the nonfluorinated products tested. FRE was the most inert. Three organic chemicals caused the glass fibers to separate. and two organic solvents caused weight gains exceeding 10 percent. ABS was the most readily degraded material tested. By the end of the study, only the acid and alkaline solutions had little effect on ABS. FRP was more severely degraded by the organic chemicals than FRH but was less affected than PVC. FRP and FRE. lost weight when exposed to the highly acidic conditions. 相似文献
In this study, the six materials were exposed to 28 neat organic compounds (including one acid) and to extremely acidic and alkaline aqueous solutions for up to 112 days. This was done to simulate the most aggressive environments to which monitoring well casings may be exposed. The casings were observed for changes in weight and signs of physical degradation (swelling, softening, deterioration, or dissolution).
The two fluorinated polymers (FEP and PTFE) were not degraded by any of the lest chemicals. Among the nonfluorinated products tested. FRE was the most inert. Three organic chemicals caused the glass fibers to separate. and two organic solvents caused weight gains exceeding 10 percent. ABS was the most readily degraded material tested. By the end of the study, only the acid and alkaline solutions had little effect on ABS. FRP was more severely degraded by the organic chemicals than FRH but was less affected than PVC. FRP and FRE. lost weight when exposed to the highly acidic conditions. 相似文献
3.
This report examines sorption of low ppb levels of organic solutions by polytetra- fluoroethylene (PTFE), rigid polyvinyl chloride (PVC), and stainless steel 304 and 316 well casings. Nineteen organics were selected, including several munitions and chlorinated solvents. Compounds were selected to offer a range of physical properties, such as solubility in water, octanol/water partition coefficient, and molecular structure. When these results were compared with the results from a similar study conducted at ppm levels, the rate and extent of sorption by PTFE and PVC were the same as seen previously for almost all analytes. There were no losses of any compounds associated with stainless steel. At these low levels (ppm and ppb), the rate of diffusion within the polymer (PVC and PTFE) is independent of concentration. Only with PTFE are the rates rapid enough to be of concern when monitoring for some contaminants in ground water. Tetrachloroethylene was the compound PTFE sorbed the most rapidly. The study showed that PVC well casings are suitable for monitoring low levels (ppm and ppb) of organics. 相似文献
4.
This letter describes the extension of signal subspace processing (SSP) to the arena of anomaly detection. In particular, we develop an SSP-based, local anomaly detector that exploits the rich information available in the multiple bands of a hyperspectral (HS) image. This SSP approach is based on signal processing considerations, and its entire formulation reduces to a straightforward (and intuitively pleasing) geometric and algebraic development. We extend the basic SSP concepts to the HS anomaly detection problem, develop an SSP HS anomaly detector, and evaluate this algorithm using multiple HS data files. 相似文献
5.
This is the second part of a study conducted to determine whether polymeric sampling tubing can affect organic analyte concentrations during a sampling event. In this part of the study, we looked for sorption and desorption of tricholoroethylene (TCE) and leaching of organic constituents in water pumped through five types of polymeric tubing. The materials tested were a rigid fluoropolymer, a flexible fluoropolymer, low-density polyethylene (LDPE), and two plasticized polypropylene tubings. The effects of tubing length and flow rate were examined.
The least sorptive tubings, both initially and at equilibrium, were the fluoropolymers. However, in some instances the LDPE tubing had little effect on TCE concentrations. This was when a slow flow rate was used to sample relatively shallow wells (50 feet [15 m] or less) or when a faster flow rate (1 L/min) was used to sample wells that are less than 500 feet (152 m). Further testing is recommended using more sorptive analytes.
Using high performance liquid chromatography (HPLC), we were unable to detect any constituents leaching from any of the tubings used in these studies, even when a slow flow rate was used. However, desorption of sorbed analytes is a concern for all the tubings tested, including the rigid fluoropolymer. 相似文献
The least sorptive tubings, both initially and at equilibrium, were the fluoropolymers. However, in some instances the LDPE tubing had little effect on TCE concentrations. This was when a slow flow rate was used to sample relatively shallow wells (50 feet [15 m] or less) or when a faster flow rate (1 L/min) was used to sample wells that are less than 500 feet (152 m). Further testing is recommended using more sorptive analytes.
Using high performance liquid chromatography (HPLC), we were unable to detect any constituents leaching from any of the tubings used in these studies, even when a slow flow rate was used. However, desorption of sorbed analytes is a concern for all the tubings tested, including the rigid fluoropolymer. 相似文献
6.
Twenty polymeric tubings were filled with a test solution containing eight organic solutes. The test solutions were monitored for losses, indicating that sorption had occurred, and for signs that leaching of organic constituents had occurred. The tubings tested included seven flexible products and eight fluoropolymers. Among the rigid tubings tested, three fluoropolymers (fluorinated ethylene propylene [FEP], FEP-lined polyethylene, polyvinylidene fluoride) were the least sorptive tubings. However, even these tubings readily sorbed some of the analytes. Among the flexible tubings tested, a fluoroelastomer tubing and a tubing made of a copolymer of vinylidene fluoride and hexafluoropropylene were the least sorptive.
Several of the tubings tested leached constituents into the test solution. The polyurethane, polyamide, flexible polyvinyl chloride (PVC), polyester-lined PVC, and silicone-modified thermoplastic elastomer tubings were found to leach the most constituents. We were unable to detect any constituents leaching from the polyethylene tubings, the rigid fluoropolymer tubings, and one of the plasticized polypropylene tubings. 相似文献
Several of the tubings tested leached constituents into the test solution. The polyurethane, polyamide, flexible polyvinyl chloride (PVC), polyester-lined PVC, and silicone-modified thermoplastic elastomer tubings were found to leach the most constituents. We were unable to detect any constituents leaching from the polyethylene tubings, the rigid fluoropolymer tubings, and one of the plasticized polypropylene tubings. 相似文献
7.
The absence of “rim gravels” north of Grand Canyon and of “Canaan Peak-type” gravels south of Grand Canyon suggests that a paleocanyon, which intersected the transport of these gravels north and south, may have begun forming in the Laramide in approximately the same position as today's central Grand Canyon. This Laramide-age canyon is envisioned as having flowed generally from the SW to NE; from the Peach Springs Canyon area to Mile 197 where it was captured by karst; then along a N. 60°E joint system to the Kanab Point area where it converged with drainage coming off the west side of the Kaibab arch. From there it flowed north along the west flank of the Kaibab arch to Paleogene Lake Claron. The critical idea suggested by this proposed model is that the modern Colorado River utilized Laramide paleotopography in establishing its course through the central Grand Canyon, with younger sections of the canyon integrating with it later, in the middle to late Miocene. This paleocanyon route, in association with headward erosion from the Grand Wash Cliffs toward the Kaibab arch after 16–17 Ma, helps account for the total volume of rock eroded from Grand Canyon, which cannot be explained by present-day incision rates. 相似文献
8.
松辽盆地早白垩世火山岩地球化学特征及其构造意义 总被引：4，自引：2，他引：2
松辽盆地早白垩世发育基性岩类的橄榄玄武岩、玄武岩,中性岩类的玄武安山岩、安山岩、粗安岩,酸性岩类的粗面岩、粗面英安岩、英安岩和流纹岩。早白垩世火山岩都具有大离子亲石元素(LILE)、轻稀土元素(LREE)相对富集的特征,并具有较低的(~(87)Sr/~(86)Sr)_i值和较高的(~(143)Nd/~(144)Nd)_i值。基性岩类Ce/Nb=1.92～8.31,Th/Nb=0.08～0.44,(~(87)Sr/~(86)Sr)_i=0.7031～0.7047,ε_(Nd)(t)=+1.7～+5.2;中性岩类Ce/Nb=3.70～15.80,Th/Nb=0.34～2.58,(~(87)Sr/~(86)Sr)_i=0.7040～0.7054,ε_(Nd)(t)=0～+3.0;酸性岩类Ce/Nb=4.29～15.80,Th/Nb=0.11～1.02,(~(87)Sr/~(86)Sr)_i=0.7038～0.7066,ε_(Nd)(t)=+1.0～+3.3。基性岩类岩浆主要来自被富集了的亏损地幔源的部分熔融,受混染程度很小;中性岩类岩浆源于年轻地壳组分被来自亏损地幔岩浆的再次部分熔融;酸性岩类浆岩可能主要来自源于亏损地幔的初生地壳部分熔融,并受到了上地壳的混染。晚侏罗世-早白垩世,由于蒙古-鄂霍次克洋关闭引发强烈的挤压造山后,发生的岩石圈拆沉作用致使来自亏损地幔的岩浆熔融上涌导致岩石圈主动伸展拉张,地表则表现出大规模的裂谷断陷作用和大范围的火山活动。这个阶段的伸展拉张以主动拉张为主。 相似文献
9.
新疆哈密香山西铜镍-钛铁矿床系同源岩浆分异演化产物——矿相学、锆石U-Pb年代学及岩石地球化学证据 总被引：19，自引：9，他引：10
香山西岩体是东天山地区发现的唯一的一个铜镍-钛铁复合型含矿岩体,前人对香山西铜镍-钛铁矿床成因认识一直存在争议。本次通过矿相学研究结合电子探针分析,在香山西铜镍矿石中发现了铜镍硫化物与钛铁氧化物共生的现象,并首次测定了香山西钛铁辉长岩的SIMS锆石U-Pb年龄为278.6±1.8Ma(MSWD=1.2),与前人测得香山中岩体角闪辉长岩的锆石U-Pb年龄基本一致,证实了香山西铜镍矿与钛铁矿为共生关系,两者空间上渐变过渡。岩石地球化学研究表明,香山岩体(包括钛铁辉长岩)为同源岩浆经结晶分异作用形成的一套镁铁-超镁铁质岩体,具有拉斑玄武质岩浆分异演化趋势,并且经历了与地壳物质的混染。与中段和东段岩石相比,香山西辉长岩类具有相对高的REE、SiO2(平均48.99%)、K2O+Na2O(平均3.43%)、TiO2(平均1.26%)和明显低的Mg#值(平均62.4),表现出分异演化程度高于中段和东段。经反演得出香山岩体原始岩浆含MgO约10%,FeO约9%,TiO2约1.14%,与同一成矿带内其它含铜镍矿岩体原始岩浆成份相近,应为 普通的拉斑玄武质岩浆。因此,香山西钛铁矿床的形成机制可能是由普通的拉斑玄武质岩浆,经历了较高程度的分异演化导致钛铁氧化物在残余岩浆中逐步富集,岩浆在上升侵位过程中与地壳物质的混染,不仅促使了岩浆中硫化物的饱和,同时提高了岩浆体系的氧逸度,进而促使了钛铁氧化物结晶沉淀。对香山西钛铁矿床成因研究的启示意义在于,除我国攀西地区高钛的玄武质岩浆外,普通的拉斑玄武质岩浆,在有利的分异演化条件下(如初始低氧逸度、相对高度的分异演化、后期与地壳物质混染)也有可能形成大型钛铁矿床。 相似文献
10.
南秦岭宁陕地区月河坪夕卡岩型钼矿Re-Os年龄和矿床学特征 总被引：4，自引：2，他引：2
宁陕地区月河坪钼矿床位于南秦岭多金属成矿带,属于夕卡岩型钼矿。本文采用辉钼矿Re-Os同位素定年方法,精确地测定月河坪钼矿的成矿时代。分析结果显示,5件辉钼矿样品Re-Os同位素模式年龄的变化范围小,集中在189.8Ma和195.4Ma之间,获得加权平均年龄值191.4±1.6Ma,与等时线回归计算得到的年龄值193.6±3.5Ma在误差范围内相吻合。结果说明成矿时代为早侏罗纪,成矿作用属于中国北部燕山期大规模成矿期的一部分。结合已报道的成矿年龄资料,月河坪钼矿床可能形成于扬子板块与华北板块的后碰撞造山作用过程,但有可能受到后期岩浆活动的改造和破坏。同时推测在南秦岭地区存在印支末期到燕山早期的成矿事件,这对于秦岭造山带尤其是南秦岭地区钼矿资源勘探具有借鉴意义。 相似文献