Anaerobic oxidation of methane (AOM) in marine sediments from the Skagerrak (Denmark): II. Reaction-transport modeling     

A.W. Dale  P. Regnier  B.B. Jørgensen 《Geochimica et cosmochimica acta》2008,72(12):2880-2894

A steady-state reaction-transport model is applied to sediments retrieved by gravity core from two stations (S10 and S13) in the Skagerrak to determine the main kinetic and thermodynamic controls on anaerobic oxidation of methane (AOM). The model considers an extended biomass-implicit reaction network for organic carbon degradation, which includes extracellular hydrolysis of macromolecular organic matter, fermentation, sulfate reduction, methanogenesis, AOM, acetogenesis and acetotrophy. Catabolic reaction rates are determined using a modified Monod rate expression that explicitly accounts for limitation by the in situ catabolic energy yields. The fraction of total sulfate reduction due to AOM in the sulfate-methane transition zone (SMTZ) at each site is calculated. The model provides an explanation for the methane tailing phenomenon which is observed here and in other marine sediments, whereby methane diffuses up from the SMTZ to the top of the core without being consumed. The tailing is due to bioenergetic limitation of AOM in the sulfate reduction zone, because the methane concentration is too low to engender favorable thermodynamic drive. AOM is also bioenergetically inhibited below the SMTZ at both sites because of high hydrogen concentrations (∼3-6 nM). The model results imply there is no straightforward relationship between pore water concentrations and the minimum catabolic energy needed to support life because of the highly coupled nature of the reaction network. Best model fits are obtained with a minimum energy for AOM of ∼11 kJ mol⁻¹, which is within the range reported in the literature for anaerobic processes.  相似文献   

A seismic refraction study of cretaceous oceanic lithosphere in the Northwest Pacific Basin     

Michel Bée  L. Dale Bibee 《Marine Geophysical Researches》1989,11(4):239-261

A seismic refraction study on old (110 Myr) lithosphere in the northwest Pacific Basin has placed constraints on crustal and uppermantle seismic structure of old oceanic lithosphere, and lithospheric aging processes. No significant lateral variation in structure other than azimuthally anisotropic mantle velocities was found, allowing the application of powerful amplitude modeling techniques. The anisotropy observed is in an opposite sense to that expected, suggesting the tectonic setting of the area may be more complex than originally thought. Upper crustal velocities are generally larger than for younger crust, supporting current theories of decreased porosity with crustal aging. However, there is no evidence for significant thickening of the oceanic crust with age, nor is there any evidence of a lower crustal layer of high or low velocity relative to the velocity of the rest of Layer 3. The compressional and shear wave velocities rule out a large component of serpentinization of mantle materials. The only evidence for a basal crustal layer of olivine gabbro cumulates is a 1.5 km thick Moho transition zone. In the slow direction of anisotropy, upper mantle velocities increase from 8.0 km s^-1 to 8.35 km s^-1 in the upper 15 km below the Moho. This increase is inconsistent with an homogeneous upper mantle and suggests that compositinal or phase changes occur near the Moho.  相似文献   

Freezing as a method of sample preservation for the analysis of dissolved inorganic nutrients in seawater   总被引：1，自引：0，他引：1  

John E. Dore  Terrence Houlihan  Dale V. Hebel  Georgia Tien  Luis Tupas  David M. Karl 《Marine Chemistry》1996,53(3-4)

It is often desirable or necessary to store collected seawater samples prior to analysis for dissolved inorganic nutrients. It is therefore important to establish preservation and storage techniques that will ensure sample integrity and will not alter the precision or accuracy of analysis. We have performed a series of experiments on the storage of nutrient samples collected at the oligotrophic North Pacific benchmark Station ALOHA, using both standard autoanalyses and low-level techniques. Our results reveal that for oligotrophic oceanic waters, the immediate freezing of an unfiltered water sample in a clean polyethylene bottle is a suitable preservation method. This procedure is simple, it avoids potentially contaminating sample manipulations and chemical additions, and it adequately preserves the concentrations of nitrate + nitrite, soluble reactive phosphate, and soluble reactive silicate within a single water sample.  相似文献   

Dynamics of the long-period tides     

Carl Wunsch  Dale B. Haidvogel  Mohamed Iskandarani  R. Hughes 《Progress in Oceanography》1997,40(1-4)

The long-period tides are a tool for understanding oceanic motions at low frequencies and large scales. Here we review observations and theory of the fortnightly, monthly and pole tide constitutents. Observations have been plagued by low signal-to-noise ratios and theory by the complex lateral geometry and great sensitivity to bottom slopes. A new spectral element model is used to compute the oceanic response to tidal forcing at 2-week and monthly periods. The general response is that of a heavily damped (Q ≈ 5) system with both the energy input from the moon and the dissipation strongly localized in space. The high dissipation result is probably generally applicable to all low frequency barotropic oceanic motions. Over much of the ocean, the response has both the character of a large-scale and a superposed Rossby wave-like character, thus vindicating two apparently conflicting earlier interpretations. To the extent that free waves are excited they are consistent with their being dominated by Rossby and topographic Rossby wave components, although gravity modes are also necessarily excited to some degree. In general, a modal representation is not very helpful. The most active regions are the Southern Ocean and the western and northern North Atlantic. These results are stable to changes in geometry, topography, and tide period. On a global average basis, the dynamical response of Mm is closer to equilibrium than is Mf.  相似文献   

Microwave emission from a sunspot     

Jeongwoo W. Lee  G. J. Hurford  Dale E. Gary 《Solar physics》1993,144(1):45-57

From the gyroresonance brightness temperature spectrum of a sunspot, one can determine the magnetic field strength by using the property that microwave brightness is limited above a frequency given by an integer-multiple of the gyrofrequency. In this paper, we use this idea to find the radial distribution of magnetic field at the coronal base of a sunspot in the active region, NOAA 4741. The gyroresonance brightness temperature spectra of this sunspot are obtained from multi-frequency interferometric observations made at the Owens Valley Radio Observatory at 24 frequencies in the range of 4.0–12.4 GHz with spatial resolution 2.2″–6.8″. The main results of present study are summarized as follows: first, by comparison of the coronal magnetic flux deduced from our microwave observation with the photospheric magnetic flux measured by KPNO magnetograms, we show that theo-mode emission must arise predominantly from the second harmonic of the gyrofrequency, while thex-mode arises from the third harmonic. Second, the radial distribution of magnetic fieldsB(r) at the coronal base of this spot (say, 2000–4000 km above the photosphere) can be adequately fitted by $$B(r) = 1420(1 \pm 0.080)\exp \left[ { - \left( {\frac{r}{{11.05''(1 \pm 0.014)}}} \right)^2 } \right]G,$$ wherer is the radial distance from the spot center at coronal base. Third, it is found that coronal magnetic fields originate mostly from the photospheric umbral region. Fourth, although the derived vertical variation of magnetic fields can be approximated roughly by a dipole model with dipole moment 1.6 × 10³⁰ erg G^?1 buried at 11000 km below the photosphere, the radial field distribution at coronal heights is found to be more confined than predicted by the dipole model.  相似文献   

Infrared spectrum of Io, 2.8–5.2 μm     

Dale P. Cruikshank 《Icarus》1980,41(2):240-245

The reflectance spectrum of Io is presented from 2.8 to 5.2 μm, extending the earlier results of D. P. Cruikshank, T. J. Jones, and C. B. Pilcher (1978, Astrophys. J. 225, L89–L92), and demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 μm. Laboratory spectra of nitrates and carborates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on the recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds as reported in a companion paper (F. P. Fanale, R. H. Brown, D. P. Cruikshank, and R. N. Clark, 1979, Nature280, 761–763).  相似文献   

Galilean satellite eclipse studies: III. Jovian methane abundance     

Dale W. Smith  Thomas F. Greene 《Icarus》1980,44(1):134-141

The methane abundance in the lower Jovian stratosphere is measured using Galilean satellite eclipse light curves. Spectrally selective observations in and between absorption bands are compared. An average mixing ratio at the locations measured is [CH₄]/[H₂] ～ 1.3 × 10^?3, larger than the value 0.9 × 10^?3 expected for a solar abundance of carbon. Some zenographic variation of the mixing ratio may occur. Observationally compatible values are 1.3–2.0 × 10^?3 in the STZ, 1.3– 2.6 × 10^?3 on the GRS/STrZ edge, and 0.7–1.3 × 10^?3 in the GRS.  相似文献   

Remote comets and related bodies: VJHK colorimetry and surface materials     

William K. Hartmann  Dale P. Cruikshank  Johan Degewij 《Icarus》1982,52(3):377-408

Spectrophotometric data show that major compositional groups among outer solar system (OSS) surfaces include bright ices and at least two distinct classes of blackish carbonaceous-like materials, called C-type and RD-type. VJHK colorimetry of asteroids, satellites, and laboratory samples shows that these three classes can be distinguished by VJHK colors. We define an “α index” that denotes the position of objects in VJHK color - color diagrams; it empirically increases with albedo and ice/dirt ratio. We use the above data to define color fields that may be useful in interpreting our observations of eight comets (1980–1981). All eight comets have colors generally resembling RD asteroids and are inconsistent with reflection off clean ice surfaces. The observations suggest that these comets' halos contain RD dirt or dirty ice grains colored by RD dirt, supporting J. Gradie and J. Veverka's [Nature283, 840–842 (1980)] prediction of RD, rather than C, material in comets. Remote Comet P/Schwassmann-Wachmann 1 was observed both during outburst and quiescence and had the highest α index of any observed comet. Comet α indices appear to be correlated with solar distance. Further work will be needed to clarify possible coloring effects due to particle size, dispersal, and composition. We suggest a number of physical interpretations based on a single two-component mixing model, which assumes that all OSS planetesimals formed primarily from bright ices and dark carboneceous-like dirt, consistent with condensation theory. We discuss differentiation processes that concentrated one component or the other at the surface. All measured OSS interplanetary bodies have surfaces of dark dirt or dark dirty ice colored by the dirt component. Comets, consistent with the Whipple dirty iceberg model, are such objects close enough to the Sun for volatilization to throw dirty ice grains into the coma. In remote comets, the ice component of the grains remains stable, and we see dirty ice grains; in near comets, the ice component vaporizes, and we see dirt grains. A volatile-depleted dusty regolith on P/Schwassmann-Wachmann 1 and other remote comets could explain their eruptive behavior by means of gas pressure buildup in the porous, weakly bonded dust.  相似文献   

Hydrocarbons in surficial sediments from the Scotian Shelf     

Paul D Keizer  J Dale  D.C Gordon 《Geochimica et cosmochimica acta》1978,42(2):165-172

Surface sediments from 20 stations on the Scotian Shelf, collected on a transect from Halifax to Emerald Bank and around Sable Island, have been analyzed for hydrocarbon content and composition by gas chromatography and fluorescence spectrophotometry. Some samples were taken near abandoned exploratory drilling sites in the Sable Island area. Hydrocarbons appear to be mainly derived from biogenic terrestrial sources as evidenced by an inverse correlation of concentration with increasing distance from the mainland and a strong odd carbon preference in the n-alkanes. Contribution from petroleum sources, while minor, was most noticeable between Halifax and Emerald Bank. There is also evidence that the hydrocarbon composition at abandoned exploratory drilling sites has been slightly altered.  相似文献   

Cross-formational hydrocarbon fluid flows in the Tertiary deltaic system of the Beaufort–Mackenzie Basin     

Maowen Li  Yongqiang Xiong  Lloyd R. Snowdon  Dale Issler 《Journal of Geochemical Exploration》2006,89(1-3):214

Molecular and isotopic compositions of crude oils in the Beaufort–Mackenzie Basin confirm three genetic end-member oil groups and suggest extensive cross-formational hydrocarbon fluid flows in the Tertiary deltaic system. Inter- and intra-fractional variations in the geochemistry of the Tertiary-reservoired oils indicate that the oil source/maturity signatures were substantially masked by biomarkers that were picked up along migration pathways. Thus, many of the previously recognized “immature non-marine oils” are in fact thermally mature, probably derived from unpenetrated deeper marine source rocks. Although the effective source rock volumes have not been evaluated and their exact stratigraphic levels remain unknown, the relative timing of oil generation versus trap formation, rather than poor source quality, may be the cause of under-filled traps in the offshore area.  相似文献