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新疆博格达造山带晚古生代构造-岩浆演化过程:火山岩组合及地球化学证据 总被引：9，自引：3，他引：6
最近,笔者在博格达山东段北部的西地-伊齐-小红柳峡一带的地质调查中发现,该区发育有大量晚石炭世柳树沟组双峰式火山岩及早二叠世卡拉岗组酸性火山岩建造,但双峰式火山岩性质及成因有别于其南侧七角井早石炭世双峰式火山岩。玄武岩富钠贫钾(K_2O=0.18%～0.45%,Na_2O=2.24%～3.63%),属拉斑系列;TiO_2=1.6%～1.7%,略高于MORB,较高的Al(Al_2O_3=16.2%～16.7%)、高Mg(MgO=8.12%～9.54%,Mg~#=61～64),以及低K_2O/TiO_2和K_2O/P_2O_5比值(分别为0.1～0.27、0.63～1.68),反映了在岩浆演化过程中分离结晶作用不明显;Rb/Sr比值0.01～0.02,Zr/Nb=21.6～39.7,Zr/Y=5.38～7.47,以及不相容元素Ba、Zr、Hf相对略富集、Nb-Ta和Th相对亏损,显示岩石具有板内玄武岩的特点;稀土元素球粒陨石标准化配分图上整体接近于平坦型,(La/Yb)_N=1.8～1.9,Eu无异常至轻微正异常(δEu=1.07～1.12),正ε_(Nd)(t)值(+5.63～+5.89),(~(143)Nd/~(144)Nd)_I=0.512927～0.512944,Th/Yb0.2,Ta/Yb=0.1,表明玄武岩浆源于亏损软流圈地幔,且在演化过程中不曾发生过斜长石的分离结晶作用,并暗示当时的大陆地壳可能由于拉张而变得较薄,玄武岩浆形成后快速上升至地表喷发。双峰式火山岩中的流纹岩Rb-Sr等时线年龄为296±2Ma(1σ),具高Si(SiO_2=76%～80%),富钾贫钠(K_2O=5.1%～5.7%,Na_2O=0.94%～2.03%);低Al(Al_2O_3=7.9%～10.4%);低Ti、Ca和P含量,属高钾钙碱性系列;微量元素Rb、Th、Zr、Hf、K相对富集,Ba、Sr、P、Ti、Nb、Ta为显著亏损;轻稀土元素适度富集且轻、重稀土分馏程度低,(La/Yb)_N=5.1～7.1,(La/Sm)_N=2、(Gd/Yb)_N=1.6～2.2,以及强烈的负Eu异常(δEu=0.17～0.2),(~(87)Sr/~(86)Sr)_I=0.7051～0.7052,δ~(18)O=11.6‰,指示岩石源于地壳物质的部分熔融,源区存在有斜长石残留,形成于大陆裂谷环境。早二叠世末流纹岩(Rb-sr等时线年龄为278±2Ma)具高Si(SiO_2=74%),富钾贫钠(K_2O/Na_2O2),低Al(Al_2O_3=11.0%)以及较低的Ti和P含量的特征,岩石为高钾钙碱性系列;微量元素PM标准化图解上表现为Rb、Ba、Th、U、K、La、Ce不相容元素相对富集,高场强元素Nb、Ta、P、Ti以及Sr为明显的负异常;轻稀土轻度富集,(La/Yb)_N=5～6,(La/Sm)_N=3,(Gd/Yb)_N=1.3～1.4,以及强烈的负Eu异常(δEu=0.31～0.39),(~(87)Sr/~(86)Sr)_I为0.7069,δ~(18)O=11.97‰,指示源于地壳物质部分熔融的产物,形成于伸展垮塌的构造环境。综合研究结果表明,博格达山前身裂谷岩浆作用始于早石炭世,结束于晚石炭世末期,早二叠世末进入后造山伸展的演化阶段。 相似文献
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Deposits of Fe-Si-Mn oxyhydroxides are commonly found on the seafloor on seamounts and mid-ocean spreading centers. At Franklin Seamount located near the western extremity of Woodlark Basin, Papua New Guinea, Fe-Si-Mn oxyhydroxides are being precipitated as chimneys and mounds upon a substrate of mafic lava. Previous studies have shown that the vent fluids have a low temperature (20–30°C) and are characterized by a total dissolved iron concentration of 0.038 mM kg-1, neutral pH (6.26) and no measurable H2S. The chimneys have a yellowish appearance with mottled red–orange patches when observed in situ from a submersible, but collected samples become redder within a few hours of being removed from the sea. The amorphous iron oxyhydroxides, obtained from active and inactive vents, commonly possess filamentous textures similar in appearance to sheaths and stalks excreted by the iron-oxidizing bacteria Leptothrix and Gallionella; however, formless agglomerates are also common. Textural relationships between apparent bacterial and non-bacterial iron suggest that the filaments are coeval with and/or growing outwards from the agglomerates. The amorphous iron oxyhydroxides are suggested to precipitate hydrothermally as ferrosic hydroxide, a mixed-valence (Fe2+-Fe3+) green–yellow iron hydroxide compound. Consideration of the thermodynamics and kinetics of iron in the vent fluid, suggest that the precipitation is largely pH controlled and that large amounts of amorphous iron oxyhydroxides are capable of being precipitated by a combination of abiotic hydrothermal processes. Some biologically induced precipitation of primary ferric oxyhydroxides (two-XRD-line ferrihydrite) may have occurred directly from the fluid, but most of the filamentous iron micro-textures in the samples appear to have a diagenetic origin. They may have formed as a result of the interaction between the iron-oxidizing bacteria and the initially precipitated ferrosic hydroxide that provided a source of ferrous iron needed for their growth. The processes described at Franklin Seamount provide insight into the formation of other seafloor oxyhydroxide deposits and ancient oxide-facies iron formation. 相似文献
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